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《材料导报》期刊社  2017, Vol. 31 Issue (20): 53-57    https://doi.org/10.11896/j.issn.1005-023X.2017.020.012
  材料研究 |
立方织构Ni-Cr-Mo-W合金薄带及其性能*
刘成红1, 王均安1,2, 熊邦汇1, 张植权1, 陈纪昌1, 贺英1
1 上海大学材料科学与工程学院, 上海 200072;
2 上海市高温超导重点实验室, 上海 200444
Cubic Textured Ni-Cr-Mo-W Alloy Tape and Its Properties
LIU Chenghong1, WANG Jun’an1,2, XIONG Banghui1, ZHANG Zhiquan1, CHEN Jichang1, HE Ying1
1 School of Materials Science and Engineering, Shanghai University, Shanghai 200072;
2 Shanghai Key Laboratory of High Temperature Superconductors, Shanghai 200444
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摘要 为了得到高份额立方织构金属基带,同时兼顾居里温度和屈服强度的要求,设计了Ni-7.8%Cr-1.1%Mo-1.6%W(原子分数)合金。采用冷坩埚悬浮熔炼技术冶炼合金铸锭,铸锭经过锻造、热轧、冷轧和再结晶退火,最终得到厚度为100 μm的合金薄带。采用电子背散射衍射(EBSD)技术对合金薄带再结晶织构进行了表征,并研究了其磁性能及力学性能。结果表明:经大变形量冷轧和优化的两步法退火后Ni-7.8%Cr-1.1%Mo-1.6%W合金薄带立方织构份额为93.4%,小角晶界体积分数为84.5%;合金薄带的居里温度为25 K,远低于77 K;合金薄带室温下的屈服强度为 182 MPa,与 Ni-5%W合金相当,且抗拉性能十分优异。
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刘成红
王均安
熊邦汇
张植权
陈纪昌
贺英
关键词:  Ni-Cr-Mo-W合金  再结晶织构  两步退火法  居里温度  屈服强度    
Abstract: Quaternary Ni-7.8at%Cr-1.1at%Mo-1.6at%W alloy was designed based on the requirements of sharp cubic texture, lower Curie temperature and moderate yield strength for the substrate of 2G high temperature superconductor wire. The alloy ingot was prepared by using cold crucible induction levitation melting and a tape with a final thickness of 100 μm was obtained after forging, hot rolling, cold rolling and recrystallization annealing. The recrystallization texture of the alloy tape was characterized by electron back scatter diffraction (EBSD) technology and its magnetic and mechanical properties were also evaluated. The results show that the cubic texture percentage and the small angle grain boundary volume fraction of Ni-7.8at%Cr-1.1at%Mo-1.6at%W alloy tape reach 93.4% and 84.5%, respectively, after heavy cold rolling and two-step annealing. The Curie temperature of the alloy tape is 25 K, far below 77 K, and the yield strength of the alloy tape at room temperature is 182 MPa, equivalent to that of Ni-5at%W alloy tape. All this indicates that Ni-7.8at%Cr-1.1at%Mo-1.6at%W alloy tape possesses advantages over the available Ni-based alloy tapes and would substitute Ni-5at%W alloy tape for the coating of 2G high temperature superconductor.
Key words:  Ni-Cr-Mo-W alloy    recrystallization texture    two-step annealing    Curie temperature    yield strength
               出版日期:  2017-10-25      发布日期:  2018-05-05
ZTFLH:  TG146.1+5  
  TM26  
基金资助: *上海市“科技创新行动计划”重大科技项目(11DZ1100303);上海市高温超导重点实验室项目(14DZ2260700);上海大学科研培育基金项目
作者简介:  刘成红:男,1989年生,硕士研究生,主要从事涂层导体用金属基带材料开发和组织控制研究 E-mail:liuchenghongshu@126.com 王均安:通讯作者,男,1963年生,研究员,博士研究生导师,主要从事金属和合金组织与织构控制研究 E-mail:jawang@i.shu.edu.cn
引用本文:    
刘成红, 王均安, 熊邦汇, 张植权, 陈纪昌, 贺英. 立方织构Ni-Cr-Mo-W合金薄带及其性能*[J]. 《材料导报》期刊社, 2017, 31(20): 53-57.
LIU Chenghong, WANG Jun’an, XIONG Banghui, ZHANG Zhiquan, CHEN Jichang, HE Ying. Cubic Textured Ni-Cr-Mo-W Alloy Tape and Its Properties. Materials Reports, 2017, 31(20): 53-57.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.020.012  或          http://www.mater-rep.com/CN/Y2017/V31/I20/53
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