金属基纳米材料在过硫酸盐高级氧化工艺中的应用进展

doi:10.11896/cldb.21040022

Abstract
Figure/Table
References
Related Citation (11)

Download:

Full Text ( PDF ) (21013KB)
Export: BibTeX | EndNote (RIS)

Abstract With the rapid development of persulfate advanced oxidation methods, the improvement of catalysts for the efficient activation of persulfate has attracted considerable attention from researchers worldwide. Among the heterogeneous catalysts for persulfate, metal-based nanomaterials are characterized by good catalytic properties, chemical stability, and reusability, owing to their small particle size, large specific surface area, high specific surface activation energy, and excellent magnetic properties. Therefore, metal-based nanomaterials are considered to be the most suitable materials as persulfate activators and have considerable potential for application in the field of environmental pollution control. However, single metal nanoparticles are prone to particle agglomeration, self-oxidation, and metal ion release during the reaction process, thereby partly limiting the extensive application of metal nanocatalysts.
To address this problem, researchers have used composite materials as alternatives to single materials as persulfate activators to treat environmental pollutants. For example, metal nanoparticles have been loaded onto different carrier materials during catalyst preparation, which facilitates synergistic treatment effects, reduces the loss of metal ions, and enhances the reusability of catalysts. In addition, polymetallic nanocomposites with unique structures have been prepared as heterogeneous catalysts, and the synergistic effects of multiple metals have been demonstrated to further enhance the activation performance of catalysts, thereby improving the efficiency of pollutant removal. Numerous studies have recently examined the preparation and structural properties of metal-based nanoparticles, mechanisms underlying the generation of free radical and non-free radical species in activation process of persulfate, and the removal effects and mechanisms of pollutant by metal-based nanocomposites activated persulfate, thereby contributing to valuable research data.
In this paper, we present a comprehensive review of the theoretical and applied research that has been conducted on persulfate oxidation using nano-zero-valent metals, nano-metal oxides, nano-ferrite, and supported metal nanoparticles as catalysts. We present a systematic summary of the preparation methods and structural characteristics of different metal nanoparticles, the reaction mechanisms underlying the persulfate activation in generating active species. We also propose that metal nanoparticles have low catalytic stability and certain environmental risks when used for persulfate activation. Moreover, we suggest future research directions, which will serve as a reference for the development and application of safe and efficient metal nanocatalysts for use in the persulfate advanced oxidation.

Key words： Metal nanoparticles activated persulfate advanced oxidation process heterogeneous catalysis free radical

Published: 25 February 2023 Online: 2023-03-02

CLC number:

X505

Fund:Natural Science Foundation of Heilongjiang Province, China (LH2019D002).

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	MUSAJAN Zulhumar
	ZHAO Jing
	XIAO Pengfei

Cite this article:

MUSAJAN Zulhumar,ZHAO Jing,XIAO Pengfei. Application Progress of Metal Nanomaterials in Persulfate-based Advanced Oxidation Process[J]. Materials Reports, 2023, 37(4): 21040022-8.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.21040022 OR http://www.mater-rep.com/EN/Y2023/V37/I4/21040022

