层状双金属氢氧化物及其复合材料的制备与应用研究新进展

doi:10.11896/cldb.19120181

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Abstract In a world with rising concern about energy security, environmental crisis, and global warming, exploring superior catalysts for oxygen evolution reaction, super capacitor, and the treatment of pollutant ions in waste water are getting more and more attention. Layered double hydro-xide (LDH) has many properties such as memory effect, nice catalysis ability, anion exchange, acid-base and thermal stability, which has been widely concerned in various fields to solve the above problems.
LDH has excellent performance for oxygen evolution electrocatalysis, low cost, adjustable structure. The intercalation reaction can be carried out between layers of LDH. However, the poor electron conductivity of LDH reduces its electrochemical performance. Moreover, the LDH layers are easy to agglomerate in the synthesis process, resulting low conductivity and low catalytic activity. These problems can be solved by improving the synthesis method of LDH and compounding LDH with various functional materials.
In recent years, in order to improve the conductivity of LDH, researchers have in situ grown LDH on various conductive substrate, which can expose more active sites and as a result improve the catalytic activity of LDHs. By compounding LDH with graphene, the specific capacitance, conductivity and cycle stability of LDH/graphene composites can be enhanced, and the adsorption capacity of LDH for CO₂ can also be improved, making LDH widely used to solve energy crisis and environmental pollution problems.
This article reviews the synthesis methods of LDH and LDH composites, and summarizes the applications of LDH and its composites in catalysis, energy storage, and environmental protection in recent years. First, the application of LDH in electrocatalytic water oxidation and photocatalysis is introduced, and then the application of LDH materials in supercapacitors and environmental problems such as water pollution treatment is described.

Key words： layered double hydroxide synthesis method catalytic energy storage adsorption

Published: 03 November 2021

CLC number:

O69

Fund:National Natural Science Foundation of China (21862011, 51864024), the Youth Excellence Fund of Yunnan Province (2019FI003) and the High-level Talent Introduction Project of Kunming University of Science and Technology (KKKP201707010, KKKP201752011).

About author:: Zhengfang Yang is a postgraduate in the Kunming University of Science and Technology. She conducts research under the guidance of professor Jue Hu. Her research has focused on the synthesis and electrocataly-tic application of layered double hydroxides.
Jue Hu received her Ph.D. degree from Hefei Institutes of Physical Science, Chinese Academy of Sciences in 2012. After one year postdoctoral research at Brookhaven National Laboratory and two-year postdoctoral research at Hong Kong University of Science and Technology, she is currently a full professor in Kunming University of Science and Technology. Her research interests are metal base materials for electrocatalysis.

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	YANG Zhengfang
	ZHANG Yue
	CAI Jinxiao
	LIU Zhiyong
	HU Jue

Cite this article:

YANG Zhengfang,ZHANG Yue,CAI Jinxiao, et al. Recent Advances in the Preparation and Application of Layered Double Hydroxides and Their Composites[J]. Materials Reports, 2021, 35(19): 19062-19069.

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http://www.mater-rep.com/EN/10.11896/cldb.19120181 OR http://www.mater-rep.com/EN/Y2021/V35/I19/19062

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