有机硫水解催化剂研究进展

doi:10.11896/cldb.20080196

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (5286KB)
Export: BibTeX | EndNote (RIS)

Abstract Organic sulfur is the key and difficult point in the purification of coke oven gas, natural gas, yellow phosphorus tail gas, synthetic ammonia and other gases, among which COS and CS₂ account for the main part. Catalytic hydrolysis is considered to be one of the most effective ways to purify organic sulfur in industrial gases, which is a low-cost and high-efficiency purification technology. COS and CS₂ can be converted to H₂S by catalytic hydrolysis at lower temperature, and H₂S can be then removed efficiently. There are two major advantages for refined desulfurization by catalytic hydrolysis: (i) high conversion rate, low reaction temperature, and no hydrogen source consumption; (ii) mature purification process of the hydrolysate H₂S, which can be used for the recovery of sulfur resources.
Catalytic hydrolysis has been well studied and applied in industry, but the oxidation reaction in the hydrolysis process is an important reason for the reduction of the efficiency and life of the hydrolysis catalyst. Therefore, the development of cheap and efficient hydrolysis catalysts has become a research hotspot in this field. Moreover, high selectivity of H₂S is a core indicator of organic sulfur hydrolysis catalysis.
The hydrolysis catalysts prepared with γ-Al₂O₃ and activated carbon as support are the catalysts with a better application effect at present. Besides, the application of γ-Al₂O₃ is the earliest and most extensive, but its poor antioxidant capacity and catalyst poisoning characteristics make it limited in the application process. Supports such as TiO₂ and ZrO₂ have been followed with interest in recent years, and the addition of different active components provides the possibility to break through the low selectivity of H₂S and anti-toxicity. In addition, the study on the mechanism of organic sulfur hydrolysis also provides a theoretical basis for the development of hydrolytic catalysts. On this basis, the activity and life of organic sulfur hydrolysis catalysts can be improved by adjusting the reaction path and improving influencing factors in the hydrolysis process.
This review introduces the research and application of the main supports and active components on COS and CS₂ catalytic hydrolysis. The hydrolysis mechanism of organic sulfur and hydrolysis catalyst deactivation reason has also been summarized, and the problems faced and future prospect of the catalytic hydrolysis method are analyzed. It is hoped that this paper can provide reference for the design of new high efficiency hydrolytic catalytic materials.

Key words： organic sulfur catalytic hydrolysis catalyst hydrolysis mechanism deactivation

Published: 10 September 2022 Online: 2022-09-10

CLC number:

X511

Fund:National Natural Science Foundation of China(21876071, 51868030), and Science and Technology Program of Science and Technology Department of Yunnan Province (2019FD043).

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	WANG Mingfei
	CHEN Peng
	TAO Lei
	XUE Yu
	LIU Jingye
	WANG Xueqian
	MA Yixing
	WANG Langlang
	LI Jiaqi

Cite this article:

WANG Mingfei,CHEN Peng,TAO Lei, et al. Research Progress of Organic Sulfur Hydrolysis Catalyst[J]. Materials Reports, 2022, 36(17): 20080196-9.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.20080196 OR http://www.mater-rep.com/EN/Y2022/V36/I17/20080196

