石墨烯基水润滑添加剂研究进展

doi:10.11896/cldb.19050101

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Abstract With the rapid development of industry and people's increasing emphasis on environmental protection, traditional lubricants can no longer meet people's needs in terms of avoiding environmental pollution,therefore, the environmentally friendly lubricants become an important direction in tribological research.Water-based lubricant has been used as green and eco-friendly lubricant to meet the needs of certain special environments and protect ecological requirements due to the advantages of low cost, excellent cooling performance, biodegradability, and safety performance. However, the shortcomings of water-based lubricant such as low kinematic viscosity, limited lubricating properties and easy corrosion limit the development of water lubrication technology in practical applications, so it is necessary to introduce nano-additives to solve these problems. The graphene-based material is a sheet-structured nanomaterial with excellent mechanical properties, and the sliding between the sheets belongs to ultra-lubricated sliding, so it can be used as a water-based lubricating additive. However, graphene is a stable material composed of a benzene-like ring unit and there is a strong π-π interaction between the sheets, which easily causes aggregate precipitation in water. Therefore, in recent years, many researchers have used different methods to functionally modify graphene-based materials. It has been found that the modified graphene-based materials have better dispersion stability in water-based solutions and maintain the original mechanics of graphene. So it can be used as an additive to significantly improve the lubrication properties of water-based solutions.
This paper summarizes the current methods of graphene modification for potential applications of water lubricating additives: (1) the covalently modification of graphene-based materials prepared by chemical reaction between the modified molecule and the oxygen-containing group of graphene oxide. (2) Functional modification of graphene-based materials obtained by non-covalent bonding of π-π interaction, ionic interaction and hydrogen bonding between modified molecules and graphene-based materials.(3) The size control of graphene-based materials. The modified graphene-based water-lubricating additive can effectively reduce the friction coefficient and wear rate of workpieces, and improve the corrosion inhibition efficiency of water-based lubricants. However, the graphene-based materials are used as a water-based lubricant additive which achieve long-term dispersion stability in water also has some challenges. At present, the evaluation system of water-based lubricants mostly adopts the evaluation system of oil-based lubricants, and lacks the test standards and methods for cooling performance and biodegradability. Therefore, it is necessary to establish a complete and systematic evaluation system for graphene-based water lubricating additives.

Key words： water-based lubricant nano-additive graphene tribological property friction-reduced and anti-wear

Published: 03 November 2021

CLC number:

TH117.1

Fund:National Science Fund for Distinguished Young Scholars of China (51825505), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDA13040601), the Major Project of Ningbo Science and Technology Innovation 2025 (2018B10028), the Youth Innovation Promotion Association CAS (2018336).

About author:: Yongxin Wang received his Ph.D. dregree in mate-rials science from State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences in 2011, subsequently worked at the Division of Surface Engineering and Remanufactu-ring, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, and a visiting scholar at the University of Landau, Koblenz, Germany. The main research directions are tribological interface behavior and friction-resistant wear-resistant coating materials. Based on discoveries and innovations in related research fields. He has published more than 80 papers in ACS Applied Materials and Interfaces, Carbon and other domestic and international authoritative academic journal.

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	WANG Yongxin
	HU Yiwen
	ZHAO Haichao
	LI Jinlong
	WANG Chunting
	MAO Jinming
	WANG Liping
	XUE Qunji

Cite this article:

WANG Yongxin,HU Yiwen,ZHAO Haichao, et al. Research Progress of Graphene as Additives of Water-based Lubricants[J]. Materials Reports, 2021, 35(19): 19055-19061.

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http://www.mater-rep.com/EN/10.11896/cldb.19050101 OR http://www.mater-rep.com/EN/Y2021/V35/I19/19055

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