1 An L, Xiao P. RSC Advances, 2020, 10, 19401.
2 Xiao P, An L, Wu D. New Carbon Materials, 2020, 35, 667.
3 Duan X, Sun H, Kang J, et al. ACS Catalysis, 2015, 5, 4629.
4 Saravanan A, Kumar P, Karishma S, et al. Chemosphere, 2021, 264, 128580.
5 Liu J, Jiang J, Meng Y, et al. Journal of Hazardous Materials, 2020, 388, 122026.
6 Rana A, Yadav K, Jagadevan S. Journal of Cleaner Production, 2020, 272, 122880.
7 Xiao R, Luo Z, Wei Z, et al. Current Opinion in Chemical Engineering, 2018, 19, 51.
8 Xiao P F, Jiang S J. Chemical Industry and Engineering Progress, 2018, 37(12), 4862 (in Chinese).
肖鹏飞, 姜思佳. 化工进展, 2018, 37(12), 4862.
9 Du J, Wang Y, Faheem, et al. RSC Advances, 2019, 9, 20323.
10 Jin X Y, Li R C, Chen Z L. Environmental Chemistry, 2014, 33(5), 812 (in Chinese).
金晓英, 李任超, 陈祖亮. 环境化学, 2014, 33(5), 812.
11 Li R, Jin X, Megharaj M, et al. Chemical Engineering Journal, 2015, 264, 587.
12 Kim C, Ahn J, Kim T, et al. Environmental Science & Technology, 2018, 52, 3625.
13 Yirsaw B, Megharaj M, Chen Z, et al. Journal of Environmental Sciences, 2016, 44, 88.
14 Fu X Y, Zhao W T, Du J S, et al. China Water & Wastewater, 2020, 36(11), 57 (in Chinese).
傅晓艳, 赵委托, 杜江坤, 等. 中国给水排水, 2020, 36(11), 57.
15 Fu X Y, Bao J G, Du J S, et al. Safety and Environmental Engineering, 2015, 22(6), 51 (in Chinese).
傅晓艳, 鲍建国, 杜江坤, 等. 安全与环境工程, 2015, 22(6), 51.
16 Shah N, Khan J, Sayed M, et al. Journal of Cleaner Production, 2020, 246, 119032.
17 Ghorbanian Z, Asgari G, Samadi M, et al. Journal of Molecular Liquids, 2019, 296, 111873.
18 Moghaddam S, Rasoulifard M, Vahedpour M, et al. Korean Journal of Chemical Engineering, 2014, 31, 1577.
19 Ye Q, Xu H, Zhang J, et al. Chemical Engineering Journal, 2020, 382, 123054.
20 Shah N, Khan J, Sayed M, et al. Chemical Engineering Journal, 2019, 356, 199.
21 Shi Q Q, Pu S Y, Yang X. Environmental Science, 2020, 41(10), 4615 (in Chinese).
石清清, 蒲生彦, 杨犀. 环境科学, 2020, 41(10), 4615.
22 Fang L, Liu K, Li F, et al. Journal of Hazardous Materials, 2021, 403, 123669.
23 Shan A, Farooq U, Lyu S, et al. Chemical Engineering Journal, 2020, 386, 123995.
24 Chen L, Cai T, Sun W, et al. Journal of the Taiwan Institute of Chemical Engineers, 2017, 80, 720.
25 Shabanloo A, Salari M, Shabanloo N, et al. Journal of Molecular Liquids, 2020, 298, 112088.
26 Yeşil R, Çetinkaya S. Journal of Nanoparticle Research, 2020, 22, 198.
27 Ding Y, Pan C, Peng X, et al. Chemical Engineering Journal, 2020, 384, 123378.
28 You J, Sun W, Su S, et al. Chemical Engineering Journal, 2020, 400, 125925.
29 Zhang L, Liu B, Li J. Journal of Molecular Liquids, 2020, 299, 112096.
30 Zhang L, Guo Y, Xie R, et al. Water, Air, & Soil Pollution, 2020, 231, 375.
31 Jiang X, Guo Y, Zhang L, et al. Chemical Engineering Journal, 2018, 341, 392.
32 Zhang L, Shen S. Journal of Industrial and Engineering Chemistry, 2020, 83, 123.
33 Wu Y, Chen X, Han Y, et al. Environmental Science & Technology, 2019, 53, 9081.
34 Wu X, Xu G, Zhu J. Ultrasonics Sonochemistry, 2019, 58, 104634.
35 Yao Y, Chen H, Lian C, et al. Journal of Hazardous Materials, 2016, 314, 129.
36 Jiang Z, Zhao J, Li C, et al. Carbon, 2020, 158, 172.
37 Xiao P F, An L, Han S. Chemical Industry and Engineering Progress, 2020, 39(8), 3293 (in Chinese).
肖鹏飞, 安璐, 韩爽. 化工进展, 2020, 39(8), 3293.
38 Wang Y, Zhu X, Feng D, et al. Catalysts, 2019, 9, 1062.
39 Zhai W Y, Li M, Zhang Q. China Environmental Science, 2020, 40(6), 2483 (in Chinese).
翟文琰, 李孟, 张倩. 中国环境科学, 2020, 40(6), 2483.
40 Zhang B, Wang Q, Zhang Y, et al. Separation and Purification Technology, 2020, 242, 116820.
