高性能锂硫电池研究进展与改进策略

doi:10.11896/cldb.20080027

Abstract
Figure/Table
References
Related Citation (4)

Download:

Full Text ( PDF ) (11503KB)
Export: BibTeX | EndNote (RIS)

Abstract With the consumption of fossil fuels and the rapid development of electric vehicles (EVs), portable devices and grid storage, traditional lithiu-mion batteries are unable to satisfy the ever-increasing demand of society. It is very important for researchers to explore for replaceable green new energy sources. In recent years, high-energy density and low-cost lithium sulfur batteries (LSBs) technology has received great attention. In theory, the area capacity of the cell cathode is directly determined by the sulfur content and the sulfur loading. Therefore, it is imperative to deve-lop high-performance lithium sulfur batteries (HLSBs) with high loading for improving the area capacity and energy density. However, the actual energy density of LSBs is far lower than its theoretical value. The main reasons can be summarized in the ‘Shuttle effect' of lithium polysulfides (LiPSs), the poor conductivity of sulfur and lithium sulfide (Li₂S₂/Li₂S) and uncontrollable growth of lithium dendrites. More importantly, the above-mentioned problems will become more serious when the sulfur loading increases to the practical application level. In response to these problems, researchers have designed various strategies to suppress the “shuttle effect” of LiPSs, such as physical coating, electrostatic repulsion and polar adsorption. Moreover, some nano-catalytic materials have attracted wide attention from researchers due to the polar effect, surface defects and other advantages. Therefore, researchers have successively developed various catalytic materials with different structures such as one-dimensional, two-dimensional and three-dimensional to accelerate the redox reaction, which has effectively improved the cycle life and coulombic efficiency of LSBs. Although researchers have made great contributions in terms of cycle life, the commercialization prospects of the technology depend on whether it can be made into durable and safe battery system. Therefore, the researching teams has developed new functional electrolyte additives, high-performance separators and interlayers, and micro/nano-structured lithium anodes or lithium composite anodes to stabilize lithium anodes for improving battery safety. From the perspective of commercialization, the area capacity and energy density of LSBs need to reach 5 mAh·cm^-2 and 500 Wh·kg^-1 to meet the requirements of commercial EVs. Thus, researchers are not only improving battery performance, but also constantly increasing the sulfur loading to achieve higher energy density, which is closer to commercial requirements.
In this review, the current development strategies for high performance HLSBs are presented and reviewed from three aspects including the suppression of LiPSs ‘Shuttle effect', electrocatalysis strategy and overall safety strategy. These strategies have significant effects on inhibiting the ‘Shuttle effect' and improving the utilization efficiency of active substances, especially on prolonging the cycle life and safety. At last, the future challenges and opportunities of high-performance HLSBs have also been indicated.

Key words： high-loading lithium sulfur battery shuttle effect adsorption strategy catalytic effect lithium dendrite

Published: Online: 2022-06-09

CLC number:	TM919
	O646

Fund:National Natural Science Foundation of China (51673148, 51678411) and China Postdoctoral Science Foundation Grant (2019M651047).

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	FENG Yang
	WANG Gang
	CHEN Junyan
	KANG Weimin
	DENG Nanping
	CHENG Bowen

Cite this article:

FENG Yang,WANG Gang,CHEN Junyan, et al. Research Progress and Improvement Strategy of High-performance Lithium Sulfur Battery[J]. Materials Reports, 2022, 36(11): 20080027-14.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.20080027 OR http://www.mater-rep.com/EN/Y2022/V36/I11/20080027

