| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Research Progress of Geopolymer Cementitious Material Modification for Improving Durability of Concrete |
| WANG Aiguo1, ZHENG Yi1, ZHANG Zuhua2, LIU Kaiwei1, MA Rui1, SUN Daosheng1
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1.Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei 230022
2.Key Laboratory for Green & Advanced Civil Engineering Materials and Application Technology of Hunan Province, College of Civil Engineering, Hunan University, Changsha 410082 |
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Abstract Geopolymers belong to the family of cementitious materials that are formed by reaction between solids with pozzolanic activity or hydraulicity potential and alkaline activator. In the past years extensive researches have shown the advantages over traditional Portland cement-based materials in the following aspects: mechanical properties, high temperature stability, sulfate resistance and corrosion resistance. However, some technical problems still remain, including low carbonization resistance and large drying shrinkage, limiting the application in construction engineering.
Geopolymers have large volume shrinkage during geopolymerization, and are prone to form microcracks, which become channels for outside ions, thus reduce impermeability and durability of geopolymer. During carbonization, CO2 dissolved in pore solution and reacts with alkali activated slag (AAS) product C-(A)-S-H gels to form CaCO3, which can destroy the structure of geopolymer product. N-A-S-H gels are the main products of fly ash-based geopolymer which have no decalcification reaction during carbonization. Carbonization lower the pH of pore solution, and change the stable environment of products.
From the perspectives of composition and structure modification, this paper reviews the latest research progresses of using MgO, LDHs, nanoparticles and improved curing methods, and clarifies the mechanisms of modification of geopolymer gelling materials to improve concrete durability. MgO reacts with water to form expansion component Mg(OH)2, which can effectively compensate geopolymer drying shrinkage and self-shrinkage. Moreover, MgO participate in geopolymerization to produce hydrotalcite, which improves the carbonization resistance. LDHs have interlayer ion exchange ability and the replacement between outside and inside ions reduces the attack of erosive ions on geopolymer. Nanoparticles have nucleation and particle filling functions, refining the pore structure of geopolymer. Silica-alumina nanoparticles also participate in geopolyme-rization and facilitate a more compact structure. High temperature (autoclave) curing can promote geopolymerization, improve the pore structure, reduce the generation of microcracks and the permeability of geopolymer.
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Published: 02 July 2019
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| Fund:This work was financially supported by the Natural Science Foundation of China (51778003, 51878263), Opening Foundation of State Key Laboratory of High Performance Civil Engineering Materials (2018CEM002), Anhui Province Higher Education Revitalization Program ([2014] No.11), Anhui Provincial Education Department (gxfxZD2016134) and National Speciality Comprehensive Reform Pilot Project (ZG0241). |
|
|
| [1] |
Shi C J, Jiménez A F, Palomo A. Cement and Concrete Research,2011,41(7),750.
|
| [2] |
Zhang Z H, Synthesis, performances and reaction mechanism of meta-kaolin-based geopolymer. Ph.D. Thesis, Nanjing University of Technology,China,2010(in Chinese).
|
|
张祖华.偏高岭土基无机聚合物的制备,性能与反应机理.博士学位论文,南京工业大学,2010.
|
| [3] |
Adamiec P, Benezet J C, Benhassaine A. Particuology,2008,6(2),93.
|
| [4] |
Lothenbach B, Scrivener K, Hooton R D. Cement and Concrete Research,2011,41(12),1244.
|
| [5] |
Luukkonen T, Abdollahejad Z, Yliniemi J, et al. Cement and Concrete Research,2018,103,21.
|
| [6] |
Provis J L. Cement and Concrete Research,2018,114,40.
|
| [7] |
Xu H, Van D J S J. International Journal of Mineral Processing,2000,59(3),247.
|
| [8] |
Glukhovsky V D. Slag-alkali concretes produced from fine-grained aggregate, Vishcha Shkolay Press, Ukraine,1981.
|
| [9] |
Fang X W, Shen C N, Yang D B, et al. Journal of Building Materials,2007,10(1),89(in Chinese).
