农林废弃物吸附废水中重金属Pb<sup>2+</sup>的性能及机理研究进展

doi:10.11896/cldb.19110180

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Abstract Excessive Pb²⁺ in human body can cause some diseases such as anemia, renal failure, endocrine system and central nervous system disorders. Pb²⁺ pollution may exist in the form of waste water and solid waste. Among them, the Pb²⁺ containing waste water can not only directly cause the water source pollution, but also contaminate the soil in the related area. So the treatment of Pb²⁺ containing waste water is urgent.
Pb²⁺ can be removed from water by means of ion exchange, chemical precipitation, electrochemical method, membrane filtration and adsorption method. Adsorption method has been extensively used for the treatment of waste water due to its high efficiency, easy operation and low cost. Commercial activated carbon has better adsorption effect to treat waste water, but the high cost limits its utilization as an adsorbent. Hence, it is a key point to develop an alternative of activated carbon for the technology of wastewater treatment.
Agricultural and forestry waste (AFW) has been widely used to remove the Pb²⁺ in wastewater due to the advantages such as wealth sources, great varieties, low cost, good adsorption effect and renewability. Moreover, the adsorption efficiency of AFW can be improved by means of acid-base salt modification, structure modification, carbonization modification, organic solvent modification and compound modification. Meanwhile the factors such as the initial concentration of Pb²⁺, amount of adsorbent, pH value, adsorption temperature and time have great influences on the adsorption efficiency of AFW. AFW can efficiently adsorb the Pb²⁺ in wastewater through ion exchange, coordination action, physical adsorption and chemical precipitation. The adsorption kinetics can be described by pseudo second order, and the thermodynamics can be calculated by Langmuir isotherm model and Freundlich thermodynamic model.
This paper reviewes the research progress on the adsorption of Pb²⁺ in wastewater by AFW. The modification of AFW, the influence factors of Pb²⁺ adsorption and adsorption mechanism are discuss in this paper. We also discuss the directions of future research on the adsorption of Pb²⁺ by AFW, thus to provide a reference for the development of stable and renewable AFW adsorbents.

Key words： agricultural and forestry waste adsorption wastewater heavy metal Pb²⁺ modification adsorption mechanism

Published: 02 September 2020

CLC number:

X703.1

Fund:National Natural Science Foundation of China Regional Fund (51662024, 21866018) and Kunming University of Science and Technology Introduction of Scientific Research Fund Funded Projects (KKSY201605021)

About author:: Luxing Wang received her bachelor's degree in chemical engineering and technology from Wuhan Polytechnic University in 2018. She is currently pursuing her master's degree at Faculty of Chemical Engineering, Kunming University of Science and Technology. Her research has focused on environmental chemical enginee-ring.
Zhongqiu Luo received her Ph.D. degree in environmental engineering from Kunming University of Science and Technology in 2015. Her research interests are the resource utilization of industry solid wastes and treatment of hazardous wastes, including the depth activation technology for fly ash, phosphorus slag, red mud, steel metallurgical slag, preparation chemically bonded ceramics materials used industry solid wastes as raw materials, and its performance evaluation methods and application for treating hazardous wastes.

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	WANG Luxing
	ZHOU Xintao
	LUO Zhongqiu
	MU Weihong
	MA Yue
	SHAO Zhoujun

Cite this article:

WANG Luxing,ZHOU Xintao,LUO Zhongqiu, et al. Research Progress of the Properties and Mechanism of Heavy Metal Pb²⁺ Absorbed by Agricultural and Forestry Waste in Wastewater[J]. Materials Reports, 2020, 34(17): 17115-17123.

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http://www.mater-rep.com/EN/10.11896/cldb.19110180 OR http://www.mater-rep.com/EN/Y2020/V34/I17/17115

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