用于盐湖卤水镁锂分离的纳滤技术研究进展

doi:10.11896/cldb.201903006

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Abstract As an energy metal that “pushes the world forward”, lithium plays a significant role in the development of the national economy. Currently, there has been consistent growth in demand for lithium resources of various industries like glass, electrical appliances and pharmaceuticals, etc. Hence, it is of great importance in extraction and storage of lithium resources. Compared with the traditional method of extracting lithium from ores, extracting lithium from salt lake brine show notable superiority, because it is free for large amount of chemical input, and economical with substantially reduced cost, which makes it become a primary way for achieving lithium resources. Unfortunately, lithium and magnesium exist as a symbiosis in the salt lake brine, and the chemical properties of magnesium and lithium are similar with small difference in their ionic hydration radius. As a result, the problem of separating magnesium and lithium must be figure out first, in order to achieve high-efficiency lithium extraction from salt lakes. Presently, there are many ways for separating magnesium and lithium from salt lake. Nevertheless, these methods still suffer from large energy consumption, low economic benefit, environmental unfriendliness, and unfriendly unavailability for high magnesium-lithium ratio salt lake.
Nanofiltration (NF) is a pressure-driven membrane separation technique between ultrafiltration and reverse osmosis. Thanks to the special pore size range and charge properties of nanofiltration membranes, monovalent, divalent and multivalent ions can be separate effectively. Consequently, nanofiltration technique has become an emerging method for magnesium and lithium separation, and shows remarkable advantage in the field of separation of magnesium and lithium in brine of salt lake, which is regarded as an important research direction by researchers at home and abroad.
Research results show that the separation mechanism of NF membrane mainly includes electrostatic repulsion and steric resistance. In addition to the impact of solute size and pore size, the charge properties of the membrane surface exert a great effect on the separation of solute. Currently, the commercial NF membranes that have been mostly employed for magnesium and lithium separation are negative charged membranes. As the difference in ionic hydration radius of magnesium and lithium is not obvious, the steric hindrance effect plays a minor role in the separation process, and the separation of magnesium-lithium by membrane is mainly realized by electrostatic exclusion. In recent years, researchers have verified that positive charged NF membrane presents excellent performance in selective separation of Mg²⁺ and Li⁺. According to the electrostatic repulsive effect, high valence cations (Mg²⁺) own a higher positive charge than low valence (Li⁺), leading to a stronger exclusion between high valence cations and positive charged NF membrane and resulting in a stronger rejection to Mg²⁺ than Li⁺.
From the point of view of the distribution and extraction of lithium resources in salt lake, this article summarizes various methods for magnesium and lithium separation from brine. Based on the structure and mechanism of nanofiltration membrane, the relevant characteristics of nanofiltration membrane are analyzed and summarized comprehensively, and the application status and existing problems of magnesium and lithium separation by nanofiltration are reviewed. In view of the special structure and distribution of magnesium and lithium in salt lake brine in China, the prospect of nanofiltration technology applied to the separation of magnesia and lithium in salt lake is proposed.

Key words： salt lake brine lithium resources separation of magnesium and lithium nanofiltration membrane separation

Published: 13 February 2019

CLC number:

TQ131.11

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	Articles by authors
	XU Ping
	QIAN Xiaoming
	GUO Changsheng
	XU Zhiwei
	ZHAO Lihuan
	MAI Wei
	LI Jing
	TIAN Xu
	DUO Yongchao

Cite this article:

XU Ping,QIAN Xiaoming,GUO Changsheng, et al. Nanofiltration Technology Used for Separation of Magnesium and Lithium from Salt Lake Brine:a Survey[J]. Materials Reports, 2019, 33(3): 410-417.

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http://www.mater-rep.com/EN/10.11896/cldb.201903006 OR http://www.mater-rep.com/EN/Y2019/V33/I3/410

