| INORGANIC MATERIAL S AND CERAMIC MATRIX COMPOSITES |
|
|
|
|
|
| Research Progress on Light Alloy-Air Batteries |
| YAO Wanpeng1, CAO Fuyong2, LI Yan1, QI Jiantao3
|
1 College of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China
2 College of Materials, Xiamen University, Xiamen 361005, China
3 College of Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, China |
|
|
|
Abstract As a new form of energy, metal-air batteries have the advantages of high theoretical energy density, low price, good safety, wide range of temperature and so on. At present, there are four types of metal-air batteries which are popular and widely studied, including zinc-air battery, aluminum-air battery, lithium-air battery and magnesium-air battery.
Light alloy-air batteries use light alloy material with high energy density as anode, air electrode as cathode, alkaline or neutral salt solution as electrolyte, mainly including aluminum-air battery and magnesium-air battery. Aluminum and magnesium with high electrochemical capacity, low cost and abundant reserves are excellent candidate anode materials for metal-air batteries and regarded as a promising alternative to fossil fuels as an energy storage material. However, the performance of metal-air batteries using pure aluminum and pure magnesium is not good as expected at the beginning with enormous study problems. With the development of aluminum alloys and magnesium alloys, the application of light alloys in metal-air batteries greatly reduces the self-corrosion problem of metal anodes, improves the discharge activity of electrode and the overall performance of battery is significantly enhanced. For aluminum-air battery, the corrosion rate of the aluminum alloy electrode decreases due to the doping of Sn, In, Ga, Mg and other elements, while the utilization rate of the anode increases and the passivation film on the electrode surface is destroyed which achieves the activation effect. In the case of magnesium-air battery, Al, Zn, Mn, Li and other alloying elements can improve the corrosion resistance and the discharge capacity of batteries is also improved. The addition of some rare earth elements can refine the grain of light alloys and improve the corrosion and passivation problems of light alloy electrodes.
This paper introduces the basic principles of metal-air batteries, describes the performance of two types of light alloy-air batteries, analyzes the main problems existing in metal-air batteries and briefly introduces the solutions. This paper mainly focuses on the alloying mode of the anode of the battery and the performance of various light alloys in the batteries. The corrosion reasons and control measures in light alloy-air batteries are summarized and prospected.
|
|
Published: 24 June 2020
|
|
|
| Fund:National Natural Science Foundation of China (51701239), the Shandong Provincial Natural Science Foundation, China (ZR2017LEM005), and the Fundamental Research Funds for the Central Universities (18CX02128A) |
About author:: Wanpeng Yaoreceived his B.E. degree from the College of Materials Science and Engineering, China University of Petroleum (East China) in 2015 and master degree from the College of Materials Science and Engineering, China University of Petroleum (East China) in 2018. He is currently pursuing his doctor’s degree at Materials Science and Engineering, China University of Petroleum (East China) under the supervision of Prof. Yan Li and associate professor Jiantao Qi. His research was funded by the NSFC project of “Multiscale Characterization and Controllable Preparation of Functional Conversion Coatings on Magnesium Alloys”.
Yan Lireceived his B.S. and Ph.D. degrees in metallurgy of nonferrous metals from Northeastern University in 1995 and 2000, respectively. After one-year postdoctoral research at Institute of Oceanography, Chinese Academy of Sciences, he became a researcher and doctoral supervisor in 2001 and 2004, respectively. Then he won the First Prize of Shandong Provincial Science and Technology Progress Award in 2001 and the First hundred outstanding introduced talents of Qingdao in 2002. In December 2004, he visited Tokyo Institute of Technology (Japan) as a scholar. In December 2009, he was appointed as the professor of China University of Petroleum (East China) and then as the doctoral supervisor in January 2010. He was the deputy secretary general of Shandong and Qingdao Society for Corrosion and Protection and the deputy director of Specialized Committee of Water Treatment and Organic Heat Carrier, Shandong Special Equipment Society in 2014 and 2015, respectively. In 2017, he was selected as the vice chairman of Specialized Committee of Corrosion and Protection in Oil and Gas Fields and Pipeline, Chinese Society for Corrosion and Protection. His research interest is corrosion electrochemistry, including marine corrosion, environmentally sensitive fracture, anticorrosive coatings, corrosion inhibitors, corrosion monitoring and mathematical modeling.
