镧系金属-有机框架材料作为荧光探针的研究进展

doi:10.11896/cldb.20060292

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Abstract Metal-organic frameworks (MOFs) are ordered network complexes formed by the connection of metal ions with organic ligands coordination bonds, demonstrating high application potential in ion exchange, gas separation and storage, catalysis, fluorescence sensing, and drug delivery.
The quantitative detection of target components can be achieved by using changes in fluorescence intensity after the interaction between MOFs with fluorescence emission properties and guest molecules. For MOFs with a single ligand luminescence, the quantitative method is vulnerable to external interference, and the accuracy of the results is affected. The properties of metal ions and organic ligands determine the fluorescence properties of MOFs, which is the focus of research in this field. The trivalent lanthanide ion (Ln³⁺) has a 4f electron layer, which is incompletely filled, and exhibits unique fluorescence properties. Besides, it is prone to coordination with oxygen and nitrogen atoms. It can form high-coordination complexes with a particular topological structure by coordinating with organic ligands. Lanthanide metal-organic frameworks (Ln-MOFs) formed by Ln³⁺ and organic ligands are widely used as ratio fluorescent probes because of their ordered structure and high specific surface area, as well as the combined fluorescence properties of organic ligands and lanthanides. Ln-MOFs that respond to different components can be deve-loped by selecting different organic ligands and lanthanides.
This paper offers a retrospection of the research efforts with respect to the progress of Ln-MOFs in fluorescence detection and temperature sensing of anions, cations and small molecules. This paper also provides analysis of the detection results, detection mechanism and influencing factors. Moreover, we summarize the design concept of Ln-MOFs as fluorescent probes. Finally, we pay attention to the problems existing in the research on Ln-MOFs and focus on the prospect of its future development.

Key words： Ln-MOF fluorescent probe trivalent lanthanide ion (Ln³⁺) luminous function application

Published: 25 August 2022 Online: 2022-08-29

CLC number:

O657

Fund:Natural Science Foundation Outstanding Youth of Heilongjiang Province (YQ2019H034) and the Research Foundation of Education Bureau of Heilongjiang Province (135109201).

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	Articles by authors
	CHU Hongtao
	YIN Jie
	LIN Qing
	SUI Bingrong
	TAN Jinming
	SU Liqiang
	MA Wenhui

Cite this article:

CHU Hongtao,YIN Jie,LIN Qing, et al. Research Progress of Lanthanide Metal-Organic Framework Materials as Fluorescent Probes[J]. Materials Reports, 2022, 36(16): 20060292-8.

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http://www.mater-rep.com/EN/10.11896/cldb.20060292 OR http://www.mater-rep.com/EN/Y2022/V36/I16/20060292

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