1 Kesler S E, Gruber P W, Medina P A, et al. Ore Geology Reviews,2012,48(5),55.
2 Wu Q, Liu X F, Zheng M P, et al. Modern Chemical Industry,2017(5),1(in Chinese).
伍倩,刘喜方,郑绵平,等.现代化工,2017(5),1.
3 Araoka D. Japanese Magazine of Mineralogical & Petrological Sciences,2015,44(5),259.
4 Wu D F, Sun S Y, Yu J G. CIESC Journal,2018,69(1),141(in Chinese).
吴东帆,孙淑英,于建国.化工学报,2018,69(1),141.
5 Swain B. Separation & Purification Technology,2016,172,388.
6 Christmann P, Gloaguen E, Labbé J F, et al. In: Lithium Process Che-mistry, Elsevier, Netherlands,2015,pp.1.
7 Sun X, Hao H, Zhao F, et al. Environmental Science & Technology,2018,52(5),2827.
8 Cai Y L, Li J W. Acta Geoscientica Sinica,2017,38(1),25(in Chinese).
蔡艳龙,李建武.地球学报,2017,38(1),25.
9 Zheng M P, Zhang Y S, Liu X F, et al. Acta Geoscientica Sinica,2016,90(9),2123(in Chinese).
郑绵平,张永生,刘喜方,等.地质学报,2016,90(9),2123.
10 Li S Y, Kang L W, Liu J J, et al. Guangdong Chemical Industry,2016,43(24),81(in Chinese).
李神勇,康莲薇,刘建军,等.广东化工,2016,43(24),81.
11 Gao F, Zheng M P, Nie Z, et al. Acta Geoscientica Sinica,2011,32(4),483(in Chinese).
高峰,郑绵平,乜贞,等.地球学报,2011,32(4),483.
12 Yu J J, Zheng M P, Wu Q. Chemical Industry and Engineering Progress,2013,32(1),13(in Chinese).
余疆江,郑绵平,伍倩.化工进展,2013,32(1),13.
13 Liu Z, Zhou Y F, Chai D P, et al. Materials Review,2015(z2),1(in Chinese).
刘卓,周云峰,柴登鹏,等.材料导报,2015(z2),1.
14 Nie Z, Bu L Z, Wang Y S, et al. Inorganic Chemicals Industry,2013,45(5),1(in Chinese).
乜贞,卜令忠,王云生,等.无机盐工业,2013,45(5),1.
15 Fu Y, Zhong H. Multipurpose Utilization of Mineral Resources,2010(2),30(in Chinese).
付烨,钟辉.矿产综合利用,2010(2),30.
16 Zhao X, Zhang Q, Wu H H, et al. Chemical Industry and Engineering Progress,2017(7),796(in Chinese).
赵旭,张琦,武海虹,等.化学进展,2017(7),796.
17 Yu C, Gan Y X. Xinjiang Non-ferrous Metals,2007,30(A01),100(in Chinese).
于超,甘玉霞.新疆有色金属,2007,30(A01),100.
18 Zhao D, Du X M, Wang S Q, et al. Journal of Salt Science and Chemical Industry,2017,46(6),40(in Chinese).
赵冬,杜雪敏,王士强,等.盐业与化工,2017,46(6),40.
19 Zhang Z. The separation of lithium and magnesium and the preparation of magnesium hydroxide flame retardant use the calcined magnesium slag from salt lake. Master’s thesis, Chengdu University of Technology, China,2009(in Chinese).
张珍.盐湖煅烧镁渣锂镁分离及新型氢氧化镁阻燃剂的研究.硕士学位论文,成都理工大学,2009.
20 Yin H J, Deng T L, Li D C. Inorganic Chemicals Industry,2009,41(5),1(in Chinese).
尹红军,邓天龙,李栋婵.无机盐工业,2009,41(5),1.
21 Zhu H F, Gao J, Guo Y F, et al. Guangdong Trace Elements Science,2010,17(11),25(in Chinese).
朱华芳,高洁,郭亚飞,等.广东微量元素科学,2010,17(11),25.
22 Liu Y H, Deng T L. World Sci-Tech R&D,2006,28(5),69(in Chinese).
刘元会,邓天龙.世界科技研究与发展,2006,28(5),69.
23 Zhou Z, Liang S, Qin W, et al. Industrial & Engineering Chemistry Research,2013,52(23),7912.
24 Zhang L H, Yang Z P, Li C Z, et al. Inorganic Chemicals Industry,2016,48(12),52(in Chinese).
张黎辉,杨志平,李存增,等.无机盐工业,2016,48(12),52.
25 Ji Z Y, Huang Z H, Yuan J S, et al. Materials Review B: Research Papers,2017,31(6),131(in Chinese).
纪志永,黄智辉,袁俊生,等.材料导报:研究篇,2017,31(6),131.
26 Wang L, Zhang X, Ma L B, et al. Journal of Salt Science and Chemical Industry,2018,47(4),8(in Chinese).
王亮,张欣,马来波,等.盐科学与化工,2018,47(4),8.
27 Zhong H. Journal of Mineralogy and Petrology,1991(4),105(in Chinese).