Jiantao Qireceived his bachelor degree in the College of Chemical Engineering, China University of Petro-leum (CUP, East China) in 2011 and the doctoral degree from Corrosion and Protection Centre, School of Materials, University of Manchester in 2015. He has rich engineering and research experience as an independent postdoc researcher, competing the LATEST 2 project with Prof. George Thompson (OBE, RAE Fellow) at University of Manchester and the NEPAL FUI project in the PCS lab (ENSCP-CNRS) with cooperation of Prof. Philippe Marcus. He started as a lecture in the CUP at June 2016 and was promoted to be a full associate professor and supervisor of master students at Dec. 2017. His research focuses on corrosion and protection of alloys, including surface modification, functional conversion coatings, physics and chemistry at the surface and interface, SERS Raman, XPS, RBS, electrochemical assessments and corrosion protection strategy. |
|
|
1 Li H, Gao Y, Sui X L, et al. Carbon, 2017(2), 5(in Chinese).
李华, 高颖, 隋旭磊, 等. 炭素, 2017(2), 5.
2 Reddy T B, Linden D. Linden’s handbook of batteries, McGraw-Hill, USA, 2010.
3 Wang Z W, Li Q F, Gao B L, et al. Non-ferrous Mining and Metallurgy, 2002, 18(1), 38(in Chinese).
王兆文, 李庆峰, 高炳亮, 等.有色矿冶, 2002, 18(1), 38.
4 Zhu M J, Yuan Z S, Sang L, et al. Chinese Journal of Power Sources, 2012, 36(12), 1953(in Chinese).
朱明骏, 袁振善, 桑林, 等.电源技术, 2012, 36(12), 1953.
5 Zhao Y Z, Hu C L, Luo Z H, et al. Materials Reprots, 2017, 31(S1), 215(in Chinese).
赵玉振, 胡承亮, 罗志虹, 等.材料导报, 2017, 31(专辑29), 215.
6 Tan P, Jiang H R, Zhu X B, et al. Applied Energy, 2017, 204, 780.
7 Wang T H, Hang Y, Zhang D W. Journal of Hefei University of Technology, 2018, 41(10), 1420(in Chinese).
王桃环, 杭阳, 张大伟.合肥工业大学学报(自然科学版), 2018, 41(10), 1420.
8 Wu Z B, Song S S, Dong A, et al. Materials Reprots A: Review Papers, 2019, 33(1), 135(in Chinese).
吴子彬, 宋森森, 董安, 等.材料导报:综述篇, 2019, 33(1), 135.
9 Zhang D, Zhang C Z, Mu D B, et al. Chemical Industry and Engineering Progress, 2012, 24(12), 2472(in Chinese).
张栋, 张存中, 穆道斌, 等.化学进展, 2012, 24(12), 2472.
10 Gu D M, Wang Y, Gu S, et al. Acta Chimica Sinica, 2013, 71(10), 1354(in Chinese).
顾大明, 王余, 顾硕, 等.化学学报, 2013, 71(10), 1354.
11 Girishkumar G, McCloskey B, Luntz A C, et al. The Journal of Physical Chemistry Letters, 2010, 1(14), 2193.
12 Yu Q, Li M L, Ma L, et al. Ordnance Material Science and Engineering, 2019, 42(1), 95(in Chinese).
余琼, 李明利, 马兰, 等.兵器材料科学与工程, 2019, 42(1), 95.
13 Zhang T, Tao Z, Chen J. Materials Horizons, 2014, 1(2), 196.
14 Cui L J. The preparation and performance of catalysts of oxygen electrode in lithium-air batteries. Master’s Thesis, Taiyuan University of Science and Technology, China, 2018(in Chinese).
崔雷杰. 锂空气电池氧气电极催化剂的制备及其性能研究. 硕士学位论文, 太原科技大学, 2018.
15 Zhao S N, Li A H. Chinese Journal of Power Sources, 2014, 38(10), 1969(in Chinese).
赵少宁, 李艾华.电源技术, 2014, 38(10), 1969.
16 Ren X Y. Battery Bimonthly, 1994, 24(6), 284(in Chinese).
任学佑.电池, 1994, 24(6), 284.
17 Shi P F, Yin G P, Xia B J, et al. Journal of Power Sources, 1993, 45(1), 105.
18 Tuck C D S, Hunter J A, Scamans G M. Journal of the Electrochemical Society, 1987, 134(12), 2970.
19 Egan D R, Ponce de León C, Wood R J K, et al. Journal of Power Sources, 2013, 236, 293.
20 Keir D S, Pryor M J, Sperry P R. Journal of the Electrochemical Society, 1967, 114(8), 777.
21 Doche M L, Novel-Cattin F, Durand R, et al. Journal of Power Sources, 1997, 65(1), 197.
22 Smoljko I, Gudić S, Kuzmanić N, et al. Journal of Applied Electroche-mistry, 2012, 42(11), 969.
23 Ma J L, Wen J B, Li G F, et al. Heat Treatment of Metals, 2008, 33(8), 57(in Chinese).
马景灵, 文九巴, 李光福, 等.金属热处理, 2008, 33(8), 57.
