超亲水/水下超疏油膜功能材料及其研究进展

doi:10.11896/cldb.19090150

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Abstract Separation of oily wastewater, especially oil/water emulsions, is a worldwide challenge. Since membrane separation technology has high separation efficiency, low energy consumption and simple operation process, it has great advantages in the treatment of oily water. Superhydrophilic/underwater superoleophobic membrane is “water-removing” material with special wettability. Compared with superhydrophobic-supe-roleophilic membrane, superhydrophilic/underwater superoleophobic membrane is more resistant to organic pollution and biological pollution.
The disadvantages of filter membranes are chemical stability and membrane fouling. Membrane fouling will lead to reduction of separation efficiency, flux decline, shorter service life. Therefore, alleviating membrane pollution is essential to wastewater treatment. The focuses of hydrophilic modification are increasing filtration flux, improving anti-fouling ability and designing appropriate pore size.
Many researchers modified substrate through different methods to improve the hydrophilicity and anti-fouling capacity. Up till now, fruitful achievements have been received. Modification methods of polymer membrane are mainly divided into two types: bulk modification and surface modification. Bulk modification means hydrophilic modification on membranes including graft copolymerization or blending. Surface modification refers to the grafting of polar or hydrophilic monomers on the surface of commercial filter membranes. Hydrophilic modification methods for metal meshes include chemical etching, surface coating, electrochemical deposition and et al. By changing the chemical composition and roughness of the membrane surface, hydrophilicity, separation efficiency and anti-fouling performance can be greatly improved. In order to deal with industrial oil spills and protect the environment, it is urgent to develop new separation materials and technologies with high separation efficiency, high selectivity and stable performance.
Filter membrane is the research object of the article. Firstly, the theory and construction mechanism of superhydrophilic/underwater superoleophobic surface are introduced. Then, preparation and modification methods of filter membrane are comprehensively discussed based on different types of substrates. Recent advances of superhydrophilic/underwater superoleophobic metal membranes, polymer-dominated membranes and new functional separation membrane based on nanomaterials are comprehensively introduced. The performance of the oil/water membrane is comprehensively evaluated from the aspects of wettability, filtration flux, separation efficiency and antifouling ability. Finally, the future deve-lopment trend of oil/water filter membrane is summarized and prospected.

Key words： filter membrane superhydrophilic under water superoleophobic oil/water separation hydrophilic modification

Published: 02 September 2020

CLC number:

TB383

Fund:Provincial Basic Research Program of China (2018A030313235) and the Research Fund Program of Guangdong Provincial Key Lab of Green Chemical Product Technology (GC201813)

About author:: Lanfang Xu received her B.S. degree in applied che-mistry from Jiangnan University in 2016. She is currently pursuing her M.E. at the Institute of Chemistry and Chemical Engineering, South China University of Technology under the supervision of Feng Wang. Her research has focused on superhydrophilic/underwater superoleophobic functional membrane materials and light curing coating.
Feng Wang received his M.S. degree in chemistry from Hunan University in 2005 and received his Ph.D. degree in polymer chemistry at School of Chemistry and Chemical Engineering, South China University of Technology in 2008. He is currently an assistant researcher in School of Chemistry and Chemical Engineering, South China University of Technology. He is a member of Fine Chemicals. His research interests include modification of nanomaterials, organic and inorganic hybrid materials for water treatment.

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Cite this article:

XU Lanfang,WANG Feng,YU Yinghao, et al. Research Progress on Superhydrophilic/Underwater Superoleophobic Functional Membrane Materials[J]. Materials Reports, 2020, 34(17): 17105-17114.

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http://www.mater-rep.com/EN/10.11896/cldb.19090150 OR http://www.mater-rep.com/EN/Y2020/V34/I17/17105

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