铝基层状复合材料界面金属间化合物的研究现状

doi:10.11896/cldb.17110069

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Abstract The process of science and technology, and the emergence of novel technologies and industries,have brought about extensive demand for engineering materials worldwide, as well as stringent requirement for material properties. Accordingly, the limitations for the application of conventional single metal materials has grown more prominent, which cannot satisfy the demands of technology development any longer. Recently, the continuously increasing consumption of energy and resources has led to the gradual depletion of mineral resources. For the sake of saving resources and energy, and reducing the weight of products, environmentally friendly. Composite materials have become the mainstream development direction. As regard to dissimilar metal composites, they are able to be endowed with multiple excellent performances by selecting different metal component layers, which can satisfy the need for wear resistance, corrosion resistance, high thermal and conductivity. At present, metal matrix composites hold widespread application in various fields including petroleum, machinery, chemical industry, electronics and household appliances.
Aluminum matrix laminated composite materialsare capable to meet a variety of special requirements, which is not only because of the corrosion resistance, high thermal conductivity, low density of Al, but also profiting from excellent properties brought by other components, such as corrosion resistance of stainless steel, high conductivity and heat conduction of copper, corrosion resistance of titanium to high temperature impact, amazing electromagnetic shielding performance and low density of magnesium. The implementation of composites like Al/stainless steel, Al/Ni, Al/Ti can remarkably reduce the use of precious metals such as Cr, Ni, Ti. Usually, diffusion annealing will be carried out after heterogeneous metal compounding, aiming at achieving better interfacial bonding properties of aluminum matrix laminated composites. However, intermetallic compounds generated at the interface of laminated composites during the diffusion annealing of heterogeneous metals will do harm to the interlaminar bonding strength, and even lead to delamination, which seriously deteriorates the performance of the composite materials. Consequently, the research on the formation and growth of intermetallic compounds is the key to the development of aluminum matrix laminated composites.
This paper providesa systematical description on aluminum matrix laminated composite materials including Al/stainless steel, Al/Ni, Al/Cu, Al/Ti and Al/mg, introduces phase compositions and growth kinetics of the intermetallic compounds, and points out the formation conditions of the intermetallic compounds of these aluminum matrix laminated composites. meanwhile, it reveals the initial formation process of intermetallic compounds, which includes metal mutual diffusion, initial formation after the maximum solid solubility, transformation of different intermetallic compounds, thickness increase. And it also expounds the relationship of thickness, with diffusion time and temperature, and the relationship between thickness of intermetallic compounds (X) and time (t) meets the equation of X=ktⁿ. Finally, the effect of Si on the intermetallic compounds at the interface of Al/Ti and Al/Ni is prospected.

Key words： aluminum matrix laminated composite materials intermetallic compound activity energy growth kinetic

Published: 10 April 2019

CLC number:

TB331

Fund:This work was financially supported by the Jiangsu Province Key Laboratory for Clad materials (Bm2014006) and Natural Science Foundation of Jiangsu Province (BK20161151)

About author:: Yinna Han, received her master's degree from Nort-heastern University in June 2013. She is R&D engineer of Yinbang Clad material Co. Ltd., mainly engaging in laminated composite materials research and development.Dejing Zhou, senior engineer, national “ten thousand plan” of science and technology innovation talents, the chief expert of 863 theme project, youth science and technology innovation leading personnel in the ministry of Science and Technology, “double gen talent” in Jiangsu Province, chief expert of innovative talents team of "six talents summit” in Jiangsu, president of Wuxi new wu district innovation and entrepreneurship association and president of the institute of technical research of Yinbang Clad material Co. Ltd.

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Cite this article:

HAN Yinna,ZHANG Xiaojun,LI Long, et al. A Review on Study of the Intermetallic Compounds at the Interface of Aluminum matrix Laminated Composites[J]. Materials Reports, 2019, 33(7): 1198-1205.

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http://www.mater-rep.com/EN/10.11896/cldb.17110069 OR http://www.mater-rep.com/EN/Y2019/V33/I7/1198

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