24 Choi Y, Kalubarme R S, Jang H, et al. Korean Journal of Metal Mate-rial, 2011, 49(11), 839.
25 You W, Lin S Y. Aluminium Fabrication, 1998, 21(5), 35(in Chinese).
游文, 林顺岩.铝加工, 1998, 21(5), 35.
26 Gudić S, Smoljko I, Kliškić M. Journal of Alloys and Compounds, 2010, 505(1), 54.
27 Gudić S, Smoljko I, Kliškić M. Materials Chemistry and Physics, 2010, 121(3), 561.
28 Bockris J O, Conway B E, Yeager E, et al. Comprehensive treatise of electrochemistry, Plenum Press, USA, 1981.
29 Macdonald D D, Lee K H, Moccari A, et al. Corrosion, 1988, 44(9), 652.
30 Wilhelmsen W, Arnesen T, Hasvold Ø, et al. Electrochimica Acta, 1991, 36(1), 79.
31 Cui J L. Investigations on the aluminum alloying for aluminum-air battery. Master’s Thesis, Tianjin University, China, 2016(in Chinese).
霍佳磊. 铝-空气电池用铝合金负极的合金化研究. 硕士学位论文, 天津大学, 2016.
32 Ma J, Wen J, Zhu H, et al. Journal of Power Sources, 2015, 293, 592.
33 Wen J B, Gao J W, He J G, et al. Transactions of Materials and Heat Treatment, 2014, 35(9), 131(in Chinese).
文九巴, 高军伟, 贺俊光, 等. 材料热处理学报, 2014, 35(9), 131.
34 Ma J, Wen J, Gao J, et al. Journal of Power Sources, 2014, 253, 419.
35 Tang Y G, Han H T, Xie Z H. Journal of Central South University (Scie-nce and Technology), 2006, 37(4), 737(in Chinese).
唐有根, 韩红涛, 谢正和.中南大学学报(自然科学版), 2006, 37(4), 737.
36 Qi G T, Zhang Y Y. Chinese Journal of Rare Metals, 2004, 28(6), 1010(in Chinese).
齐公台, 张盈盈.稀有金属, 2004, 28(6), 1010.
37 Mao Z W. Study on aluminum alloy anode for alkaline power battery. Master’s Thesis, Central South University, China, 2009(in Chinese).
毛志伟. 碱性动力电池铝合金阳极研究. 硕士学位论文, 中南大学, 2009.
38 Shi C X, Li H D, Wang D Z, et al. Materials Reprots, 2001, 15(4), 5(in Chinese).
师昌绪, 李恒德, 王淀佐, 等.材料导报, 2001, 15(4), 5.
39 Mu W Y, Li Z X, Du J H, et al. Materials Reprots A: Review Papers, 2011, 25(7), 35(in Chinese).
慕伟意, 李争显, 杜继红, 等.材料导报:综述篇, 2011, 25(7), 35.
40 Deng S H, Yi D Q, Lan B, et al. Chinese Journal of Power Sources, 2008, 32(8), 508(in Chinese).
邓姝皓, 易丹青, 兰博, 等.电源技术, 2008, 32(8), 508.
41 Song G, Atrens A, John D S, et al. Corrosion Science, 1997, 39(10), 1981.
42 Wang N G. Research on electrochemical behavior of AP65 magnesium alloy in sodium chloride solution. Master’s Thesis, Central South University, China, 2013(in Chinese).
王乃光. AP65镁合金在氯化钠溶液中电化学行为研究. 硕士学位论文, 中南大学, 2013.
43 Lin M C, Tsai C Y, Uan J Y. Corrosion Science, 2009, 51(10), 2463.
44 Liu W, Cao F, Chang L, et al. Corrosion Science, 2009, 51(6), 1334.
45 Ma Y, Li N, Li D, et al. Journal of Power Sources, 2011, 196(4), 2346.
46 Gao S. Studying of performance of rare earth-magnesium anode for magnesium air battery. Master’s Thesis, Henan University of Technology, China, 2017(in Chinese).
高顺. 稀土镁合金负极对镁空气电池性能影响研究. 硕士学位论文, 河南工业大学, 2017.