1 Bonnick P, Muldoon J. Energy & Environmental Science,2020,13(12), 4808.
2 Manthiram A, Fu Y, Chung S H, et al. Chemical Reviews, 2014, 114(23), 11751.
3 Peng H J, Huang J Q, Cheng X B, et al. Advanced Energy Materials, 2017, 7(24), 1700260.
4 Lin Z, Liang C D. Journal of Materials Chemistry A, 2015, 3(3), 936.
5 Chen W, Hu Y, Lei T Y, et al. Advanced Energy Materials, 2020, 10(17), 2000082.
6 Pang Q, Liang X, Kwok C Y, et al. Nature Energy, 2016, 1(9), 16132.
7 Seh Z W, Sun Y, Zhang Q, et al. Chemical Society Reviews, 2016, 45(20), 5605.
8 Liu Y T, Liu S, Li G R, et al. Advanced Materials, 2021, 33(8), 2003955.
9 Li X L, Liu M, Jiang J C, et al. Journal of Chongqing University of Technology(Natural Science), 2020, 34(2), 40(in Chinese).
李旭玲,刘梦,姜久春,等. 重庆理工大学学报(自然科学版),2020, 34(2), 40.
10 Kang W M, Deng N P, Ju J G, et al. Nanoscale, 2016, 8(37), 16541.
11 Lin D C, Liu Y Y, Cui Y. Nature Nanotechnology, 2017, 12(3), 194.
12 Peng H J, Huang J Q, Zhang Q. Chemical Society Reviews, 2017, 46(17), 5237.
13 Liu M, Deng N P, Ju J G, et al. Advanced Functional Materials, 2019, 29, 1905467.
14 Deng N P, Ma X M, Ruan Y L, et al. Progress of Chemistry, 2016, 28(9), 1435(in Chinese).
邓南平, 马晓敏, 阮艳丽, 等. 化学进展, 2016, 28(9), 1435.
15 Liu J W, Wang J N, Zhu L, et al. Materials Reports A:Review Papers, 2020, 34(1), 1155(in Chinese).
刘建伟, 王嘉楠, 朱蕾, 等. 材料导报:综述篇, 2020, 34(1), 1155.
16 Zhang Q, Cheng X B, Huang J Q, et al. New Carbon Materials, 2014, 29(4), 241(in Chinese).
张强, 程新兵, 黄佳琦, 等. 新型炭材料, 2014, 29(4), 241.
17 Bai S Y, Kim B H, Kim C R, et al. Nature Nanotechnology, 2021, 16(1), 77.
18 Li Z, Guan B Y, Zhang J T, et al. Joule, 2017, 1(3), 576.
19 Li Z, Zhang J T, Chen Y M, et al. Nature Communications, 2015, 6, 8850.
20 Pei F, Lin L L, Fu A, et al. Joule, 2018, 2(2), 323.
21 Hui P, Yang R, Deng Q J, et al. Chemistry Bulletin, 2019, 82(11), 982(in Chinese).
惠鹏, 杨蓉, 邓七九, 等. 化学通报, 2019, 82(11), 982.
22 Huang J Q, Sun Y Z, Wang Y F, et al. Acta Chimica Sinica, 2017, 75(2), 173.
23 Dong L W, Liu J P, Chen D J, et al. ACS Nano, 2019, 13(12), 14172.
24 Li G R, Lu F, Dou X Y, et al. Journal of the American Chemical Society, 2020, 142(7), 3583.
25 Wu F X, Lv H F, Chen S Q, et al. Advanced Functional Materials, 2019, 29(27), 1902820.
26 Zhang T, Tang T Y, Hou Y L. Materials Reports A:Review Papers, 2019, 33 (1), 90(in Chinese).
张腾, 唐天宇, 侯仰龙. 材料导报:综述篇, 2019, 33 (1), 90.
27 Chen Z C, Fang R Y, Liang C, et al. Materials Reports A:Review Papers, 2018, 32 (5), 1401(in Chinese).
陈子冲, 方如意, 梁初, 等. 材料导报:综述篇,2018,32 (5),1401.
28 Huang X, Tang J Y, Luo B, et al. Advanced Energy Materials, 2019, 9(32), 1901872.
29 Xiao X, Wang H, Bao W Z, et al. Advanced Materials, 2019, 31(33), 1902393.
30 Li G, Lei W, Luo D, et al. Energy & Environmental Science, 2018, 11(9), 2372.
31 Zheng Z J, Ye H, Guo Z P. Energy & Environmental Science, 2021, 14(4), 1835.
32 Liu T, Sun S M, Song W, et al. Journal of Materials Chemistry A, 2018, 6(46), 23486.
33 Zhang Y Z, Wang R C, Tang W Q, et al. Journal of Materials Chemistry A, 2018, 6(42), 20926.
34 Balach J, Linnemann J, Jaumann T, et al. Journal of Materials Chemistry A, 2018, 6(46), 23127.
