Research Progress of Pultrusion Molding Process of Fiber Reinforced Thermoplastic Composites
ZHAO Xintao1, JIANG Ning1,*, WANG Mingdao1, LI Junteng2, LI Di1, TAN Hongsheng3
1 School of Transportation and Vehicle Engineering, Shandong University of Technology, Zibo 255000, Shandong, China 2 School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, Shandong, China 3 School of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, Shandong, China
Abstract: As a thermoplastic composite molding process for continuous fixed-section composites production, pultrusion process has advantageous cha-racteristics including high raw material utilization rate, high production efficiency, low waste rate, strong replicability, designability, and has been widely used in the field of automotive lightweight designs, construction building materials, wind power blades and others. Thermoplastic resin matrix is a solid substance at room temperature and has poor fluidity in the molten state, so it is difficult to impregnate the fibers, which becomes the bottleneck of the development of pultrusion process. Therefore, the key to improve the pultrusion process is to focus on the fiber impregnation technology. This paper reviews the research progress of pultrusion process of fiber-reinforced thermoplastic composites. The pultrusion process is divided into non-reactive pultrusion and reactive pultrusion according to the different impregnation methods. The impregnation characteristics, manufacture processes and optimization scheme of each molding process are introduced. In addition, the influence law of diffe-rent fiber impregnation methods on the quality of the products in pultrusion process is expounded. Finally, the existing problems of pultrusion process are discussed, and the development trend of pultrusion process for fiber reinforced thermoplastic composites is prospected, which can provide guidance for further research and innovation of pultrusion process.
赵新涛, 姜宁, 王明道, 李骏腾, 李迪, 谭洪生. 纤维增强热塑性复合材料拉挤成型工艺研究进展[J]. 材料导报, 2024, 38(1): 22050237-9.
ZHAO Xintao, JIANG Ning, WANG Mingdao, LI Junteng, LI Di, TAN Hongsheng. Research Progress of Pultrusion Molding Process of Fiber Reinforced Thermoplastic Composites. Materials Reports, 2024, 38(1): 22050237-9.
1 Volk M, Wong J, Arreguin S, et al. Composites Part B: Engineering, 2021, 227, 109339. 2 Xu D M, Zhang X L, Jing T. Environmental Protection, 2019, 47(20), 54 (in Chinese). 许冬梅, 张兴林, 荆涛. 环境保护, 2019, 47(20), 54. 3 Sun Y B, Li H F, Zhang B M. Aeronautical Science & Technology, 2016, 27(5), 1 (in Chinese). 孙银宝, 李宏福, 张博明. 航空科学技术, 2016, 27(5), 1. 4 Zhou X L, Qian C X, Wang J G, et al. Hi-Tech Fiber and Application, 2004, 29(1), 41 (in Chinese). 周效谅, 钱春香, 王继刚, 等. 高科技纤维与应用, 2004, 29(1), 41. 5 Diez-Pascual A M, Naffakh M. Polymer, 2012, 53(12), 2369. 6 Liu D, Zhu Y, Ding J, et al. Composites Part B: Engineering, 2015, 77, 363. 7 Kudo K, Furutani M, Arimitsu K. ACS Macro Letters, 2015, 4(10), 1085. 8 Biron M. Thermoplastics and thermoplastic composites, William Andrew, UK, 2018, pp. 1. 9 Liu B, An W L, Ni N N. Aeronautical Manufacturing Technology, 2021, 64(22), 80 (in Chinese). 刘彬, 安卫龙, 倪楠楠. 航空制造技术, 2021, 64(22), 80. 10 Wang Z J, Zhou X D. Composites Science and Engineering, 2021(10), 120 (in Chinese). 王子健, 周晓东. 复合材料科学与工程, 2021(10), 120. 11 Mindermann P, Witt M U, Gresser G T. Composites Part A: Applied Science and Manufacturing, 2022, 154, 106763. 