47 Liu X, Xue J, Zhang P, et al. Journal of Power Sources, 2019, 414, 174.
48 Wang N, Wang R, Peng C, et al. Electrochimica Acta, 2014, 149, 193.
49 Yuasa M, Huang X, Suzuki K, et al. Journal of Power Sources, 2015, 297, 449.
50 Xiong H, Yu K, Yin X, et al. Journal of Alloys and Compounds, 2017, 708, 652.
51 Liu X, Liu S, Xue J. Journal of Power Sources, 2018, 396, 667.
52 Deng M, Höche D, Lamaka S V, et al. Journal of Power Sources, 2018, 396, 109.
53 Dražić D M, Popić J P. Journal of Applied Electrochemistry, 1999, 29(1), 43.
54 Cho Y J, Park I J, Lee H J, et al. Journal of Power Sources, 2015, 277, 370.
55 Li B Y, Dong Q, Zhang J, et al. Materials China, 2016, 35(11), 849(in Chinese).
李碧谕, 东青, 张佼, 等.中国材料进展, 2016, 35(11), 849.
56 Li H M. Study on corrosion inhibitor of magnesium air battery electrolyte. Master’s Thesis, Kunming University of Science and Technology, China, 2017(in Chinese).
李慧明. 镁空气电池电解液缓蚀剂的研究. 硕士学位论文, 昆明理工大学, 2017.
57 Hong W C, Ma H Y, Zhao H B, et al. Chemical Industry and Enginee-ring Progress, 2016, 35(6), 1713(in Chinese).
洪为臣, 马洪运, 赵宏博, 等.化工进展, 2016, 35(6), 1713.
58 Brito P S D, Sequeira C A C. Journal of Fuel Cell Science and Technology, 2013, 11(1), 011008.
59 Wang C, Qiu P D, Cai K D, et al. Chemical Industry and Engineering Progress, 2016, 35(5), 1396(in Chinese).
王诚, 邱平达, 蔡克迪, 等.化工进展, 2016, 35(5), 1396.
60 Deng J F. The influence of magnesium anode with different processing conditions and inhibitor on magnesium air battery. Master’s Thesis, Chongqing University, China, 2013(in Chinese).
邓金凤. 镁负极加工状态与缓蚀剂对镁空气电池的影响. 硕士学位论文, 重庆大学, 2013.
61 Ma X L, Gao S, Zhou Y. Chinese Journal of Power Sources, 2017, 41(2), 331(in Chinese).
马晓录, 高顺, 周颖.电源技术, 2017, 41(2), 331.
62 Fan L, Lu H. Journal of Power Sources, 2015, 284, 409.
63 Fan L, Lu H, Leng J. Electrochimica Acta, 2015, 165, 22.
64 He J G, Wen J B, Zhou X D, et al. Corrosion Science and Protection Technology, 2013, 25(3), 229(in Chinese).
贺俊光, 文九巴, 周旭东, 等.腐蚀科学与防护技术, 2013, 25(3), 229.
65 Deng J F, Huang G S, Zhao Y C, et al. Rare Metal Materials and Engineering, 2014, 43(2), 316.
66 Yao Y F, Chen C G, Liu Y P, et al. Materials Reprots A: Review Papers, 2009, 23(10), 119(in Chinese).
尧玉芬, 陈昌国, 刘渝萍, 等.材料导报:综述篇, 2009, 23(10), 119.
67 Bartolomé M J, del Río J F, Escudero E, et al. Surface and Coatings Technology, 2008, 202(12), 2783.
68 Li Q, Bjerrum N J. Journal of Power Sources, 2002, 110(1), 1.
69 Chen L. Research on the anodic corrosion film-forming process and vol-tage delay of magnesium battery. Master’s Thesis, Chongqing University, China, 2015(in Chinese).
陈琳. 镁电池的负极腐蚀成膜与电压滞后研究. 硕士学位论文,重庆大学, 2015.
70 Hu Q M, Zhang Y, Chen Q R, et al. Chinese Journal of Power Sources, 2015, 39(1), 210(in Chinese).
胡启明, 张娅, 陈秋荣.电源技术, 2015, 39(1), 210.
71 Xiong Y Y, Zhang Y, Hu S F, et al. Journal of Chinese Society for Corrosion and Protection, 2013, 33(3), 241(in Chinese).
熊媛媛, 张娅, 胡少峰, 等.中国腐蚀与防护学报, 2013, 33(3), 241.
72 Zhang W B. Chinese Journal of Power Sources, 2002, 26(6), 448(in Chinese).
张文保.电源技术, 2002, 26(6), 448. |
|
|
|
渝公网安备50019002502923号 © Editorial Office of Materials Reports.
2020, Vol. 34 