1 Vaidya P D, Kenig E Y. Chemical Engineering Journal, 2009, 148(2), 207.
2 Ryzhikov A, Hulea V, Tichit D, et al. Applied Catalysis A-general, 2011, 397(1), 218.
3 Coffey M T, Hannigan J W. Journal of Atmospheric Chemistry, 2010, 67(1),61.
4 Wang Y J. Removal of low concentration carbonyl sulfur and carbon disulfide by adsorption method. Master's Thesis, Dalian University of Techno-logy, China, 2013 (in Chinese).
艳君. 吸附法脱除二氧化碳中低浓度羰基硫和二硫化碳的研究. 硕士论文, 大连理工大学, 2013.
5 Li C, Zhang T, Li J Q, et al. Applied Chemical Industry, 2015 (5), 927 (in Chinese).
李从, 张婷, 李俊青, 等.应用化工, 2015 (5), 927.
6 Chen Z H, Shang G J, Zhang L, et al. Modern Chemical Industry, 2011, 31(Z1), 244 (in Chinese).
陈兆辉, 上官炬, 张立, 等. 现代化工, 2011, 31(Z1), 244.
7 Wang G, Sun T H, Zhang H B, et al. Modern Chemical Industry, 2014, 34(1), 60 (in Chinese).
王冠, 孙同华, 张宏波, 等.现代化工, 2014, 34(1),60.
8 Sun W T. Study on preparation process of co-modifier modified cobalt-molybdenum hydrodesulfurization catalyst. Master's Thesis, Qingdao University of Science and Technology, China, 2016 (in Chinese).
孙万堂. 助剂改性钴钼加氢脱硫催化剂制备过程研究. 硕士学位论文, 青岛科技大学, 2016.
9 Yang C, Lai J L, Luo G X. Contemporary Chemical Industry, 2015, (10), 2352 (in Chinese).
杨晨, 赖君玲, 罗根祥.当代化工, 2015, (10), 2352.
10 Zhang X D, Yi H H, Tang X L, et al. New Chemical Materials, 2020, 48(5), 266 (in Chinese).
张晓东, 易红宏, 唐晓龙, 等.化工新型材料, 2020, 48(5), 266.
11 Huang H, Young N, Williams B P, et al. Catalysis Letters, 2006, 110(3-4), 243.
12 He E, Huang G, Fan H, et al. Fuel, 2019, 246(2),77.
13 Fiedorow R, Laut R, Lanai G D. Journal of Catalysis, 1984, 85(2), 339.
14 Nimthuphariyha K, Usmani A, Grisdanurak N, et al. Chemical Enginee-ring Communications, 2021, 208(4), 539.
15 Liu B N, Gao H, Zhang J, et al. Industrial Catalysis, 2019, 27(7), 39 (in Chinese).
刘博男, 高辉, 张晋, 等.工业催化, 2019,27(7), 39.
16 Ma T K, Kong X H, Fang J G, et al. Environmental Engineering. 2019, 37(6) (in Chinese).
马腾坤, 房晶瑞, 孟刘邦, 等. 环境工程, 2019, 37(6), 1.
17 Liu J, Yang X Y, Pang L. Molecular Catalysis, 1993(6), 20 (in Chinese).
刘佳, 杨锡尧, 庞礼.分子催化, 1993(6), 20.
18 Ding Y B. Energy Saving from Petroleum and Petrochemicals, 2014, 4(1), 26 (in Chinese).
丁延彬.石油石化节能, 2014, 4(1), 26.
19 Liu Y X, Shangguan J, Wang Z X, et al. Chemical Industry and Engineering Progress, 2018, 37(10), 3885 (in Chinese).
刘艳霞, 上官炬, 王泽鑫, 等.化工进展, 2018, 37(10), 3885.
20 Sui R, Lavery C B, Li D, et al. Applied Catalysis B: Environmental, 2018, 241,217.
21 Gao Z, Hua W M, Zhao X P, et al. Applied Catalysis B: Environmental, 2003, 46(3), 561.
22 Aboulayt A, Maug F, Hoggan P E, et al. Catalysis Letters, 1996, 39(3-4), 213.
23 Yue Y, Zhao X, Hua W, et al. Applied Catalysis B: Environmental, 2003, 46(3), 561.
24 Su J J, Luo P. Nitrogenous Fertilizer Technology, 2021, 42(1), 1 (in Chinese).
苏君健,罗平.氮肥技术,2021,42(1),1.
25 Liu Q, Ke M, Yu P, et al. Petrochemical Technology, 2016, 45(5), 552.
26 Dan H E, H H Yi, Tang X, et al. Journal of Rare Earths, 2010, 28(1), 343.
27 Yi H, Yu L, Tang X, et al. Journal of Central South University of Technology, 2010, 17(5), 985.
28 Li K. Development and mechanism of catalysts for hydrolysis of COS and CS₂. Master's Thesis, Kunming University of Science and Technology, China, 2013 (in Chinese).
李凯. COS、CS₂水解催化剂的开发及机理研究.硕士学位论文, 昆明理工大学, 2013.
29 Sun X, Ning P, Tang X, et al. Journal of Energy Chemistry, 2014, 23(2), 221.
