| POLYMERS AND POLYMER MATRIX COMPOSITES |
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| Polymer-based Nanoreactors in Catalytic Chemistry |
| QIU Jiaqi1, MIN Yuting1, CHEN Tao1,2,*
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1 Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
2 Key Laboratory of Green Cleaning Technology & Detergent of Zhejiang Province, Lishui 323000, Zhejiang, China |
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Abstract The polymer-based nanoreactor has the characteristics of easy preparation, good dispersion and facile modulation of molecular structure. The introduction of homogeneous catalyst into polymer-based nanoreactor can not only realize the organic combination of homogeneous catalysis and heterogeneous catalysis, but also effectively utilize the nanoreactor's substrate concentration effect, confinement effect, etc. Polymer-based nanoreactors have been widely used in many fields, such as separation, sensing, electronics, drug delivery, catalysis, etc. In the field of catalysis, the polymeric nanoreactor simulates the microenvironment of enzyme possessing excellent catalytic activity in water. Besides, polymer-based nanoreactor is recyclable and can be used for cascade catalysis. Therefore, researchers around the world have designed a large number of catalytic nanoreactors with different structures, including nanoreactors based on amphiphilic polymers, crosslinked polymers, single-chain particles and other types of polymers. These catalytic nanoreactors displayed excellent catalytic performance. This paper reviews the fabrication and catalytic application of such polymer-based nanoreactors.
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Published:
Online: 2023-01-03
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| Fund:National Natural Science Foundation of China(52273216). |
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