|
|
方祥位,申春妮,杨德斌,等.建筑材料学报,2007,10(1),89.
|
| [10] |
Liu K, Mo L, Deng M. Advances in Cement Research,2015,27(8),1.
|
| [11] |
Liu K, Deng M, Mo L, et al. Advances in Cement Research,2015,27(8),477.
|
| [12] |
Shen X D, Li Z J, Cement and concrete for marine applications, Chemical Industry Press, China,2016(in Chinese).
|
|
沈晓东,李宗津.海洋工程水泥与混凝土材料,化学工业出版社,2016.
|
| [13] |
Dunuzovic＇ N, Komljenovic＇ M, Nikolic＇ V, et al. Construction and Buil-ding Materials,2017,157,737.
|
| [14] |
Ismail I, Bernal S A, Provis J L, et al. Materials and Structures,2013,46(3),361.
|
| [15] |
Elyamany H E, Elmoaty A E M A, Elshaboury A M. Construction and Building Materials,2018,184,111.
|
| [16] |
Jin M T, Chen Y, Dong H L. Journal of Zhejiang University of Technology,2013,41(6),596(in Chinese).
|
|
金漫彤,陈颖,董海丽.浙江工业大学学报,2013,41(6),596.
|
| [17] |
Sata V, Sathonsaowaphak A, Chindaprasirt P. Cement and Concrete Composites,2012,34(5),700.
|
| [18] |
Alexander M, Bertron A, Belie N D. Performance of cement-based mate-rials in aggressive aqueous environments, Springer Netherlands Press, Germany,2013.
|
| [19] |
Bouguermouh K, Bouzidi N, Mahtout L, et al. Journal of Non-Crystalline Solids,2017,463,128.
|
| [20] |
Gao X X, Michaud P, Joussein E, et al. Journal of Non-Crystalline Solids,2013,380(12),95.
|
| [21] |
Koenig A, Herrmann A, Overmann S, et al. Construction and Building Materials,2017,151,405.
|
| [22] |
Jin M, Zheng Z, Sun Y, et al. Journal of Non-Crystalline Solids,2016,450,116.
|
| [23] |
Melo A A, Cincotto M A, Repette W L. Cement and Concrete Research,2008,38(4),565.
|
| [24] |
Collins F, Sanjayan J G. Cement and Concrete Research,2000,30(5),791.
|
| [25] |
Pavel R. Construction and Building Materials,2010,24(7),1176.
|
| [26] |
Zhang H Y, Kodur V, Wu B, et al. Construction and Building Materials,2018,163,277.
|
| [27] |
Peng H, Chen Z K, Cui C, et al. Journal of Building Materials,2017,20(3),63(in Chinese).
|
|
彭晖,陈治坤,崔潮,等.建筑材料学报,2017,20(3),63.
|
| [28] |
Fu X H, Tao W H, Sun F J. Cement Engineering,2008(2),6(in Chinese).
|
|
付兴华,陶文宏,孙凤金.水泥工程,2008(2),6.
|
| [29] |
Liu D J, Wu X, Li J H, et al. Chinese Journal of Environmental Engineering,2018,12(8),229(in Chinese).
|
|
刘道洁,吴新,李军辉,等.环境工程学报,2018,12(8),229.
|
| [30] |
Peng H, Li S L, Cai C S, et al. Bulletin of the Chinese Ceramic Society,2014,33(11),2809(in Chinese).
|
|
彭晖,李树霖,蔡春声,等.硅酸盐通报,2014,33(11),2809.
|
| [31] |
Zhang S Z, Tian Q, Lu A Q. New Building Materials,2016,43(9),22(in Chinese).
|
|
张守治,田倩,陆安群.新型建筑材料,2016,43(9),22.
|
| [32] |
Zhang Y. Study on shrinkage expansion behavior and durability of magnesia concrete.Master’s Thesis, Ningxia University, China,2014(in Chinese).