41 Wang A D, Feng Z D, Qin D Y, et al. Acta Scientiarum Naturalium Universitatis Pekinensis, 2020, 56(4), 703 (in Chinese).
王爱德, 冯振东, 覃大禹, 等. 北京大学学报(自然科学版), 2020, 56(4), 703.
42 Li S, Tang J, Liu Q, et al. Environmental International, 2020, 138, 105639.
43 Wu H, Jian W, Zhang L, et al. Materials Science in Semiconductor Processing, 2021,121, 105373.
44 Huang Z, Lin Q, Luo H, et al. Chemical Engineering Journal, 2020, 398, 125458.
45 Deng S, Zhang X, Lv G, et al. Journal of Sol-Gel Science and Technology, 2019, 91, 54.
46 Fu X, Zhang J, Zhao H, et al. Separation and Purification Technology, 2020, 230, 115886.
47 Liu L, Li Y, Pang Y, et al. Chemical Engineering Journal, 2020, 401, 126014.
48 Dong X, Ren B, Sun Z, et al. Applied Catalysis B:Environmental, 2019, 253, 206.
49 Dong X, Ren B, Zhang X, et al. Applied Catalysis B:Environmental, 2020, 272, 118971.
50 Wang Y, Zhang Y, Wang J, et al. Journal of Membrane Science, 2020, 615, 118559.
51 Tan Y, Li C, Sun Z, et al. Chemical Engineering Journal, 2020, 388, 124386.
52 Xu X, Chen W, Zong S, et al. Journal of Hazardous Materials, 2019, 377, 62.
53 Zong S, Xu X, Ran G, et al. RSC Advances, 2020, 10, 11410.
54 Yang S, Duan X, Liu J, et al. Applied Catalysis B: Environmental, 2020, 267, 118701.
55 Yang S, Huang Z, Wu P, et al. Applied Catalysis B:Environmental, 2020, 260, 118129.
56 Wu J, Wang B, Blaney L, et al. Chemical Engineering Journal, 2019, 361, 99.
57 Guo R, Meng Q, Zhuang H, et al. Chemical Engineering Journal, 2019, 355, 953.
58 Xu X, Feng Y, Zhen Z, et al. Separation and Purification Technology, 2020, 251, 117351.
59 Du X, Zhang Y, Si F, et al. Chemical Engineering Journal, 2019, 356, 178.
60 Deng J, Lu Y A, Ma X Y. Journal of China University of Mining & Technology, 2015, 44(6), 1126 (in Chinese).
邓婧, 卢遇安, 马晓雁. 中国矿业大学学报, 2015, 44(6), 1126.
61 Liu Y, Guo H, Zhang Y, et al. Environmental Pollution, 2019, 252, 1042.
62 Wu C, Yang M, Lin K. Journal of Environmental Chemical Engineering, 2018, 6, 426.
63 Li X J, Liao F Z, Ye L M, et al. Chemical Industry and Engineering Progress, 2019, 38(10), 4712 (in Chinese).
李小娟, 廖凤珍, 叶兰妹, 等. 化工进展, 2019, 38(10), 4712.
64 Bhattacharjee S, Lee Y R, Puthiaraj P, et al. Catalysis Surveys from Asia, 2015, 19(4), 203.
65 Li H X, Yang Z X, Lu S, et al. Chemosphere, 2021, 273, 129643.
66 Xian G, Kong S, Li Q, et al. Frontiers in Chemistry, 2020, 8, 177.
67 Deng J, Xu M, Qiu C, et al. Applied Surface Science, 2018, 459, 138.
68 Yan J, Lei M, Zhu L, et al. Journal of Hazardous Materials, 2011, 186, 1398.
69 Liu Y Q, Su B Q, Tao Y, et al. Chinese Journal of Environmental Engineering, 2020, 14(9), 2515 (in Chinese).
刘一清, 苏冰琴, 陶艳, 等. 环境工程学报, 2020, 14(9), 2515.
70 Keyikoglu R, Karatas O, Khataee A, et al. Separation and Purification Technology, 2020, 247, 116925.
71 Karimipourfard D, Eslamloueyan R, Mehranbod N. Journal of Environmental Chemical Engineering, 2020, 8, 103426.
72 Zhang T, Zhu H, Croue J, et al. Environmental Science & Technology, 2013, 47, 2784.
73 Qin W, Fang G, Wang Y, et al. Chemical Engineering Journal, 2018, 348, 526.
74 Li J, Ren L, Ji F, et al. Chemical Engineering Journal, 2017, 324, 63.
75 Zhao Y, Song M, Cao Q, et al. Journal of Hazardous Materials, 2020, 400, 122887.
76 Lyu J, Ge M, Hu Z, et al. Chemical Engineering Journal, 2019, 389, 124456.
77 Balakrishnan R M, Ilango I, Gamana G, et al. Journal of Water Process Engineering, 2020, 40, 101823.
78 Deng J, Xu M Y, Qiu C G, et al. Applied Surface Science, 2018, 459, 138.
79 Chen Y Q, Li M Y, Tong Y, et al. Chemical Engineering Journal, 2019, 368, 495.
80 Cai C, Liu J, Zhang Z Y, et al. Separation and Purification Technology, 2016, 165, 42.