12 Sandberg M, Yuksel O, Baran I, et al. Composites Part A: Applied Science and Manufacturing, 2021, 143, 106231. 13 Song Y S, Youn J R, Gutowski T G. Composites Part A: Applied Science and Manufacturing, 2009, 40(8), 1257. 14 Epple S, Bonten C. In: International Conference of the Polymer Proces-sing Society. Nuremberg, 2013, pp. 454. 15 Gibson A G, Månson J A. Composites Manufacturing, 1992, 3, 223. 16 Kong Q B, Ding C R, Qiao X D. Fiber Composites, 2000(2), 35 (in Chinese). 孔庆宝, 丁传荣, 乔学东. 纤维复合材料, 2000(2), 35. 17 Minchenkov K, Vedernikov A, Safonov A, et al. Polymers (Basel), 2021, 13(2), 180. 18 Chen K, Xue P, Sun H, et al. China Plastics, 2019, 33(1), 116 (in Chinese). 陈轲, 薛平, 孙华, 等. 中国塑料, 2019, 33(1), 116. 19 Luisier A, Bourban P E, Månson J A E. Composites Part A: Applied Science and Manufacturing, 2003, 34(7), 583. 20 Yu J Y, Zhou Z F. Journal of Wuhan University of Technology, 1998, 20(4), 22 (in Chinese). 余剑英, 周祖福. 武汉工业大学学报, 1998, 20(4), 22. 21 Zou X P, Yi X S. Petrochemical Technology, 1996, 25(3), 194 (in Chinese). 邹湘坪, 益小苏. 石油化工, 1996, 25(3), 194. 22 Cai H P, Wang J, Duan H J. Composites Science and Engineering, 2003(2), 51 (in Chinese). 蔡浩鹏, 王钧, 段华军. 复合材料科学与工程, 2003(2), 51. 23 Jiang X W, Li J. Shandong Textile Science & Technology, 2003(1), 52 (in Chinese). 姜晓巍, 李静. 山东纺织科技, 2003(1), 52. 24 Chen B. Composites Science and Engineering, 2014(9), 34 (in Chinese). 陈博. 复合材料科学与工程, 2014(9), 34. 25 Ye D Q. Fiber Composites, 1999(16), 24 (in Chinese). 叶鼎铨. 纤维复合材料, 1999(16), 24. 26 Silva R F, Silva J F, Nunes J P, et al. Materials Science Forum, 2008, 587, 246. 27 Jiang W. Preparation and properties of continuous carbon fiber reinforced thermoplastic composites. Master’s Thesis, Huazhong University of Science and Technology, China, 2018 (in Chinese). 蒋维. 连续碳纤维增强热塑性复合材料制备与性能研究. 硕士学位论文, 华中科技大学, 2018. 28 Teng L H, Cao W W, Zhu B, et al. Journal of Materials Engineering, 2021, 49(2), 42 (in Chinese). 滕凌虹, 曹伟伟, 朱波, 等. 材料工程, 2021, 49(2), 42. 29 Liu B, Xu A, Bao L. Journal of Thermoplastic Composite Materials, 2015, 30(5), 724. 30 Wang Y, Wang X, Wu D. Composite Interfaces, 2016, 23(8), 743. 31 Yu S, Hwang Y H, Hwang J Y, et al. Composites Science and Technology, 2019, 175, 18. 32 Sommacal S, Matschinski A, Drechsler K, et al. Composites Part A: Applied Science and Manufacturing, 2021, 149, 106487. 33 Budiyantoro C, Rochardjo H S B, Nugroho G. Machines, 2021, 9(2), 42. 34 Peltonen P, Lahteenkorva K, Paakkonen E J, et al. Journal of Thermoplastic Composite Materials, 1992, 5, 318. 35 Sun Y, Liu T H. China Rubber/Plastics Technology and Equipment, 2006, 32(6), 36 (in Chinese). 孙阳, 刘廷华. 橡塑技术与装备, 2006, 32(6), 36. 36 Irfan M S, Harris D, Paget M A, et al. Journal of Composite Materials, 2020, 55(1), 77. 37 Irfan M S, Shotton-Gale N, Paget M A, et al. Journal of Composite Materials, 2016, 51(13), 1925. 38 Akbar S, Ding C Y, Yousaf I, et al. Polymer Composites, 2008, 16, 19. 39 Goodman K E, Loos A C. Journal of Thermoplastic Composite Materials, 1990, 3, 34. 40 Cogswell F N, Staniland P A. U. S. patent, US4541884, 1985. 41 Parasnis N C, Ramani K, Borgaonkar H M. Composites Part A: Applied Science and Manufacturing, 1996, 27, 567. 42 Larson N, Rasnack W, Hoekstra N, et al. In: 2015 ASEE Annual Conference & Exposition. Washington, 2015, pp. 26. 43 Miller A H, Dodds N, Hale J M, et al. Composites Part A: Applied Science and Manufacturing, 1998, 29, 773. 44 Ramani K, Borgaonkar H, Hoyle C. Composites Manufacturing, 1995, 6, 35. 