30 He F, Liu N, Xie J L, et al. Bulletin of the Chinese Ceramic Society, 2017, 36(5), 1464 (in Chinese).
何峰, 刘纳, 谢峻林, 等.硅酸盐通报, 2017,36(5),1464.
31 Wang Y S. Research on green surfactant modified cordierite catalyst for SCO denitration performance. Master's Thesis, Xi'an University of Science and Technology, 2019 (in Chinese).
王禹苏. 绿色表面活性剂改性堇青石催化剂的制备及其在SCO脱硝中的机理研究. 硕士学位论文, 西安科技大学, 2019.
32 Yan M, Xiao Z B, Zhang Y Q, et al. Journal of East China University of Science and Technology, 2016,45 (5), 130 (in Chinese).
严明佳, 肖忠斌, 张益群, 等.华东理工大学学报, 2016,45 (5), 130.
33 Deng C, Xie H F, Cheng F. Molecular Catalysis, 2009, 23(4), 351 (in Chinese).
邓存, 谢鸿芳, 陈峰. 分子催化, 2009, 23(4), 351.
34 Wang W, Xu Z, Guo Z, et al. Chinese Journal of Catalysis, 2015, 36(2), 139.
35 Liu J, Yu L, Zhang Y. Desalination, 2014, 335(1), 78.
36 Zhang S, Yi H, Tang X, et al. Chemical Engineering Journal, 2013, 226(4), 161.
37 Zhang S, Yi H, Tang X, et al. Catalysis Today, 2019, 327, 161.
38 Li Q, Yi H H, Tang L X, et al. Chemical Engineering Journal, 2016, 284, 103.
39 Wang H, Yi H, Tang X, et al. Applied Clay Science, 2012, 70, 8.
40 Zhao S Z, Yi H H, et al. Journal of Rare Earths, 2010, S1, 329.
41 Wei Z, Zhang X, Zhang F L, et al. Environmental Science, 2019, 40(10), 4423 (in Chinese).
魏征, 张鑫, 张凤莲, 等.环境科学, 2019, 40(10), 4423.
42 Guo H, Tang L, Li K, et al. RSC Advances, 2015,5(26), 20530.
43 Kloprogge J T, Hickey L, Frost R L. Materials Chemistry & Physics, 2005,89(1), 99.
44 Kloprogge J T, Hickey L, Frost R L. Journal of Solid State Chemistry, 2004, 177(11), 4047.
45 Wang Q, Wu Z H, Hang H, et al. Catalysis Today, 2011, 164(1), 198.
46 Labajos F M, Rives V, Malet P, et al. American Chemical Society, 1996, 27(23), 1154.
47 Zhang G G, Li W F, Xie K Y, et al. Advanced Functional Materials, 2013, 23(29), 3675.
48 Zhao S Z. Microstructure design and experimental study of Nickel-based COS-depth purification materials. Master's Thesis, University of Science and Technology Beijing, China, 2016 (in Chinese).
赵顺征. 镍基COS深度净化材料的微观构型设计与实验研究. 硕士学位论文, 北京科技大学, 2016.
49 Ramasamy K K, Gray M, Job H, et al. Topics in Catalysis, 2016, 59(1), 46.
50 Yi H H, Zhao S Z, et al. Catalysis Communications, 2011, 12(15), 1492.
51 Schoedel L A, Li M, Li D, et al. Chemical Reviews, 2016, 116(19), 12466.
52 Lee S, Kapustin E A, Yaghi O M. Science, 2016, 353(6301), 808.
53 Zhao X, Yue Y, Ying Z, et al. Catalysis Letters, 2003, 89(1-2), 41.
54 Zhao S S, Ma J F, Liu Y Y, et al. Inorganic Chemistry, 2016, 55(5), 2261.
55 Shen L, Wang G, Zheng X, et al. Chinese Journal of Catalysis, 2017, 38(8), 1373.
56 Qiu C, Xu Y, Fan X, et al. Advanced Science, 2019, 6(1), 12466.
57 Su F, Antonietti M, Wang X. Catalysis Science & Technology, 2012, 2(5), 1005.
58 Guo F, Li S, Hou Y, et al. Chemical Communications, 2019, 55(75), 11259.
59 Tang S, Li C, Liang S, et al. Catalysis Letters, 1991, 8(2-4), 155.
60 Church J S, Cant N W, Trimm D L. Applied Catalysis A General, 1993, 101(1), 105.
61 Lai J J, Lai X C, Liu Y, et al. Journal of Petrochemical Universities, 2017, 30(5), 12 (in Chinese).
赖君玲, 赖晓晨, 柳叶, 等. 石油化工高等学校学报, 2017, 30(5), 12.
62 Rhodes C, Riddel S A, West J, et al. Catalysis Today, 2000, 59(3), 443.
63 Qiu J, Ning P, Wang X Q, et al. Frontiers of Environmental Science & Engineering, 2016, 10(1), 11.
64 Li Q, Yi H H, Tang X L, et al. Chemical Engineering Journal, 2016, 284(103),28.
