合金元素对Fe/Al界面反应影响的研究进展

doi:10.11896/cldb.19100056

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Abstract The interfacial reaction of Fe/Al involves steel/Al welding in regard of lightweight design, corrosion of the die by molten aluminum in the cast processing of aluminum alloys, and preparation of hot-dipping coating for improvement of the corrosion resistance and wear resistance. In all the processing, brittle Fe-Al intermetallic compound (IMC) layer is formed on the interface due to the interdiffusion of Fe and Al, which determines these properties above. Therefore, how to control this interfacial reaction according to the final performance is of great practical significance. Many literatures have studied the Fe/Al interfacial reaction from the aspects of steel/aluminum welding and hot dip aluminizing of steel, and achieved fruitful results. However, most of the interfacial reactions of Fe/Al are the reaction-diffusion processes under non-equilibrium conditions. The Fe-Al IMC formed at the interface is very thin and brittle. Besides, alloy elements and their interaction will have a significant impact on the interfacial reactions. Alloying elements, such as Si and Zn, have complex effects on the interfacial reaction. In general, Si resists this interfacial reaction, while Zn accelerates it. But the influence of Si and Zn is related to the existing form. Periodic layered structure (PLS) will be formed at the reaction interface when the Fe-Cr-B cast steel is hot-dip aluminizing, and the alloying elements such as Cr and Zn have a significant impact on this interfacial reaction. The Cr content in Fe-Cr-B cast steel plays a key role in the formation of PLS, only when the Cr content is among the critical range can the PLS be formed during the interfacial reaction. The critical content of Al in Zn-Al melt was 0.3wt% when the interfacial reaction of Fe/Al transformed to Fe/Zn. This paper focused on the influences of alloying elements on the type, morphology and thickness of the IMCs formed during the interfacial reaction of Fe/Al and the discussion of its mechanism. Combined with the previous research results of the author, the evolution of interfacial structures of Fe-Cr-B cast steels during hot-dip aluminizing were analyzed. Finally, the future research and development directions in the interfacial reaction of Fe/Al were prospected in order to provide theoretical guidance for the related engineering applications.

Key words： interfacial reaction Fe/Al alloying element periodic layered structure

Published: 22 April 2021

CLC number:

TG142.7

Fund:National Natural Science Foundation of China (51701053,42066003), the Hainan Provincial Natural Science Foundation of China(420RC522,517076), the Central Government Guiding Special Funds for the Development of Local Science and Technology (ZY2018HN09-6).

About author:: Xianman Zhangreceived his Ph.D. degree in mate-rials processing engineering from South China Univer-sity of Technology in 2015. He is now an associate professor in Mechanical and Electrical Engineering College, Hainan University. His research interests are corrosion resistance of metallic materials.

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	ZHANG Xianman
	CHEN Zaiyu
	LUO Hongfeng

Cite this article:

ZHANG Xianman,CHEN Zaiyu,LUO Hongfeng. Influences of Alloying Elements on the Interfacial Reaction of Fe/Al: a Review[J]. Materials Reports, 2021, 35(7): 7145-7154.

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http://www.mater-rep.com/EN/10.11896/cldb.19100056 OR http://www.mater-rep.com/EN/Y2021/V35/I7/7145

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