45 Sala G, Cutolo D. Composites Part A: Applied Science and Manufactu-ring, 1997, 28, 637. 46 Haffner S M, Friedrich K, Hogg P J, et al. Composites Science and Technology, 1998, 58, 1371. 47 Safonov A A, Carlone P. Composite Structures, 2018, 184, 153. 48 Connor M, Toll S, Månson J A E, et al. Journal of Thermoplastic Composite Materials, 2016, 8(2), 138. 49 Kerbiriou V, Friedrich K. Journal of Thermoplastic Composite Materials, 1999, 12, 96. 50 Novo P J, Silva J F, Nunes J P, et al. Composites Part B: Engineering, 2016, 89, 328. 51 Lapointe F, Laberge L L. Polymer Composites, 2018, 40(S2), 1015. 52 Kim D H, Lee W I, Friedrich K. Composites Science and Technology, 2001, 61, 1065. 53 Nayana V, Kandasubramanian B. Polymer Testing, 2020, 91, 106774. 54 Svensson N, Shishoo R, Gilchrist M. Journal of Thermoplastic Composite Materials, 2016, 11(1), 22. 55 Ghaedsharaf M, Brunel J E, Laberge L L. Composites Part A: Applied Science and Manufacturing, 2021, 150, 106637. 56 Ananthakrishnan V A. Pultrusion of commingled thermoplastic composite materials. Master’s Thesis, University of Nevada, USA, 2000. 57 Mader E. Scientific Journal of the Technical University of Dresden, 1997, 46, 20. 58 Ghaedsharaf M, Brunel J E, Lebel L L. Composites Part B: Engineering, 2021, 218, 108938. 59 Ishida H, Zimmerman D A. Polymer Composites, 1994, 15, 93. 60 Ageyeva T, Sibikin I, Karger-Kocsis J. Polymers (Basel), 2018, 10, 357. 61 Ning X, Ishida H. Polymer Engineering & Science, 1991, 31, 632. 62 Li Z W, Sun B H, Wang H. Fiber Composites, 1996(2), 7 (in Chinese). 李泽文, 孙宝华, 王辉. 纤维复合材料, 1996(2), 7. 63 Chen K, Jia M, Hua S, et al. Journal of Polymer Research, 2019, 26(2), 1. 64 Van-Rijswijk K, Bersee H E N. Composites Part A: Applied Science and Manufacturing, 2007, 38(3), 666. 65 Babeau A, Comas-Cardona S, Binetruy C, et al. Composites Part A: Applied Science and Manufacturing, 2015, 77, 310. 66 Chen K, Jia M, Sun H, et al. Materials (Basel), 2019, 12 (3), 463. 67 Kim B J, Cha S H, Park Y B. Composites Part B: Engineering, 2018, 143, 36. 68 Jeswani A L, Roux J A. Journal of Manufacturing Science and Enginee-ring, 2010, 132, 021007. 69 Gong M, Zhang D J, Liu Y F, et al. Materials Reports, 2020, 34(21), 21180 (in Chinese). 龚明, 张代军, 刘燕峰, 等. 材料导报, 2020, 34(21), 21180. 70 Ding X, He Q, Yang Q, et al. Polymers (Basel), 2022, 14(4), 666. 71 Suratno B R, Ye L, Mai Y W. Composites Science and Technology, 1998, 58, 191. 72 Vedernikov A, Nasonov Y, Korotkov R, et al. Journal of Composite Materials, 2021, 55(21), 2921. 73 Liu X L, Crouch I G, Lam Y C. Composites Science and Technology, 2000, 60, 857. 74 Epple S, Bonten C. In: Polymer Processing Society. Akron, 2015, pp. 1779. 75 Zoller A, Escalé P, Gérard P. Frontiers in Materials, 2019, 6, 290. 76 Kaczmarek D, Walczyk D, Garofalo J, et al. Journal of Manufacturing Processes, 2021, 64, 972. 77 Chiang C L, Chen C H. Journal of Reinforced Plastics and Composites, 2016, 35, 1554. 78 Abt T, Sánchez-Soto M, De Ilarduya A M. European Polymer Journal, 2012, 48(1), 163. 79 Abt T, Sánchez-Soto M. Critical Reviews in Solid State and Materials Sciences, 2017, 42(3), 173. 80 Obande W, Ó Brádaigh C M, Ray D. Composites Part B: Engineering, 2021, 215, 108771. 81 Masri M N, Mohd S, Bakar A, et al. International Journal of Integrated Engineering, 2021, 13(4), 172. 82 Thieleke P, Bonten C. In: Polymer Processing Society. Akron, 2019, pp. 2289.