35 Zhao T, Ye Y S, Peng X Y, et al. Advanced Functional Materials, 2016, 26(46), 8418.
36 Chen M F, Jiang S X, Huang C, et al. ACS Applied Materials & Interfaces, 2018, 10(16), 13562.
37 Xu J, Zhang W X, Chen Y, et al. Journal of Materials Chemistry A, 2018, 6(6), 2797.
38 Tao X Y, Wang J G, Liu C, et al. Nature Communications, 2016, 7, 11203.
39 Liu F, Xiao Q F, Wu H B, et al. ACS Nano, 2017, 11(3), 2697.
40 Zhao S P, Li Y P, Zhang F X, et al. Journal of Alloys and Compounds, 2019, 805, 873.
41 Li C X, Xi Z C, Guo D X, et al. Small, 2018, 14(4), 1701986.
42 Li Z H, He Q, Xu X, et al. Advanced Materials, 2018, 30(45), 1804089.
43 Ma L B, Yuan H, Zhang W J, et al. Nano Letters, 2017, 17(12), 7839.
44 Shi N X, Xi B J, Feng Z Y, et al. Advanced Materials Interfaces, 2019, 6(9), 1802088.
45 Zhuang R Y, Yao S S, Liu M H, et al. International Journal of Energy Research, 2019, 43(13), 7655.
46 Bao W Z, Liu L, Wang C Y, et al. Advanced Energy Materials, 2018, 8(13), 1702485.
47 Zheng Y, Zheng S S, Xue H G, et al. Journal of Materials Chemistry A, 2019, 7(8), 3469.
48 Guo Y, Sun M H, Liang H Q, et al. ACS Applied Materials & Interfaces, 2018, 10(36), 30451.
49 Lopez J, Mackanic D G, Cui Y, et al. Nature Reviews Materials, 2019, 4(5), 312.
50 Fu X W, Scudiero L, Zhong W H. Journal of Materials Chemistry A, 2019, 7(4), 1835.
51 Zhang Z W, Peng H J, Zhao M, et al. Advanced Functional Materials, 2018, 28(38), 1707536.
52 Wang N N, Xu Z F, Xu X, et al. ACS Applied Materials & Interfaces, 2018, 10(16), 13573.
53 Zeng P, Huang L W, Zhang X L, et al. Chemical Engineering Journal, 2018, 349, 327.
54 Chen P, Fu Y S, Wu Z, et al. Journal of Power Sources, 2019, 434, 226728.
55 Babu D B, Ramesha K. Carbon, 2019, 144, 582.
56 Tang T Y, Hou Y L. Small Methods, 2019, 4(6), 1900001.
57 He J R, Manthiram A. Energy Storage Materials, 2019, 20, 55.
58 Hong X D, Wang R, Liu Y, et al. Journal of Energy Chemistry, 2020, 42, 144.
59 Wang P, Xi B J, Huang M, et al. Advanced Energy Materials, 2021, 11(7), 2002893.
60 Lim W G, Kim S, Jo C S, et al. Angewandte Chemie International Edition, 2019, 58(52), 18746.
61 Song Y Z, Cai W L, Kong L, et al. Advanced Energy Materials, 2019, 10(11), 1901075.
62 Sun Y M, Liu N, Cui Y. Nature Energy, 2016, 1(7), 16071.
63 Peng L L, Wei Z Y, Wan C Z, et al. Nature Catalysis, 2020, 3(9), 762.
64 Zhou G M, Zhao S Y, Wang T S, et al. Nano Letters, 2020, 20(2), 1252.
65 Zhao C, Xu G L, Yu Z, et al. Nature Nanotechnology, 2021, 16(2), 166.
66 Gu X X, Lai C. Energy Storage Materials, 2019, 23, 190.
67 Liu Y T, Han D D, Wang L, et al. Advanced Energy Materials, 2019, 9(11), 1803477.
68 Zhou G M, Xu L, Hu G H, et al. Chemical Reviews, 2019, 119(20), 11042.
69 Shen Z H, Cao M Q, Zhang Z L, et al. Advanced Functional Materials, 2019, 30(3), 1906661.
70 Ali T, Yan C L. Chemsuschem, 2019, 13(6), 1447.
71 Li B, Xu H F, Ma Y, et al. Nanoscale Horizons, 2019, 4(1), 77.
72 Shao Q J, Wu Z S, Chen J. Energy Storage Materials, 2019, 22, 284.
73 Wang D, Li F, Lian R, et al. ACS Nano, 2019, 13, 11078.
74 Li J B, Chen C Y, Chen Y W, et al. Advanced Energy Materials, 2019, 9, 1901935.
75 Xu Z L, Lin S H, Onofrio N, et al. Nature Communications, 2018, 9(1), 4164.
