硅藻土功能化及其应用

doi:10.11896/cldb.19070130

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Abstract Diatomite is an inorganic nonmetallic mineral material. Due to unique ordered pore structures, applications of diatomite have been realized in chemical engineering and building materials industries. The application of diatomite was usually limited by its specific surface area (about 18—28 m²/g). Through the functionalization, diatomite materials could be vested with a certain property, thus improving the performance in environment treatment and advancing applications in the field of energy and bioengineering. Therefore, functionalization of diatomite has become a research focus.
In recent years, researches on functionalization of diatomite mainly focus on three areas: noncovalent functionalization, covalent functionalization and chemical conversion of diatomite. Normally, noncovalent functionalization indicate that using nano metal oxides and metal oxygenates to modify diatomite and the functionalized diatomite can be used in the field of energy, water treatment and sensors. Covalent functionalization of diatomite refers to modifying diatomite with functional monomer through the connection of Si-O covalent bond based on Si-O tetrahedron and Si-OH of diatomite. Functional monomers are classified into silicates and silane coupling agents. Silane coupling agents connect to diatomite through Si-OH, and it could also be used to connect other functional groups to obtain excellent properties. Covalent functionalized diatomite is commonly used in the fields of energy, sensor and water treatment. The chemical conversion of diatomite to silicon source is the other functionalization met-hod. Silicon keeps the morphology of diatomite and can be used in the field of energy and bioengineering.
Functionalization of diatomite is the key to realize the application of diatomite materials in emerging fields. Therefore, researches on diatomite functionalization would advance the application of diatomite and promote the development of emerging areas. Here, the progress of diatomite functionalization at home and abroad in recent years are summarized. The functionalization routes and their applications are introduced in detail in order to provide reference for advanced diatomite functionalization routes and their applications.

Key words： diatomite functionalization noncovalent functionalization covalent functionalization chemical conversion

Published: 03 January 2020

CLC number:

TB34

Fund:This work was financially supported by the National Key R & D Program of China (2017YFB0310804), the National Natural Science Foundation of China (51974011), Key R & D Program of Ningxia Hui Autonomous Region (2019BFG02032).

About author:: Xuekai Wang received his B.E. degree in Materials Science and Engineering from Shandong Jianzhu University in 2013 and M.E. degree in Materials Science and Engineering from Beijing University of Technology in 2018. He is currently pursuing his Ph.D. at College of Materials Science and Engineering, Beijing University of Technology under the supervision of Prof. Jinshu Wang. His research has focused on functionalized dia-tomite and water treatment;Jinshu Wang,professor of Department of Materials Science & Engineering, Beijing University of Technology. She received her Ph.D. degree in Materials Science from Beijing University of Technology. From 2002 to 2004, she has been worked in Tohoku University, Japan, as a post-doctor. She was awarded the Distinguis-hed Professor of Chang Jiang Scholars Program by the Ministry of Education, China in 2015. She received National Science Fund for Distinguished Young Scholars in 2012, and China Youth Science and Technology Award authorized by the China Association for Science and Technology in 2011. Prof. Wang is the author of over 200 peer reviewed journal (Adv. Funct. Mater., Appl. Catal. B :Environ., J. Mater. Chem. A etc.) papers and 2 books. Her research interests encompass electron emission materials, renewable energy and environmental materials.

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	WANG Xuekai
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Cite this article:

WANG Xuekai,WANG Jinshu,DU Yucheng, et al. Functionalization of Diatomite and Its Applications[J]. Materials Reports, 2020, 34(3): 3017-3027.

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http://www.mater-rep.com/EN/10.11896/cldb.19070130 OR http://www.mater-rep.com/EN/Y2020/V34/I3/3017

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