65 Ning P, Yu L L, Yi H H, et al. Journal of Rare Earths, 2010, 28(2), 205.
66 Huang H, Young N, Williams B P, et al. Catalysis Letters, 2005, 104(1-2), 17.
67 Song X. Study on the simultaneous hydrolysis of COS and CS₂ and the reaction mechanism of walnut shell based catalyst. Master's Thesis, Kunming University of Science and Technology, China, 2018 (in Chinese).
宋辛. 核桃壳基催化剂同时催化水解 COS 和 CS₂及反应机理研. 硕士学位论文, 昆明理工大学, 2018.
68 Zhu L. Study on denitration performance and mechanism of transition me-tal oxides over low temperature SCR catalyst. Master's Thesis, Southeast University, China, 2018 (in Chinese).
朱林. 过渡金属氧化物低温SCR催化剂脱硝性能及机理研究. 硕士学位论文, 东南大学, 2018.
69 Xiao Z B, Ma J X, Zhang Q Q, et al. Applied Catalysis, B Environmental, 2017, 30(5), 12.
70 He D, Yi H H, et al. Journal of Rare Earths, 2010, 28(s1), 343.
71 Huang H, Young N, Willams B P, et al. Green Chemistry, 2008, 10(5), 571.
72 David Chiche, Jean-Marc Schweitzer. Applied Catalysis B: Environmental, 2017, 15(205), 189.
73 Wang G J, Tian A X, Chen X T, et al. Petroleum Refinery Engineering, 2017, 47(9), 37 (in Chinese).
王广建, 田爱秀, 陈晓婷, 等. 炼油技术与工程, 2017, 47(9), 37.
74 Nowinska K, Fiedorow R, Adamiec J. Cheminform, 2010, 22(23), 71.
75 Song X, Ning P, Wang C, et al. Applied Surface Science, 2017, 31(414), 345.
76 Han S, Yang H, Ning P, et al. Research on Chemical Intermediates, 2018, 44(1), 1.
77 Wang Y H. Study of hydrolysis carbonyl sulfide over mixed oxides from hydrotalcite-like compounds. Master's Thesis, Kunming University of Science and Technology, China, 2011 (in Chinese).
王红妍. 类水滑石衍生复合氧化物催化水解羰基硫研究. 硕士学位论文, 昆明理工大学, 2011.
78 George Z. Journal of Catalysis, 1974, 32(2) 261.
79 Li D S, Feng T, Yao S L. Environmental Science & Technology, 2007,10,65.
80 Yu L L, Tang X L, Yi H H, et al. Industrial Catalysis, 2009, 17(5), 21 (in Chinese).
于丽丽, 唐晓龙, 易红宏, 等. 工业催化, 2009, 17(5), 21.
81 Zhao S, Yi H, Tang X, et al. Ultrasonics Sonochemistry, 2016, 32, 336.
82 Ling L, Zhang R, Han P, et al. 2016, 18(4), 1625.
83 Zhu T T, Wang C, Song X, et al. Environmental Pollution, 2018, 232, 615.
84 Han S. Catalytic hydrolysis of COS and reaction mechanism of CS₂ with Fe₂O₃ graphene. Master's Thesis, Kunming University of Science and Technology, China, 2018 (in Chinese).
韩双.Fe₂O₃石墨烯催化水解COS及CS₂反应机理研. 硕士学位论文, 昆明理工大学, 2018.
85 Sahibeddinea A, Bensitela M, Aboulayt A, et al. Journal of Molecular Catalysis A: Chemical, 2000, 20(162), 125.
86 Huisman H M, vander Berg P, Mos R, et al. American Chemical Society, 1994, 32, 393.
87 Laperdrix E, Justin I, Costentin G, et al. Applied Catalysis B: Environmental, 1998, 17, 167.
88 Liu J F, Liu Y C, Xue L, et al. Actaphysico-Shimica Sinica, 2007, 23(7), 997 (in Chinese).
刘俊锋, 刘永春, 薛莉, 等. 物理化学学报, 2007, 23(7),997.
89 Wei Z, Zhang X, Zhang F L, et al. Journal of Hazardous Materials, 2021, 5(407),135
90 Yi H Y, Yi H H, Tang X L, et al. Journal of Environmental Enginee-ring, 2012, 6(2), 545.
91 Tasdemir H M, Yasyerli S, Yasyerli N. International Journal of Hydrogen Energy, 2015, 40 (32) 9989.
92 Liu J, Liu D D. Science and Technology Economy Guide, 2020, 28(2), 64.
刘佳, 刘丹丹.科技经济导刊, 2020, 28(2), 64.
93 Wang C, Li K, Sun X, et al. Frontiers of Materials Science, 2018, 012(4), 426.
94 Song X, Sun L, Guo H, et al. ACS Omega, 2019, 4(4), 7122.
95 Yi H, Zhao S, Tang X, et al. Catalysis Communications, 2014, 56, 106.