钟辉.矿物岩石,1991(4),105.
28 Chen Q B, Ji Z Y, Liu J, et al. Journal of Membrane Science,2017,548,408.
29 Liao H R, Xu H, Li G, et al. Materials Review B: Research Papers,2015,29(2),90(in Chinese).
廖浩然,徐徽,李贵,等.材料导报:研究篇,2015,29(2),90.
30 Nie X Y, Sun S Y, Sun Z, et al. Desalination,2016,403,128.
31 Ji Z Y, Chen Q B, Yuan J S, et al. Separation & Purification Technology,2017,172,168.
32 Ball D L, Boateng D A D. US. patent application, US4636295,1987.
33 Song W D, Wang H Z, Xing K, et al. Journal of Salt Lake Research,2006,14(4),56(in Chinese).
宋卫得,王海增,邢坤,等.盐湖研究,2006,14(4),56.
34 Rautenbach R, Groschl A. Desalination,1990,77(1-3),73.
35 Li X, Zhang Z G, Ren X J, et al. Chemical Industry and Engineering Progress,2014,33(5),1210(in Chinese).
李祥,张忠国,任晓晶,等.化工进展,2014,33(5),1210.
36 Labban O, Liu C, Chong T H, et al. Journal of Membrane Science,2017,521,18.
37 Yang Y, Li X, Shen L, et al. RSC Advances,2017,7(29),18001.
38 Marchetti P, Solomon M F J, Szekely G, et al. Chemical Reviews,2014,114(21),10735.
39 Donnan F G. Journal of Membrane Science,1995,100(1),45.
40 Xu Z L, Tang Y J, Zhou B W, et al. Technology of Water Treatment,2015(12),3(in Chinese).
许振良,汤永健,周秉武,等.水处理技术,2015(12),3.
41 Ernst M, Bismarck A, Spinger J, et al. Journal of Membrane Science,2000,165(2),251.
42 Werber J R, Osuji C O, Elimelech M. Nature Reviews Materials,2016,1(5),16018.
43 Wang X L, Tu C H, Fang Y Y, et al. Membrane Science and Technology,2011,31(3),127(in Chinese).
王晓琳,涂丛慧,方彦彦,等.膜科学与技术,2011,31(3),127.
44 He Q X, Liu J Q, Yan G C, et al. Industrial Water Treatment,2010,30(7),22(in Chinese).
何启贤,刘久清,颜果春,等.工业水处理,2010,30(7),22.
45 Machado D R, Hasson D, Semiat R. Journal of Membrane Science,1999,166(1),63.
46 Chen X, Gu J H. Membrane Science and Technology,2013,33(3),108(in Chinese).
陈雪,谷景华.膜科学与技术,2013,33(3),108.
47 Qi M. Study on preparation and separation performance of cellulose acetate hollow fiber nanofiltration membrane. Master’s thesis, Zhejiang Sci-Tech University,China,2011(in Chinese).
祁明.醋酸纤维素中空纤维纳滤膜的制备与分离性能研究.硕士学位论文,浙江理工大学,2011.
48 Wen P. Preparation and characterization of graphene modified polyamide composite nanofiltration membrane. Master’s thesis, Tianjin Polytechnic University,China,2017(in Chinese).
文鹏.氧化石墨烯改性聚酰胺复合纳滤膜的制备及其性能表征.硕士学位论文,天津工业大学,2017.
49 Chen K K, Zhai D, Zhou Y, et al. Technology of Water Treatment,2014(2),42(in Chinese).
陈可可,翟丁,周勇,等.水处理技术,2014(2),42.
50 Song Y F. Study on performance of polyvinylidene fluoride tubular nanofiltration membrane. Master’s thesis, Tianjin Polytechnic University,China,2014(in Chinese).
宋云飞.聚偏氟乙烯管式纳滤膜性能研究.硕士学位论文,天津工业大学,2014.
51 Akbari A, Solymani H, Rostami S M M. Journal of Applied Polymer Science,2015,132(22),235.
52 Huang R, Chen G, Sun M, et al. Carbohydrate Research,2006,341(17),2777.
53 Jiang D, Qin D L, Xu Y F, et al. Applied Chemical Industry,2017,46(2),254(in Chinese).
姜迪,秦冬玲,徐异峰,等.应用化工,2017,46(2),254.
54 Liu S, Fang F, Wu J, et al. Desalination,2015,375(2),121.
55 Castricum H L, Sah A, Geenevasen J A J, et al. Journal of Sol-Gel Science and Technology,2008,48(1-2),11.
56 Ahmad J, Deshmukh K, Habib M, et al. Arabian Journal for Science & Engineering,2014,39(10),6805.
