纳米纤维素及其在水凝胶中的研究进展

doi:10.11896/cldb.18030139

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Abstract Hydrogels are three-dimensional networks of hydrophilic polymers formed by chemical and/or physical crosslinking. They have favorable water absorption and water retention, and will not overflow under a certain pressure. Since hydrogels entered people's eye shot, the preparation process and application range of hydrogels have been continuously optimized and enlarged. Nevertheless, hydrogels still suffer from poor water absorption, water retention, salt tolerance, mechanical strength, and degradability. Especially, hydrogels are mostly prepared by taking petro-leum products as raw materials, and the lack of oil resources in China seriously blocks the further development of hydrogels.
For the sake of solving the above problems, researchers have gradually turned their attention to the natural macromolecules. Usually, natural macromolecules exist in nature and are rich in resources. Starch, cellulose, chitosan, etc. are the earliest natural polymers that have been found to be satisfactory for introducing in hydrogels. Among them, cellulose is the most abundant one, and it has been widely used in various fields because of its non-toxic, favorable biodegradable and biocompatible properties. However, the poor water solubility and poor mechanical properties of cellulose have prompted certain hindrance in the preparation process, despite the improved effect of water absorption and water retention. Accor-dingly, the modification of cellulose has become a hot topic. Although a series of derivatives like carboxymethyl cellulose can solve the problem of cellulose insoluble in water, the gel strength and salt tolerance of hydrogel still remain unsolved. It is universally known that nanoparticles exhibit certain rigidity and are able to regulate the mechanical property of materials. Consequently, nanocellulose, one of the modified derivatives of the cellulose has attracted numerous research interests. Thanks to the nano scale size, nanocellulose not only possesses the advantages of non-to-xic, easy degradation, but also show low density, good mechanical properties, strong hydrophilicity, low coefficient of thermal expansion, etc. Compared with tranditional hydrogel, the nanocellulose-based hydrogel is superior in the following three aspects: enhanced water absorption, considerable salt tolerance, and high gel strength.
In this article, we summarize the preparation approaches ofnanocellulose and nanocellulose-based hydrogels, including physical, chemical and physico-mechanical combined methods, and analyze the merits and drawbacks of each method. Besides, we introduce the application and develo-pment of nanocellulose-based hydrogels in agriculture, biological ,water treatment and other fields. Finally, we point out the challenges in the preparation and application of nanocellulose-based hydrogels and proposed the future prospect.

Key words： hydrogel nanocellulose water absorption acid hydrolysis method enzymolysis approach surface graft copolymerization

Published: 10 April 2019

CLC number:

TB34

Fund:This work was financially supported by the National Key Research and Development Programme (2017YFB0308602), the National Natural Science Foundation of China (21376145), Shaanxi University of Science and Technology Innovation Team Project (TD12-03)

About author:: Fan Yang, received her B.S. degree in chemistry from Xianyang Normal University in 2016. She is currently pursuing her m.S. at the College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology. Her research has focused on modification and utilization of natural renewable resources.Jianzhong ma, received his B.S. degree and m.S. degree in leather chemistry and engineering from Shaanxi University of Science and Technology in 1983 and 1989;He received his Ph.D. degree in polymer chemistry and physics from Zhejiang Universityin 1998. His research has focused on organic and inorganic nanocomposites.

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Cite this article:

YANG Fan,mA Jianzhong,BAO Yan. Advances in Nanocellulose and Its Application in Hydrogels[J]. Materials Reports, 2019, 33(7): 1227-1233.

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http://www.mater-rep.com/EN/10.11896/cldb.18030139 OR http://www.mater-rep.com/EN/Y2019/V33/I7/1227