|
|
张莹.氧化镁混凝土收缩膨胀行为及耐久性研究.硕士学位论文,宁夏大学,2014.
|
| [33] |
Chen C L, Li C M. Concrete,2006(5),45(in Chinese).
|
|
陈昌礼,李承木.混凝土,2006(5),45.
|
| [34] |
Chen X, Yang H Q, Li J Z. Yangtze River,2011,42(4),88(in Chinese).
|
|
陈霞,杨华全,李家正.人民长江,2011,42(4),88.
|
| [35] |
Roy D M. Cement and Concrete Research,1999,29(2),249.
|
| [36] |
Liu S Y, Cao J J, Cai G H, et al. China Journal of Highway and Transport,2018,31(8),30(in Chinese).
|
|
刘松玉,曹菁菁,蔡光华,等.中国公路学报,2018,31(8),30.
|
| [37] |
Bernal S A, Provis J L, Walkley B, et al. Cement and Concrete Research,2013,53(2),127.
|
| [38] |
De Vries P, Midden C, Bouwhuis D. Fuel,2005,84(16),2048.
|
| [39] |
Li Z H, Yang Y M, Chen X W, et al. Journal of Yangtze River Scientific Research Institute,2018,35(7),131(in Chinese).
|
|
李兆恒,杨永民,陈晓文,等.长江科学院院报,2018,35(7),131.
|
| [40] |
Li C C, Shi H, Zhou W L, et al. Bulletin of the Chinese Ceramic Society,2016,35(2),632(in Chinese).
|
|
李超超,师华,周文良,等.硅酸盐通报,2016,35(2),632.
|
| [41] |
Krizan D, Zivanovic B. Cement and Concrete Research,2002,32(8),1181.
|
| [42] |
Collins F, Sanjayan J G. Cement and Concrete Research,1999,29(4),607.
|
| [43] |
Li Y, Sun Y. Cement and Concrete Research,2000,30(6),963.
|
| [44] |
Jin F, Gu K, Al-Tabbaa A. Construction and Building Materials,2014,51(4),395.
|
| [45] |
Bernal S A, Nicolas R S, Myers R J, et al. Cement and Concrete Research,2014,57(3),33.
|
| [46] |
Shan J X, Chen W, Tian Y P, et al. Journal of Wuhan University of Technology,2015,37(1),10(in Chinese).
|
|
单继雄,陈伟,田亚坡,等.武汉理工大学学报,2015,37(1),10.
|
| [47] |
Chen W, Chen X X, Duan P. In:the Chinese Ceramic Society Cement Branch Academic Annual Meeting. Beijing,2012(in Chinese).
|
|
陈伟,陈晓星,段平.中国硅酸盐学会水泥分会学术年会.北京,2012.
|
| [48] |
Jang J G, Park S M, Kim G M, et al. Construction and Building Mate-rials,2017,151,178.
|
| [49] |
Abdalqader A F, Jin F, Al-Tabbaa A. Construction and Building Mate-rials,2015,93,506.
|
| [50] |
Yan H, Ran Q P, Shu X, et al. Materials China,2017,36(9),645(in Chinese).
|
|
严涵,冉千平,舒鑫,等.中国材料进展,2017,36(9),645.
|
| [51] |
Wang S D, Huang Y B, Wang Z. Journal of the Chinese Ceramic Society,2000,28(6),570(in Chinese).
|
|
王绍东,黄煜镔,王智.硅酸盐学报,2000,28(6),570.
|
| [52] |
Xie Y J, Ma K L, Long G C, et al. Journal of the Chinese Ceramic Society,2006,34(11),1345(in Chinese).
|
|
谢友均,马昆林,龙广成,等.硅酸盐学报,2006,34(11),1345.
|
| [53] |
Jorge O N, Pablo G J, Srubar W V. Construction and Building Materials,2018,186,191.
|
| [54] |
Ke X Y, Bernal S A, Provis J L. Cement and Concrete Research,2017,100,1.