57 Vatanpour V, Madaeni S S, Khataee A R, et al. Desalination,2012,292(9),19.
58 Cot L, Ayral A, Durand J, et al. Solid State Sciences,2000,2(3),313.
59 Sharp K G. Advanced Materials,1998,10(15),1243.
60 Lacan P, Guizard C, Gall P L, et al. Journal of Membrane Science,1995,100(100),99.
61 Yu L Y, Xu Z L, Shen H M, et al. Journal of Membrane Science,2009,337(1),257.
62 Li X P, Hu X Y, Zhang Y F, et al. New Chemical Materials,2015(7),227(in Chinese).
李希鹏,胡晓宇,张宇峰,等.化工新型材料,2015(7),227.
63 Li Z K, Zhou Y, Zhu J M, et al. Technology of Water Treatment,2009,35(12),1(in Chinese).
李兆魁,周勇,朱家民,等.水处理技术,2009,35(12),1.
64 Zhu W P, Sun S P, Gao J, et al. Journal of Membrane Science,2014,456(8),117.
65 Wang H, Cui M B, Yan D D, et al. Materials Review B: Research Papers,2018,32(2),555(in Chinese).
王辉,崔梦冰,闫冬冬,等.材料导报:研究篇,2018,32(2),555.
66 Li H L, Tan L Y, Zhang H Q, et al. New Chemical Materials,2009,37(11),42(in Chinese).
李惠玲,谭翎燕,张浩勤,等.化工新型材料,2009,37(11),42.
67 Cheng X Q, Zhang Y L, Wang Z X, et al. DOI:10.1016/j.desal.2014.10.043.
68 Zinadini S, Zinatizadeh A A L, Rahimi M, et al. Journal of Industrial & Engineering Chemistry,2016,46,9.
69 Feng C, Xu J, Li M, et al. Journal of Membrane Science,2014,451(2),103.
70 Decher G, Hong J D. Macromolecular Symposia,1991,46(1),321.
71 Jimenez-Solomon M F, Song Q, Jelfs K E, et al. Nature Materials,2016,15(7),760.
72 Huan G L, Zhang Y F, Du Q Y, et al. Journal of Tianjin Polytechnic University,2003,22(1),47(in Chinese).
环国兰,张宇峰,杜启云,等.天津工业大学学报,2003,22(1),47.
73 Dong Y, Su Y, Ju W, et al. Desalination,2014,333(1),59.
74 Mohammad A W, Teow Y H, Ang W L, et al. Desalination,2015,356,226.
75 Wen X, Ma P, Zhu C, et al. Separation & Purification Technology,2006,49(3),230.
76 Yang G, Shi H, Liu W, et al. Chinese Journal of Chemical Engineering,2011,19(4),586.
77 Somrani A, Hamzaoui A H, Pontie M. Desalination,2013,317(7),184.
78 Kang W Q, Shi L J, Zhao Y J, et al. Inorganic Chemicals Industry,2014,46(12),22(in Chinese).
康为清,时历杰,赵有璟,等.无机盐工业,2014,46(12),22.
79 Bi Q, Zhang Z, Zhao C, et al. Water Science & Technology,2014,70(10),1690.
80 Shi H, Qi M F, Yang G, et al. In: National Chemical Engineering and Biochemical Industry Annual Conference. Changsha,2010,pp.1.
史宏,戚茂飞,杨刚,等.全国化学工程与生物化工年会.长沙,2010,1.
81 Ji C. Study on separation of magnesium and lithium by nanofiltration. Master’s thesis, East China University of Science and Technology, China,2014(in Chinese).
计超.纳滤分离镁锂过程研究.硕士学位论文,华东理工大学,2014.
82 Kang W Q. Study on separation of magnesium and lithium in saline lake brine by nanofiltration. Master’s thesis, Qinghai Institute of Salt Lakes, Chinese Academy of Science, China,2014(in Chinese).
康为清.纳滤法应用于盐湖卤水镁锂分离的研究.硕士学位论文,中国科学院研究生院(青海盐湖研究所),2014.
83 Sun S Y, Cai L J, Nie X Y, et al. Journal of Water Process Engineering,2015,7,210.
84 Xing H, Wang X H, Mao X Y. Journal of Salt and Chemical Industry,2016,45(1),24(in Chinese).
邢红,王肖虎,毛新宇.盐业与化工,2016,45(1),24.
85 Lau W J, Ismail A F, Goh P S, et al. Separation & Purification Reviews,2015,44(2),135.
86 Li X, Zhang C, Zhang S, et al. Desalination,2015,369,26.
87 Li W, Shi C, Zhou A, et al. Separation & Purification Technology,2017,186,233.