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SURFACE ENGINEERING MATERIALS AND TECHNOLOGY
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Research Progress of Piezoelectric Force Microscope on Surface Domain Structure of Ferroelectrics
HE Dongyu, MA Guozheng, XING Zhiguo, WANG Haidou
Materials Reports
2022,36(7 ):21120259 -21. DOI:10.11896/cldb.21120259
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Ferroelectrics are widely used in electronics, optics, precision electromechanical and other fields,which are also expected to be used in high-density nonvolatile memory and multifunctional nano devices in the future. The application of ferroelectrics origins from the domain and domain switching with applying of an electric field. Therefore, the understanding of ferroelectric domain polarization is very important for the design and application of ferroelectric devices.Piezoelectric force microscopy (PFM) method is a surface detection technique based on the strong coupling between polarization and electromechanical behavior, which can reflect the micro characteristics of the domain structure directly, and is used to probe nanoscale piezoelectric and ferroelectric characteristic.In this review, the latest achievements and progress in the study on ferroelectric domains by using PFM are summarized. Firstly, the mechanism and analysis methods of PFM technology are briefly introduced, and then the description of PFM technology in a wide range of ferroelectric domains and their dynamic process are shown,including ferroelectric surface domain structure characterization and identification, domain thermal stability, ferroelectric surface screening, domain nucleation, domain wall motion, domain relaxation, the role of domain defects.Finally, the development trend of PFM research on ferroelectric materials is pointed out, including the application and the regular study of PFM in ferroelectric storage, the optimal design of new ferroelectric materials, the in-depth characterization of ferroelectrics combined with other technologies, and the impact of the fine development of PFM technology on the exploration of nano piezoelectric and ferroelectric.
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Progress on the Design and Preparation of Bioinspired Slippery Surface
FAN Haifeng, GUO Zhiguang
Materials Reports
2022,36(7 ):21110226 -21. DOI:10.11896/cldb.21110226
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Inspired by the Nepenthes pitcher in nature, the slippery liquid-infused porous surfaces (SLIPS) are prepared by injecting the low surface energy liquids into the rough substrate, forming a stable and continuous solid/liquid composite film, which isolates the substrate from direct contact with the ambient fluid. Due the low surface energy of the lubricating oil layer, various liquids with different surface tensions slide on the slippery surface with little resistance, and it is difficult to infiltrate and adhere to the surface. Based on these characteristics, the slippery surfaces have a wide range of applications in anti-corrosion, anti-icing/anti-frosting, self-cleaning, antibacterial, anti-microbial adhesion and so on. However, due to the fluid characteristics of the lubricating oil, the slippery surfaces will inevitably face the problem of lubricating oil loss in practical applications, eventually leading to the failure of slippery performance. Therefore, it is of great significance to improve the stability and durability of slippery surface. In recent years, in order to reduce the loss of lubricating oil, a lot of research about the construction of rough structure, selection of modifiers and lubricating oil have been done from the design and preparation of slippery surface, which have achieved fruitful results. In this review, we mainly focus on how to design and prepare slippery surface with good stability and durability to prolong the longevity of slippery surface. Firstly, the design principles of slippery surfaces are introduced briefly. Then, the effects of rough structure, the properties of modifier and lubricating oil on the stability of slippery surface are reviewed in detail from the design and preparation of liquid-infused slippery surface. After that, the preparation process of solid slippery surface is summarized as well as the problems faced. Finally, the development prospects are reviewed in the hope that the review will provide reference for the preparation of slippery surface with excellent stability and durability.
