微波诱导催化反应在环境净化中的应用研究进展

doi:10.11896/cldb.20100163

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Abstract Catalytic purification has been developed to be a main technology involving with the removal of environmental pollutants. Microwave (MW) radiation with excellent performances of volatility, high frequency, thermal and non-thermal characteristics has caused widely attention. Therefore, MW-induced catalytic reactions play a vital role in improving environmental quality. With the continuous in-depth research of MW radiation and catalytic technology, the development of multifunctional materials with excellent MW absorbing performance and catalytic activity has become the focus of studies.
According to the way of transforming the MW, wave-absorbing materials can be divided into three types, including dielectric loss, resistance loss and magnetic loss.The absorbing performance of the wave-absorbing materials is affected by various factors such as element composition, surface configuration and pore structure. In recent years, researchers have been improving the synthetic methods of wave-absorbing materials from the matching and attenuation characteristics, and have achieved substantial progress in enhancing the MW absorbing properties of mate-rials, and making full use of MW-induced catalytic reactions to improve the energy utilization rate as well as the degradation rate of environmental pollutants.
Wave-absorbing materials will produce hot spot effect and discharge effect in the MW field. The MW-induced catalytic reaction changes the conventional thermal field to MW heating, which can realize the rapid temperature rise of the material at a lower environment temperature and achieve excellent catalytic performance. Metal materials can induce MW discharge in the MW field, and the discharge process will produce thermal effect, plasma effect and photocatalytic effect, which plays a crucial role in pollutant removal. However, since the reaction process of MW-induced cata-lysis is complicated, current studies have focused on distinguishing the influence of heat spot effect and discharge effect and clarifying the reaction pathway of MW-induced catalysis. Over the past years, a variety of catalysis with outstanding wave-absorbing and catalytic performances has been developed, and applied the MW-induced catalytic reaction to the purification treatment technology of waste water and exhaust gas, which has the advantages of fast reaction rate and high treatment efficiency.
This paper mainly introduces the principle of MW absorption of materials, expounds the improvement of MW absorption properties of materials and the application of MW hot spot effect and discharge effect in pollutant removal, and discusses the future development direction of MW-induced catalytic reactions.

Key words： catalytic microwave hot spot effect discharge plasma wave-absorbing material environment

Received: 25 September 2022 Published: 25 September 2022 Online: 2022-09-26

CLC number:	X505
	TB34

Fund:The National Natural Science Foundation of China (21876010).

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	Articles by authors
	LYU Xiujuan
	TANG Xiaolong
	YI Honghong
	ZHAO Shunzheng
	REN Chenyang

Cite this article:

LYU Xiujuan,TANG Xiaolong,YI Honghong, et al. Applying Microwave-induced Catalytic Reaction to Environmental Purification: a Review[J]. Materials Reports, 2022, 36(18): 20100163-9.

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http://www.mater-rep.com/EN/10.11896/cldb.20100163 OR http://www.mater-rep.com/EN/Y2022/V36/I18/20100163

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