Development and Prospect of Research on Plastic Crystals and Its Barocaloric Effects
FAN Xiaoyan1, ZHAO Xueting2, OU Zhiqiang1,3,*
1 School of Physics and Electronic Information, Inner Mongolia Normal University, Hohhot 010022, China 2 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China 3 Inner Mongolia Key Laboratory for Physics and Chemistry of Functional Materials, Hohhot 010022, China
Abstract: With the rapid development of economy and the increasing warming of global climate, the impact of refrigeration technology on modern society is more and more in-depth. The use of perfluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) freon refrigerants is at primary position in traditional gas compression refrigeration, however, will aggravate the greenhouse effect. To achieve global carbon neutralization, seeking high efficiency and environmentally friendly refrigeration schemes has become the key research direction for scientists, while the solid-state phase change technology based on field induction provides a promising scheme. Among them, the barocaloric eects have attracted much attention. In recent years, scientists have found the colossal barocaloric effects in a series of materials named plastic crystal, in which the entropy change is one order of magnitude higher than that of the traditional solid-state phase change refrigeration materials. Since then, the research on the barocaloric effects of plastic crystal materials has gradually increased in the scientific research community, and new plastic crystal materials with excellent performance have been continuously explored as the working medium of barocaloric effects refrigeration technology. This has greatly promoted the development of barocaloric effects refrigeration technology and provided more possibilities for realizing green and environmentally friendly high-efficiency refrigeration technology in the future. This paper will briefly explain the physical mechanism of the barocaloric effects in the plastic crystal, compare the comprehensive performance of several typical plastic crystal materials such as C5H12O2 (NPG), (NH2)C(CH2OH)3 (TRIS) and carborane, etc. and furthermore, and prospect the application of plastic crystal barocaloric effects in new solid-state refrigeration technology.
通讯作者:
*欧志强,内蒙古师范大学物理与电子信息学院副教授、硕士研究生导师。2013年于荷兰代尔夫特理工大学材料物理专业博士毕业。目前主要从事固体卡效应材料、磁功能材料等方面的研究工作。发表论文40余篇,研究成果发表在Advance Energy Materials、Journal of Alloys and Compounds等期刊杂志,出版《Magnetic Structure and Phase Formation of Magnetocaloric Mn-Fe-P-X compounds》专著1部。 zq.ou@imnu.edu.cn
范晓燕, 赵雪婷, 欧志强. 塑晶材料及其压卡效应研究发展与展望[J]. 材料导报, 2024, 38(5): 22080087-8.
FAN Xiaoyan, ZHAO Xueting, OU Zhiqiang. Development and Prospect of Research on Plastic Crystals and Its Barocaloric Effects. Materials Reports, 2024, 38(5): 22080087-8.
1 United Nations Environment Programme. The Importance of Energy Efficiency in the Refrigeration, Air-Conditioning and Heat Pump Sectors, Vienna, 2018. 2 Li D M, Zuo D R, Yu P. Materials Reports, 2021, 35(11), 11120 (in Chinese). 李冬梅, 左定荣, 余鹏. 材料导报 , 2021, 35(11), 11120. 3 Liu J, Gottschall T, Skokov K P, et al. Nature Materials, 2012, 11(7), 620. 4 Cong D, Xiong W, Planes A, et al. Physical Review Letters, 2019, 122(25), 255703. 5 Moya X, Kar-Narayan S, Mathur N D. Nature Materials, 2014, 13(5), 439. 6 Crossley S, Mathur N D, Moya X. Aip Advances, 2015, 5(6), 067153. 7 Müller K A, Fauth F, Fischer S, et al. Applied Physics Letters, 1998, 73(8), 1056. 8 Li B, Kawakita Y, Ohira-Kawamura S, et al. Nature, 2019, 567(7749), 506. 