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Current Status on Performance Enhancement of Shield Machine/TBM Cutter Ring
WANG Haoping, ZHANG Mengqi, MO Jiliang
Materials Reports
2022,36(7 ):22010052 -9. DOI:10.11896/cldb.22010052
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The disc cutter is the main part of shield machine/TBM to perform the rock-breaking and is regarded as the “tooth” of TBM. The service conditions of the disc cutter are extremely bad, and it is prone to cause wear, or even chipping of the cutter ring during service, so the cutter ring becomes the main consumable part in the construction process, which shortens the service life of shield machine/TBM. Meanwhile, the cost of shield construction is greatly increased. Therefore, how to reduce the surface damage and prolong the service life of the cutter is a key engineering problem to be solved urgently. Based on the whole life cycle stages of forming, machining, service, damage, and failure of the cutter ring, this paper summarizes the mechanism of performance enhancement of the cutter ring in service damage analysis, material composition improvement, forming process improvement, heat treatment process improvement and coating strengthening process optimization. In addition, the shortcomings and solutions of each method are analyzed. Finally, the performance enhancement method of the cutter ring is discussed and prospected, in order to provide a reference for the technical path and industrialization of cutter reinforcement.
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Research Progress and Prospect of Tribological Properties of Cold Sprayed Copper-based Composite Coatings
CHEN Wenyuan, TAN Hui, CHENG Jun, ZHU Shengyu, YANG Jun
Materials Reports
2022,36(7 ):21080083 -7. DOI:10.11896/cldb.21080083
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Copper-based composite coatings have been widely used in vital fields such as rail transportation, marine ships, metallurgy and chemical industry because of their good thermal and electrical conductivity, corrosion resistance and anti-wear property. The main coating deposition methods of powder metallurgy, thermal spraying and electroplating have the disadvantages of high preparation temperature, substrate thermal damage and high internal stress, which seriously limit the development and performance enhancement of the copper-based composite coatings. Cold spraying can solve the above problems and provide a new method for the preparation and application of the copper-based composite coating with good mechanical and tribological properties.
However,at present, for the cold spraying, the hard particle reinforcement phase and inorganic lubrication phase are difficult to deposit and their interfaces with the matrix are weak. These shortages have adverse effects on the design and preparation of the cold sprayed copper-based composite coatings with good mechanical and tribological properties. Therefore, how to achieve design of the composition and structure, and preparation of cold sprayed copper-based composite coatings with the high density, low wear and corrosive resistance, become the focus and difficulty of the research on the tribological properties of cold sprayed copper-based composite coatings in the future.
In the process of cold sprayed copper-based composite coating preparation and the studies of its tribological properties, the researchers realized the effective deposition of hard particles and inorganic solid lubricants by means of the metal coated powders and mechanical ball milling. In addition, heat treatment, laser remelting and friction stir welding play a positive role in improving the plasticity and the particle interface bonding of cold sprayed copper-based composite coatings, which is expected to achieve the synergistic optimization of microstructure, mechanical and tribological properties of the coatings.
In this paper, the research status and development prospect of thetribological properties of cold sprayed copper-based composite coatings are reviewed. The development of cold spraying and the principle of the coating deposition are provided. The research progress of the tribological properties and the influence of post-treatment technology on the structure and properties of the coatings are summarized. It is expected to be useful for the design, preparation and application of cold sprayed copper-based composite coatings that related to friction and wear.
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Research Progress of Key Technology and Process of Magnetorheological Finishing
XIAO Qiang, WANG Jiaqi, JIN Longping
Materials Reports
2022,36(7 ):20080279 -10. DOI:10.11896/cldb.20080279
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With the increasing demand for ultra smooth planar components, the surface roughness should reach nanometer level, the surface shape accuracy should reach micron level, and there should be no surface and subsurface damage. The traditional ultra precision polishing techno-logy is low efficiency, high cost, difficult to control, easy to produce surface subsurface damage, which is difficult to meet the production requirements. Magnetorheological finishing (MRF) is a kind of ultra precision machining technology which uses the rheological property of MRF slurry in magnetic field. It is a new precision manufacturing method. The polishing process can be effectively controlled, and can achieve precision polishing, which can achieve ultra precision quality requirements.
