合金元素在Al基牺牲阳极中的作用机理

doi:10.11896/cldb.20090294

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Abstract Aluminum alloys, with large capacity and high current efficiency, have great potential to serve as ideal sacrificial anodes. However, the compact passive film easily formed on the surface of aluminum has serious impact on the efficiency of aluminum-based sacrificial anodes. Alloy elements can achieve de-passivation, promote the active dissolution of aluminum matrix and increase the discharge quantity of aluminum-based sacrificial anodes. Thus, the activation mechanisms of alloy elements on aluminum-based sacrificial anodes have been extensively and in-depth investigated. The main activation mechanisms include: (i) the dissolution-redeposition effect; (ii) the adsorption theory of surface free energy; (iii) the mechanism of preferential dissolution of the second phases; (iv) the reduction of ion resistance theory; (v) the negative shifts of potential mechanism; (vi) the uncommon valency theory, et al. The activation mechanisms mentioned above are almost focused on the integrity destruction of oxide films via mechanical detachment or the defection formation of Al₂O₃ oxide film by producing cation vacancy. At present, the common activating elements include Hg, In, Sn, Ga, Zn, Mg, Mn, Ti, Zr, Cd, Si, Fe, Bi, Cu, rare earth (RE) elements, etc.
Activation mechanisms of alloy elements in the activation process of aluminum-based sacrificial anodes are very complicated. Besides, there are synergistic effects between these alloy elements in the activation process, and activation mechanisms have not been clarified in details, yet. Therefore, by consulting the previous researches, activation mechanisms and effects of alloy elements on the aluminum-based sacrificial anodes were sorted out. This paper is expected to be helpful to understand action mechanisms of alloy elements further and more comprehensively, and provides perspective for the design of aluminum-based sacrificial anodes with much more excellent performances.

Key words： aluminum alloy sacrificial anode alloy element activation mechanism

Published: 10 September 2022 Online: 2022-09-10

CLC number:

TB304

Fund:National Natural Science Foundation of China (51601137,51601138).

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	PENG Jingjing
	LIU Jing
	ZHANG Xian
	CHENG Lin
	WU Kaiming
	ZHANG Tao

Cite this article:

PENG Jingjing,LIU Jing,ZHANG Xian, et al. Activation Mechanisms of Alloy Elements on Aluminum-based Sacrificial Anodes[J]. Materials Reports, 2022, 36(17): 20090294-8.

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http://www.mater-rep.com/EN/10.11896/cldb.20090294 OR http://www.mater-rep.com/EN/Y2022/V36/I17/20090294

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