晶体硅金刚石线切割废料资源化利用研究进展

doi:10.11896/cldb.20080070

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Abstract Crystalline silicon solar cell is one of the most important cell in the photovoltaic industry. The preparation of cell materials requires cutting polycrystalline silicon ingots to silicon wafers. Nearly half of the crystalline silicon will enter the cutting fluid in the form of ultrafine powder during the cutting process, which will cause waste of silicon resources and environmental pollution.
The cutting waste consists of 90% silicon powder and less Fe, Al, Ca and other impurities. At present, the research on the utilization of cutting wastes mainly focuses on the recovery of high purity silicon and the preparation of silicon-containing materials. Recovery of high purity silicon can realize the recycling of silicon resources from the end of production to the production side. However, the market requires a higher purity of silicon powder. In the purification process, it will produce higher energy consumption and secondary pollutants such as waste water and residue. Cutting waste materials can be directly used to prepare silicon containing materials such as alloys, ceramics, nanomaterials and battery materials, so as to obtain corresponding high value-added materials. However, there is still a large research space for product performance control and overall quality improvement.
In this paper, the production process and composition characteristics of polycrystalline diamond cutting waste are briefly described, the cutting wastes recovery used for preparation of high purity silicon, silicon alloy, nitride, nanomaterials and cell materials are summarized, the technological characteristics of various high purity silicon recovery methods (acid leaching method, melting method and other new methods) are reviewed, and the future development direction of resource utilization is discussed.

Key words： crystalline silicon cutting waste resource utilization

Published: 10 December 2021 Online: 2021-12-23

CLC number:

TF09

Fund:National Natural Science Foundation of China(51774224)

Corresponding Authors: xaxxd@xauat.edu.cn;xmli88@126.com

About author: Xiaoming Li received his doctor's degree in 2005 from Xi'an Jiaotong University. He is a professor of Xi'an University of Architecture and Technology. He focuses on the research of new metallurgical technology and comprehensive utilization of resources.
Xiangdong Xing received his B.E. and M.S.degree from Xi'an University of Architecture and Technology in 2009 and received his Ph.D. degree from University of Science and Technology Beijing in 2014. He is currently an associate professor in Xi'an University of Architecture and Technology. His main research direction is the comprehensive utilization of complex and refractory mineral resources.

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	LI Xiaoming
	RUAN Jinbang
	ZANG Xuyuan
	ZHANG Xinyi
	HE Yun
	ZHANG Lianzeng
	XING Xiangdong

Cite this article:

LI Xiaoming,RUAN Jinbang,ZANG Xuyuan, et al. Research Progress on Resource Utilization of Crystal Silicon Diamond-Wire Cutting Waste[J]. Materials Reports, 2021, 35(23): 23229-23234.

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http://www.mater-rep.com/EN/10.11896/cldb.20080070 OR http://www.mater-rep.com/EN/Y2021/V35/I23/23229

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