基于YD2-<i>o</i>-C8的高效卟啉染料敏化剂的研究进展

doi:10.11896/cldb.19120182

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Abstract Metalloporphyrins have attracted much attention in the field of sensitizers for dye-sensitized solar cells (DSSC) due to their strong coordination ability and flexible structure. Zinc porphyrin dye sensitizer YD2-o-C8 has become a research hotspot due to its high molar absorption coefficient and environmental friendliness. However, YD2-o-C8 and its derivatives still have some shortcomings in the application: (1) the carboxyl anchoring group is easy to desorb, which makes the dye unstable; (2) the low absorption intensity of dye sensitizer in the near-infrared region reduces the photoelectric conversion performance, which limits its large-scale production and application; (3) the easily self-polymerized dye sensitizer can shorten the service life and reduce the photoelectric conversion efficiency of dye-sensitized solar cells.
In recent years, based on zinc porphyrin dye sensitizer YD2-o-C8, many derivative porphyrin dye sensitizers with D-π-A structure have been synthesized by changing the structure of electron donor, electron acceptor and conjugated π-bridge. Dye sensitizers such as WW-6 and NCH₃-YD2 appeared by changing the electron donor group. Dye sensitizers such as YD2-II-CA and PorCND1A1 appeared by changing the conjugate π-bridge. Dye sensitizers such as YD2-o-C8T and MH1 are produced by changing the electron-acceptor and anchoring group. These dye sensitizers expand the absorption range of B band and Q band, improve the absorption intensity of near-infrared region, and then improve the photoelectric conversion efficiency of dye-sensitized solar cells. Even some dye sensitizers surpass YD2-o-C8 in stability and service life, which makes the development of dye sensitizer family take on a new look.
In this paper, the experimental and theoretical progress of D-π-A zinc porphyrin dye sensitizer YD2-o-C8 and its derivatives are reviewed. The improvement of YD2-o-C8 in electron donor group, conjugated π-bridge and electron-acceptor and anchoring group and its influence on the photoelectric conversion performance are emphasized. The development prospect of porphyrin dye sensitizer is also prospected.

Key words： porphyrin dye sensitizer electron donor conjugated π-bridge electron acceptor

Published: 31 May 2021

CLC number:

TM914.4

Fund:National Natural Science Foundation of China (21376010, 21776021), and Beijing Municipal High Level Innovative Team Building Program (IDHT20180504).

About author:: Qingtang Yuan received his B.E. degree in applied chemistry from Qingdao Agricultural University in 2018. He is currently pursuing his master's degree at the Department of Environmental Chemical Engineering, Beijing University of Technology under the supervision of full associate professor Yanmin Yu. His research has focused on porphyrin dye sensitized solar cells.
Yanmin Yu received her Ph.D. degree in analytical chemistry from University of Science and Technology of China in 2006. She is currently a full associate professor in Beijing University of Technology. Her research inte-rests are theoretical calculations of porphyrins.

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	YUAN Qingtang
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	SONG Xufeng

Cite this article:

YUAN Qingtang,YU Yanmin,SONG Xufeng. Advances in High Efficiency Porphyrin Dyes Based on YD2-o-C8[J]. Materials Reports, 2021, 35(9): 9210-9217.

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http://www.mater-rep.com/EN/10.11896/cldb.19120182 OR http://www.mater-rep.com/EN/Y2021/V35/I9/9210

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