水系锌离子电池负极材料的研究进展

doi:10.11896/cldb.19050206

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Abstract Secondary batteries have been widely applied due to their high energy density, wide electrochemical window, and highly reversible cycle, however, the organic electrolytes of traditional secondary batteries are expensive, flammable and toxic. Compared with organic electrolytes, aqueous electrolytes have the advantages of high ionic conductivity, high power density, simple manufacturing and low cost. Therefore, researchers pay more attentions to novel secondary aqueous batteries which using a neutral or weakly acidic inorganic-salt aqueous solution as electrolyte. In particular, metal zinc has been considered as promising anode material for large-scale energy storage owing to its abundant reserves, nontoxicity, low redox potential (-0.76 V) and high theoretical capacity (820 mAh·g^-1). Hence, the rechargeable aqueous zinc ion batteries (AZIBs) is extremely attractive in recent years.
In fact, AZIBs still face the problems of the zinc dendritic, low plating/stripping columbic efficiency and insufficient utilization of zinc anode. The zinc dendritic usually originate from uneven Zn²⁺ distribution on the Zn foil, while low coulombic efficiency is caused by hydrogen evolution reaction of zinc electrode and generation of irreversible side-products. At present, the optimization of zinc anode materials for AZIBs have been focused on the following four points: (ⅰ) Optimizing the structure of the zinc electrode. Zinc negative electrode with 3D or porous type structure have more sites for zinc deposition/dissolution and limit the growth of zinc dendrite. (ⅱ) Application of additives. Adding inorganic or organic substances to the negative electrode material, which could change the hydrogen evolution potential, corrosion potential and polarization behavior of zinc, reduces hydrogen evolution corrosion of zinc and the formation of side-products, etc. (ⅲ) Formation of the functional protection layer. The protection layer is beneficial to the uniform deposition/dissolution of zinc and inhibits the growth of zinc dendrites. (ⅳ) Introducing the conductive material. On the one hand, the addition of a conductive material to the zinc negative electrode can improve the conductivity of the electrode; on the other hand, it will make for the uniform deposition/dissolution of zinc. These methods of modifying the zinc negative electrode can increase the stability of the anode material, so that the cycle stability and coulombic efficiency of AZIBs are effectively improved.
Firstly, this paper briefly introduces the structure and working principles of the AZIBs. Secondly, the research progress of anode materials for AZIBs has been mainly discussed by the following chapters,including the challenges and optimization strategies of zinc anode materials. Finally, this paper has made a promising prospect for the development of anode materials for AZIBs, which will provide important ideas for the preparation of zinc anode materials.

Key words： aqueous zinc ion battery zinc anode materials energy storage zinc dendritic

Published: 24 June 2020

CLC number:

TQ15

Fund:National Natural Science Foundation of China (51771071), and the Guidance Project of Scientific Research Program from Hubei Provincial Department of Education (B2019046)

About author:: Binxu Lanreceived his B.S. degree in Zhengzhou University of Aeronautics in 2017. He is currently pursuing his M.S. degree at the School of Materials and Chemical Engineering, Hubei University of Technology under the supervision of Prof. Shijie Dong. His research has focused on aqueous zinc ion battery electrode material.
Wenwei Zhangreceived his B.E. degree in Materials Science and Engineering from Hubei University of Automotive Technology in June 2018. He is currently a postgraduate in the School of Materials and Chemical Engineering, Hubei University of Technology. He is under the supervision of Prof. Shijie Dong and Ph.D Ping Luo. His research interest is the development of electrode materials for aqueous rechargeable zinc ion batteries.
Ping Luo, lecturer of Hubei University of Technology, received his Ph.D. degree in material processing engineering from Huazhong University of Science and Technology in June 2015. He worked in Hubei University of Technology in the same year. He is mainly engaged in research on new energy materials and has published more than 20 articles in important journals at home and abroad, and has applied for more than 30 invention patents.

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	LAN Binxu
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	ZUO Chunli
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Cite this article:

LAN Binxu,ZHANG Wenwei,LUO Ping, et al. Research Progress on Anode Materials for Aqueous Zinc-ion Batteries[J]. Materials Reports, 2020, 34(13): 13068-13075.

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http://www.mater-rep.com/EN/10.11896/cldb.19050206 OR http://www.mater-rep.com/EN/Y2020/V34/I13/13068

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