76 He B, Li W C, Zhang Y, et al. Journal of Materials Chemistry A, 2018, 6(47), 24194.
77 Li L, Chen L, Mukherjee S, et al. Advanced Materials, 2017, 29(2), 1602734.
78 Fan Y, Yang Z, Hua W X, et al. Advanced Energy Materials, 2017, 7(13), 1602380.
79 Fan G L, Li F, Evans D G, et al. Chemical Society Reviews, 2014, 43(20), 7040.
80 Li Y, Fan J, Zhang J, et al. ACS Nano, 2017, 11(11), 11417.
81 Xiao Z B, Li Z L, Meng X P, et al. Journal of Materials Chemistry A, 2019, 7(40), 22730.
82 Song Y Z, Sun Z T, Fan Z D, et al. Nano Energy, 2020, 70, 104555.
83 Cheng Z B, Chen Y L, Yang Y S, et al. Advanced Energy Materials, 2021, 11(12), 2003718.
84 Wu H B, Lou X W. Science Advances, 2017, 3, 9252.
85 Zhong Y J, Xu X M, Liu Y, et al. Polyhedron, 2018, 155, 464.
86 Yang Y X, Wang Z H, Jiang T Z, et al. Journal of Materials Chemistry A, 2018, 6(28), 13593.
87 Zhang J T, Li Z, Chen Y, et al. Angewandte Chemie International Edition, 2018, 57(34), 10944.
88 Zhang J T, Hu H, Li Z, et al. Angewandte Chemie International Edition, 2016, 55(12), 3982.
89 Guan B, Zhang Y, Fan L S, et al. ACS Nano, 2019, 13(6), 6742.
90 Ding M, Huang S Z, Wang Y, et al. Journal of Materials Chemistry A, 2019, 7(43), 25078.
91 Chen Y, Zhang W X, Zhou D, et al. ACS Nano, 13(4), 4731.
92 Luo D, Li G R, Deng Y P, et al. Advanced Energy Materials, 2019, 9(18), 1900228.
93 Deng N P, Liu Y, Li Q X, et al. Energy Storage Materials, 2019, 23, 314.
94 Cheng X B, Zhang Q. Progress of Chemistry, 2018, 30 (1), 51(in Chinese).
程新兵, 张强. 化学进展, 2018, 30 (1), 51.
95 Zhang H, Eshetu G G, Judez X, et al. Angewandte Chemie International Edition, 2018, 57(46), 15002.
96 Fan L L, Deng N P, Yan J, et al. Chemical Engineering Journal, 2019, 369, 874.
97 Jeong Y C, Kim J H, Nam S, et al. Advanced Functional Materials, 2018, 28(38), 1707411.
98 Li W Y, Yao H B, Yan K,et al. Nature Communications, 2015, 6, 7436.
99 Yang T Z, Qian T, Liu J, et al. ACS Nano, 2019, 13(8), 9067.
100 Tang B, Wu H, Du X F, et al. Small, 2020, 16(5), 1905737.
101 Pei F, Dai S, Guo B F, et al. Energy & Environmental Science, 2021, 14(2), 975.
102 Judez X, Martinez-Ibañez M, Santiago A, et al. Journal of Power Sources, 2019, 438(31),226985.
103 Xu S M, McOwen D W, Zhang L, et al. Energy Storage Materials, 2018, 15, 458.
104 Rana M, Li M, Huang X, et al. Journal of Materials Chemistry A, 2019, 7(12), 6596.
105 Wang L, Deng N P, Fan L L, et al. Materials Letters, 2018, 233, 224.
106 Zhao H J, Deng N P, Kang W M, et al. Energy Storage Materials, 2019, 26, 334.
107 Deng N P, Liu Y, Li Q X, et al. Chemical Engineering Journal, 2019, 382, 122918.
108 Guo D, Ming F W, Su H, et al. Nano Energy, 2019, 61, 478.
109 Li Y J, Wang W Y, Liu X X, et al. Energy Storage Materials, 2019, 23, 261.
110 Zhao Y Y, Ye Y S, Wu F, et al. Advanced Materials, 2019, 31(12), 1806532.
111 Zhang H M, Liao X B, Guan Y P, et al. Nature Communications, 2018, 9, 3729.
112 Cha E, Patel M D, Park J, et al. Nature Nanotechnology, 2018, 13(4), 337.
113 Pei F, Fu A, Ye W B, et al. ACS Nano, 2019, 13(7), 8337.
114 Kong L L, Wang L, Ni Z C, et al. Advanced Functional Materials, 2019, 29(13), 1808756.