9 Hou H, Qian S, Takeuchi I. Nature Reviews Materials, 2022, 7(8), 633. 10 Tong X, Shen L M, Li L, et al. Vacuum & Cryogenics, 2021, 27(4), 316 (in Chinese). 童潇, 申利梅, 李亮, 等. 真空与低温, 2021, 27(4), 316. 11 Gottschall T, Skokov K P, Fries M, et al. Advanced Energy Materials, 2019, 9(34), 1901322. 12 Hou H, Finkel P, Staruch M, et al. Nature Communications, 2018, 9(1), 4075. 13 Shi J, Han D, Li Z, et al. Joule, 2019, 3(5), 1200. 14 Nair B, Usui T, Crossley S, et al. Nature, 2019, 575(7783), 468. 15 Li Z C, Shi J Y, Chen J P, et al. Journal of Refrigeration, 2021, 42(1), 1 (in Chinese). 李子超, 施骏业, 陈江平, 等. 制冷学报, 2021, 42(1), 1. 16 Mañosa L, Planes A. Applied Physics Letters, 2020, 116(5), 050501. 17 Hou H, Simsek E, Stasak D, et al. Journal of Physics D: Applied Phy-sics, 2017, 50, 404001. 18 Mañosa L, Planes A. Advanced Materials, 2017, 29(11), 1603607. 19 De Oliveira N A. Acta Materialia, 2023, 246, 118657. 20 Cazorla C. Applied Physics Reviews, 2019, 6(4), 041316. 21 Zhang J, Xu Y, An S, et al. Chinese Physics B, 2020, 29(7), 076202. 22 Lloveras P, Aznar A, Barrio M, et al. Nature Communications, 2019, 10(1), 1. 23 Song R Q, Zhang Z D, Li B, et al. Journal of Refrigeration, 2022, 43(4), 35 (in Chinese). 宋睿琪, 张志东, 李昺, 等. 制冷学报, 2022, 43(4), 35. 24 Brand R, Lunkenheimer P, Loidl A. The Journal of Chemical Physics, 2002, 116(23), 10386. 25 Staveley L A K. Annual Review of Physical Chemistry, 1962, 13(1), 351. 26 Zhang Z, Li K, Lin S, et al. arXiv preprint, 2021, 2103, 04348. 27 Boldrin D. Applied Physics Letters, 2021, 118(17), 170502. 28 Greco A, Aprea C, Maiorino A, et al. International Journal of Refrigeration, 2019, 106, 66. 29 Lloveras P, Tamarit J L. MRS Energy & Sustainability, 2021, 8(1), 3. 30 Chandra D, Ding W, Lynch R A, et al. Journal of the Less Common Metals, 1991, 168(1), 159. 31 Tamarit J L, Perez-Jubindo M A, De La Fuente M R. Journal of Physics, Condensed Matter, 1997, 9(25), 5469. 32 Li F B, Li M, Xu X, et al. Nature Communications, 2020, 11(1), 1. 33 Dannenberg J J. An introduction to hydrogen bonding by george A, Oxford University Press, New York and Oxford, 1997, pp. 303. 34 Zhang Z, Chen Y N, Qi J, et al. Chinese Physics B, 2022, 31(3), 036802. 35 Khot S S, Anbhule P V, Desai U V, et al. Comptes Rendus Chimie, 2018, 21(9), 814. 36 Aznar A, Lloveras P, Barrio M, et al. Journal of Materials Chemistry A, 2020, 8(2), 639. 37 Potenza J A, Lipscomb W N. Inorganic Chemistry, 1966, 5(9), 1471. 38 Beall H A, Lipscomb W N. Inorganic Chemistry, 1967, 6(5), 874. 39 Leites L A, Bukalov S S. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science, 1989, 38(10), 2079. 40 Momma K, Izumi F. Journal of Applied Crystallography, 2011, 44(6), 1272. 41 Yamamuro O, Hayashi M, Matsuo T, et al. The Journal of Chemical Physics, 2003, 119(9), 4775. 42 Zhang K, Song R Q, Qi J, et al. Advanced Functional Materials, 2022, 32(20), 2112622. 43 Leites L A. Chemical Reviews, 1992, 92(2), 279. 44 Andrade V, Paixão L S, Carvalho A M G, et al. arXiv preprint, 2022, 2208, 08474. 45 Carey D M. The Journal of Chemical Physics, 1998, 108(7), 2669. 46 Wang X, Guo Q, Zhong Y, et al. Renewable Energy, 2013, 51, 241. 47 Solangi K H, Kazi S N, Luhur M R, et al. Energy, 2015, 89, 1065. 48 Mañosa L, González-Alonso D, Planes A, et al. Nature Materials, 2010, 9(6), 478. 49 Mañosa L, Gonzalez-Alonso D, Planes A, et al. Nature Communications, 2011, 2(1), 1. 50 Li B, Zhang Z D. Science China Physics, Mechanics & Astronomy, 2021, 51(6), 44 (in Chinese). 李昺, 张志东. 中国科学, 物理学, 力学, 天文学, 2021, 51(6), 44.
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2024, Vol. 38 
