POLYMERS AND POLYMER MATRIX COMPOSITES |
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A Review on the Shape Memory Polyurethane and Its Nonwoven Progress |
SUN Huanwei1, ZHANG Heng1,2, LI Xia1,2, ZHEN Qi2,3, CUI Jingqiang2,4, QIAN Xiaoming5, ZHANG Yifeng1
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1 School of Textiles, Zhongyuan University of Technology, Zhengzhou 451191, China 2 Henan Key Laboratory of Medical Polymer Materials Technology and Application, Xinxiang 453400, China 3 School of Clothing, Zhongyuan University of Technology, Zhengzhou 451191, China 4 Henan Tuoren Medical Device Co., Ltd., Xinxiang 453400, China 5 School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China |
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Abstract As a fibrous material with engineering structure, nonwoven made by physical or chemical methods is a functional fabric which derived from textile technology. And the nonwovens have been widely used in various fields such as medical treatment, filtration and separation,civil and construction. Thus, optimizing the structure and enhancing the performance of the nonwovens are the urgently topics for the high-quality application. Nowadays, one of the shape memory polymers, shape memory polyurethane (SMPU) has been widely used in medical and health, aerospace, textile and clothing fields due to its advantages of easy processing, large deformation, outstanding shape memory effect and diverse sti-mulation methods. It can be seen that the combining the SMPU and nonwoven technology will maintain the original characteristics of nonwovens while providing the shape memory functions. This provides a drive for the innovation and upgrading of nonwoven technology, and also provides a basis for the high-quality application of shape memory materials. Presently, the preparation of SMPU nonwovens mainly include blending, direct-web-forming and post-processing methods. The blending met-hod can be divided into composite fiber web-forming and blending spinning. The blending method has an advantage of uniform of shape memory effect resulted from the of the fully mixed of the fibers or polymers. Besides, the direct-web-forming method can be divided into categories of electrospinning and melt blowing. The electrospinning has been widely used in the preparing of nano-scale nonwovens with light weight, multi-pore and low cost. In contrast, the SMPU nonwovens from the melt blowing process have serious properties i.e fluffy structure, small pore size and large porosity, and have be widely used in oil absorbing materials, filtration materials and sound insulation etc. Further, post-processing method mainly applied in the coating and solution has the advantages of simple operation, low cost, and excellent shape memory effect. However, the application of SMPU nonwovens still limited in the laboratory and serious bottlenecks should be overcome for the large scale industrialization and functional applications. In this work, the shape memory mechanism, classification and application are reviewed and the research progress of the preparation method is analyzed of the SMPU nonwovens for the purpose of further development and high-quality application.
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Published: 10 December 2021
Online: 2021-12-23
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Fund:National Natural Science Foundation of China (52003306), the National Biomedical Material Production and Application Demonstration Platform of China (TC190H3ZV/1), the Key Research Projects of Henan Higher Education Institutions (20A540001), the Henan Key Laboratory of Medical Polymer Materials Technology and Application (1-TR-B-03-210117), and Zhongyuan University of Technology (K2020YY002) |
Corresponding Authors:
zhangheng2699@zut.edu.cn
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About author: Huanwei Sun, graduated from Zhongyuan University of Technology with a bachelor's degree in engineering in June 2019. He is currently a master student of the Textile School of Zhongyuan University of Technology, conducting research under the guidance of Dr. Zhang Heng. The current research direction is the high-quality application of functional nonwovens. Heng Zhang, master supervisor of Zhongyuan university of Technology, is mainly engaged in the research on new technology and functional application of advanced textiles. Recent 5 years, he has published more than 30 SCI/EI academic papers and authorized 17 invention patents, such as Polymer, ACS Appl. Polym. Mater.,Polym Test and Journal of Textile Research. |
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