|
| [55] |
Yoon H N, Park S M,Lee H K. Construction and Building Materials,2018,178,584.
|
| [56] |
Duan P, Chen W, Ma J, et al. Construction and Building Materials,2013,48,601.
|
| [57] |
Duan P, Yan C J, Chen W, et al. Journal of the Chinese Ceramic Society,2014,42(8),1037(in Chinese).
|
|
段平,严春杰,陈伟,等.硅酸盐学报,2014,42(8),1037.
|
| [58] |
Shui Z H, Yu R, Chen Y X, et al. Construction and Building Materials,2018,176,228.
|
| [59] |
Duan P, Yan C, Zhou W. Construction and Building Materials,2018,160,725.
|
| [60] |
Ma J, Duan P, Ren D, et al. Journal of Materials Research and Technology,2018,8(1),292.
|
| [61] |
Chen Y, Yu R, Wang X, et al. Construction and Building Materials,2018,177,51.
|
| [62] |
Qu Z Y, Yu Q L, Brouwers H J H. Cement and Concrete Research,2018,105,81.
|
| [63] |
Wu Y, Duan P, Yan C. Applied Clay Science,2018,158,123.
|
| [64] |
Chen G W, Shui Z H, Duan P, et al. Journal of Wuhan University of Technology,2014,36(8),1(in Chinese).
|
|
陈国玮,水中和,段平,等.武汉理工大学学报,2014,36(8),1.
|
| [65] |
Wang A G, Lv B C, Duan P, et al. Materials Review B: Research Papers,2018,32(5),1707(in Chinese).
|
|
王爱国,吕邦成,段平,等.材料导报:研究篇,2018,32(5),1707.
|
| [66] |
Chen Y X, Shui Z H, Chen W, et al. Bulletin of the Chinese Ceramic Society,2015,34(7),1968(in Chinese).
|
|
陈宇轩,水中和,陈伟,等.硅酸盐通报,2015,34(7),1968.
|
| [67] |
Duan P. Research on modification mechanism and the application of layered double hydroxides for durability of concrete. Ph.D. Thesis, Wuhan University of Technology, China,2014(in Chinese).
|
|
段平.层状双氢氧化物改善混凝土耐久性能的机理及应用研究.博士学位论文,武汉理工大学,2014.
|
| [68] |
Wang L G, Zhang S P, Li D X. Bulletin of the Chinese Ceramic Society,2016,35(7),2128(in Chinese).
|
|
王立国,张树鹏,李东旭.硅酸盐通报,2016,35(7),2128.
|
| [69] |
Li G S, Gao G, Zhu J P, et al. New Chemical Materials,2018,46(6),15(in Chinese).
|
|
李根深,高戈,朱建平,等.化工新型材料,2018,46(6),15.
|
| [70] |
Mohammad B, Alireza J, Fadi A. Construction and Building Materials,2018,181,27.
|
| [71] |
Wang D, Zhang W, Ruan Y, et al. Construction and Building Materials,2018,189,487.
|
| [72] |
Ardalan R B, Jamshidi N, Arabameri H, et al. Construction and Building Materials,2017,146,128.
|
| [73] |
Jalal M, Fathi M, Farzad M. Mechanics of Materials,2013,61,11.
|
| [74] |
Senff L, Hotza D, Lucas S, et al. Materials Science and Engineering: A (Structural Materials: Properties, Microstructure and Processing),2012,532,354.
|
| [75] |
Land G, Stephan D. Journal of Materials Science,2012,47(2),1011.
|
| [76] |
Guo X L, Shi H S, Xia M. Journal of Functional Materials,2016,47(11),1(in Chinese).
|
|
郭晓潞,施惠生,夏明.功能材料,2016,47(11),1.
|
| [77] |
Gao K, Lin K L, Wang D Y, et al. Construction and Building Materials,2014,53(4),503.
|
| [78] |
Revathi T, Jeyalakshmi R, Rajamane N P. Applied Surface Science,2018,449,322.