1 Zhu H, Li Y, Fang Z, et al.ACS Nano, 2014, 8(4),3606.
2 Suttie E D . Polymer Degradation & Stability, 2001, 73(3),567.
3 Irie Y. Chemistry, 2017, 57(9),598.
4 Bao Y, ma J, Li N. Carbohydrate Polymers, 2011, 84(84),76.
5 Bai Y m. Study on preparation and properties of hydroxyl ethyl acrylate crosslinking copolymer hydrogels. master's Thesis, East China University of Science and Technology, China, 2014 (in Chinese).
白玉明. 丙烯酸羟乙酯交联共聚物水凝胶的制备及性能研究. 硕士学位论文, 华东理工大学, 2014.
6 Zhen W J, Shan Z H. modern Chemical Industry, 2008, 28(6),85(in Chinese).
甄文娟, 单志华. 现代化工, 2008, 28(6),85.
7 Payen A. Comptes Rendus, 1838, 7, 1052.
8 Spange S , Heinze T , Klemm D . Polymer Bulletin, 1992, 28(6),697.
9 Konwarh R, Karak N, misra m. Biotechnology Advances, 2013, 31(4),421.
10 Lavoine N, Desloges I, Dufresne A, et al. Carbohydrate Polymers, 2012, 90(2),735.
11 Beck-Candanedo S, Roman m , Gray D G . Biomacromolecules, 2005, 6(2),1048.
12 Terech P, Chazeau L, Cavaille J Y. macromolecules, 1999, 32(6),1872.
13 Grunert m, Winter W T. Journal of Polymers and the Environment, 2002, 10(1),27.
14 Revol J F. Carbohydrate Polymers, 1982, 2(2),123.
15 Fengel D, Wegener G. Wood: chemistry, ultrastructure, reactions. De Gruyter, Germany, 2011.
16 Araki J, Wada m, Kuga S, et al.Colloids & Surfaces A Physicochemical & Engineering Aspects, 1998, 142(1),75.
17 Zhang T, Zhang Y, Wang X Y, et al. materials Letters, DOI:10.1016/j.matlet.2018.06.101.
18 Herrick F W,Casebier R L, Hamilton J K, et al. Journal of Applied Polymer Science, 1983, 37(9),797.
19 Zimmermann T,Pöhler E, Geiger T. Advanced Engineering materials, 2004, 6(9),754.
20 Li J, Wang Y, Wei X, et al.Carbohydrate Polymers, 2014, 113,388.
21 Eriksen Ø, Syverud K, Gregersen Ø. Nordic Pulp & Paper Research Journal, 2008, 23(3),299.
22 Spence K L,Venditti R A, Rojas O J, et al. Cellulose, 2011, 18(4),1097.
23 Charreau H, Foresti m L, Vazquez A. Recent Patents on Nanotechnology, 2013, 7(1),56.
24 Tang L R. Preparation, properties and application ofnanocellulose crystal. master's Thesis, Fujian Agriculture and Forestry University, China, 2010 (in Chinese).
唐丽荣. 纳米纤维素晶体的制备、表征及应用研究. 硕士学位论文, 福建农林大学, 2010.
25 Nickerson R F,Habrle J A. Industrial & Engineering Chemistry, 1947, 39(11),1507.
26 Rånby B G, Ed. Ribi. Cellular and molecular Life Sciences, 1949, 6(1),12.
27 Li S, Li C, Li C, et al.Polymer Degradation & Stability, 2013, 98(9),1940.
28 Walter B, Gallatin J C.U.S. patent application, US3041246, 1962.
29 Pääkkö m, Ankerfors m, Kosonen H, et al. Biomacromolecules, 2007, 8(6),1934.
30 Henriksson m, Henriksson G, Berglund L A, et al. European Polymer Journal, 2007, 43(8),3434.
31 Hassan m L, Bras J, Hassan E A, et al.Industrial Crops & Products, 2014, 55(6),102.
32 Nechyporchuk O, Pignon F, Belgacem m N. Journal of materials Science, 2015, 50(2),531.
33 Xu m, Xu m D, Dai H Q, et al. Journal of Cellulose Science and Technology, 2013, 21(1),70 (in Chinese).
徐媚, 徐梦蝶, 戴红旗, 等. 纤维素科学与技术, 2013, 21(1),70.
34 Cheng Z L, Xu Q H, Gao Y. Advanced materials Research, 2012, 627,859.
35 Fukuzumi H, Saito T, Isogai A. Carbohydrate Polymers, 2013, 93(1),172.
36 Nooy A E J D, Besemer A C, Bekkum H V. Recueil des Travaux Chimiques des Pays-Bas, 1994, 113(3),165.
37 Saito T,Nishiyama Y, Putaux J L, et al. Biomacromolecules, 2006, 7(6),1687.
38 Saito T,Hirota m, Tamura N, et al. Biomacromolecules, 2009, 10(7),1992.
39 Akira I,Tsuguyuki S, Hayaka F. Nanoscale, 2011, 3(1), 71.
40 Davis N J,Flitsch S L. Tetrahedron Letters, 1993, 34(7), 1181.
41 Goetz L, mathew A,Oksman K, et al. Carbohydrate Polymers, 2009, 75(1),85.
42 Nair SS, Zhu J Y, Deng Y, et al. ACS Sustainable Chemistry & Enginee-ring, 2014, 2(4),772.
43 Naseri N, Bhanumathyamma D, mathew A P, et al. Biomacromolecules, 2016, 17(11),3714.
44 Ruiz-Palomero C, Soriano m L, Benítez-martínez S, et al. Sensors & Actuators B Chemical, 2017, 245,946.
45 Xu Z, Li J, Zhou H, et al. RSC Advances, 2016, 6(49),43626.
46 Park m, Lee D, Hyun J.Carbohydrate Polymers, 2015, 116,223.
47 Park m, Chang H,Jeong D H, et al. BioChip Journal, 2013, 7(3),234.
48 Zhou C, Wu Q, Zhang Q.Colloid and Polymer Science, 2011, 289(3),247.
49 Spagnol C, Rodrigues F H A, Pereira A G B, et al. Carbohydrate Polymers, 2012, 87(3),2038.
50 Wang L. Study on alkaline sensitivehydrogel as carrier of insecticide. master's Thesis, South China Agricultural University, China, 2011 (in Chinese).
王磊. 碱性敏感型水凝胶作为杀虫剂载体的研究. 硕士学位论文, 华南农业大学, 2011.
51 The global market fornanocellulose to 2017. Edinburgh, Lothian EH74NA, United Kingdom: Futures markets Inc., 2012, pp. 66.
52 Wang K,Nune K C, misra R D. Acta Biomaterialia, 2016, 36,143.
53 Bhattacharya m,malinen m m, Lauren P, et al. Journal of Controlled Release, 2012, 164(3),291.
54 Ahrem H, Pretzel D, Endres m, et al. Acta Biomaterialia, 2014, 10(3),1341.
55 Sampath U G T m, Ching Y C, Cheng H C, et al. Cellulose, 2017, 24(5),2215.
56 Zhou Y, Fu S, Zhang L, et al.Carbohydrate Polymers, 2014, 101(1),75.
57 Xiong Y, Wang C, Wang H, et al. Chemical Engineering Journal, 2018, 337,143.
58 Saremi. modeling of nanocellulose hydrogel coatings on textile substrates and enzymatic modification of nanocellulose coatings for sustainable dyeing. Ph.D. Thesis, University of Georgia, America, 2017.
59 Ruiz-Palomero C, Soriano m L, Benítez-martínez S, et al. Sensors & Actuators B Chemical, 2017, 245,946.