|
| [79] |
Panias D, Giannopoulou I P, Perraki T. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2007,301(1-3),246.
|
| [80] |
Guo X L, Shi H S, Dong W J. Cement Technology,2014(2),30(in Chinese).
|
|
郭晓潞,施惠生,董文靖.水泥技术,2014(2),30.
|
| [81] |
Deb P S, Sarker P K, Barbhuiya S. Cement and Concrete Composites,2016,72,235.
|
| [82] |
Adak D, Sarkar M, Mandal S. Construction and Building Materials,2014,70,453.
|
| [83] |
Kaur M, Singh J, Kaur M. Construction and Building Materials,2018,190,672.
|
| [84] |
Behfarnia K, Rostami M. Construction and Building Materials,2017,131,205.
|
| [85] |
Yang L Y. The modification of microstructure and properties of alkali activated slag.Master’s Thesis, Southeast University, China,2015(in Chinese).
|
|
杨凌艳.碱激发矿渣微结构优化及性能研究.硕士学位论文,东南大学,2015.
|
| [86] |
Deb P S, Nath P, Sarker P K. Materials and Design,2014,62(62),32.
|
| [87] |
Bakharev T. Cement and Concrete Research,2005,35(6),1233.
|
| [88] |
Xie Z L, Li X. Concrete,2014(6),55(in Chinese).
|
|
谢子令,李显.混凝土,2014(6),55.
|
| [89] |
Zuo L P, Meng H N, Xu Y M, et al. Ready-mixed Concrete,2018(5),43(in Chinese).
|
|
左李萍,蒙海宁,许彦明,等.商品混凝土,2018(5),43.
|
| [90] |
Shi D, Zhang W S, Ye J Y, et al. Journal of the Chinese Ceramic Society,2017(8),44(in Chinese).
|
|
史迪,张文生,叶家元,等.硅酸盐学报,2017(8),44.
|
| [91] |
Zhang Z, Provis J L, Ma X, et al. Cement and Concrete Composites,2018,92,165.
|
| [92] |
Kani E N, Allahverdi A, Provis J L. Cement and Concrete Composites,2012,34(1),25.
|
| [93] |
Zhang Z, Provis J L, Reid A, et al. Cement and Concrete Research,2014,64(10),30.
|
| [94] |
Jiao X K, Cao Z M, Li T, et al. Non-Metallic Mines,2016,39(4),59(in Chinese).
|
|
焦向科,曹志明,李涛,等.非金属矿,2016,39(4),59.
|
| [95] |
Jiang Z P, Ming W. Journal of Building Materials,2018,21(2),222(in Chinese).
|
|
姜正平,明维.建筑材料学报,2018,21(2),222.
|
| [96] |
Zhu H J, Yao X, Zhang Z H, et al. Non-Metallic Mines,2011,34(3),48(in Chinese).
|
|
诸华军,姚晓,张祖华,等.非金属矿,2011,34(3),48.
|
| [97] |
Graytee A, Sanjayan J G, Nazari A. Ceramics International,2018,44(7),8216.
|
| [98] |
Somna K, Jaturapitakkul C, Kajitvichyanukul P, et al. Fuel,2011,90(6),2118.
|
| [99] |
Thostenson E T, Chou T W. Composites Part A (Applied Science and Manufacturing),1999,30(9),1055.
|
| [100] |
Das S, Mukhopadhyay A K, Datta S, et al. Bulletin of Materials Science,2008,31(7),943.
|
| [101] |
Tong Y, Xia F, Zhang T, et al. Journal of Shenyang Jianzhu University (Natural Science),2015(2),313(in Chinese).
|
|
佟钰,夏枫,张婷,等.沈阳建筑大学学报(自然科学版),2015(2),313.
|
| [102] |
Dong M, Feng W, Elchalakani M, et al. Ceramics International,2017,43(14),11233.
|
| [103] |
Muhammad Z, Nasir S, Asif J. Construction and Building Materials,2018,181,227.
|
|
|
|
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2019, Vol. 33 