This paper analyzes and summarizes the key contents of magnetorheological fluid and magnetic pole in magnetorheological finishing. The components and common materials of MRF are described in detail, as well as three major indexes: settlement stability, magnetomechanical properties and shear yield stress. The results show that the sedimentation rate and stability of MRF are related to the composition of MRF. The sedimentation rate of MRF is different with different magnetic sensitive particles. Different additives can be used to change the sedimentation performance by changing the surface activity of magnetic sensitive particles. The only component of magnetorheological fluid is magnetic sensitive particle under the action of magnetic field, the magnetic sensitive particles gradually form a chain structure and are in the state of condensation. When the magnetization of the magnetic sensitive particles increases, the shear stress also changes, showing an obvious increase trend. At the same time, the influence of different configuration of magnetic pole on magnetic field and the influence of different arrangement of magnetic pole on magnetic field and polishing effect are summarized. The effects of different arrangement of magnetic poles on the size of magnetic field and the uniformity of polishing pad are described. Cylindrical and square cylindrical magnets are the most ideal permanent magnet shapes compared with other magnetic poles.
In this paper, the new research directions of MRF technology are summarized, including cluster MRF technology, combined MRF technology which can process curved surface, global MRF polishing technology and ultrasonic MRF composite processing technology. The working principle and process effect of these methods are introduced. Finally, the current stage of MRF is analyzed, the problems existing in the research of polishing technology are summarized, and the future development direction is prospected.
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Research Progress on High Temperature Tribological Properties of Ternary MAX Phase Layered Ceramic Materials
ZHU Xianyong, DING Zhenyu, MA Guozheng, PIAO Zhongyu, FU Tianli, ZHOU Li, YU Tianyang, GUO Weiling, WANG Haidou
Materials Reports
2022,36(7 ):21090166 -11. DOI:10.11896/cldb.21090166
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With the development of modern industry, traditional lubricating greases are difficult to meet the lubrication requirements of parts under high temperature conditions. As a new high-temperature self-lubricating material with a ternary laminar structure, MAX phase has received extensive attention from scholars at home and abroad in the field of high-temperature wear-resistant self-lubrication. The self-lubricating principle of MAX phase materials is that the M-position and A-position elements diffuse to the surface of the material and combine with the oxygen in the environment under the friction or thermal force, continuously forming a stable oxide lubricating film which can effectively reduce the friction coefficient and wear rate of the material. More than 80 kinds of MAX phases can be synthesized through experiments. Three of the most widely studied material systems are titanium-silicon carbon and their composites, titanium-aluminum carbon and their composites, and chromium-aluminum carbon and their composites.
This paper focuses on the mechanical and tribological properties of the above three MAX phase materials and their composites. It is analytically found that the composition, working conditions and preparation technology of MAX phase ceramic composites have an important impact on the tribological properties of the materials. Good wettability is required between the components of MAX phase composites in order to form dense and uniform composites. For example, titanium silicon carbon has poor wettability with nickel but good wettability with copper. MAX phase self-lubricating material is difficult to form stable oxide lubricating film at lower temperature than 400 ℃ and under light load, and meanwhile the preparation technology at lower temperature can effectively prevent MAX phase materials from the thermal decomposition in the preparation process, which is more conducive to the formation of lubricating film on the surface of materials. It is worth noting that the titanium-aluminum-carbon material can release carbon to the surface and graphitize at room temperature, and its tribological properties at room temperature to 400 ℃ are better than other MAX phase materials. Through the analysis and comparison of MAX phase materials with different A-site elements, it is found that the diffusion rate of Al in the material is higher than that of Si, Ge and other elements, so the oxidation film formation rate and oxidation resistance of aluminum containing MAX phase materials are better than that of silicon containing MAX phase composites. At the same time, the oxides formed in situ by aluminum containing MAX phase materials can repair micro and nano cracks in the materials.
Some new MAX phase materials with application potential in special fields, such as nuclear industry, energy storage materials and superconducting materials, are also introduced in this paper. Finally, the intrinsic characteristics and preparation technology of MAX phase materials are analyzed and summarized, and their application prospect and research direction in wide temperature range self-lubricating materials and complex engineering parts are prospected, in order to provide reference for the engineering application of MAX phase materials in high temperature wear-resistant self-lubricating field.
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Research Progress of Material Removal Mechanism in Plane Lapping and Polishing of Hard-Brittle Materials
LIU Ning, ZHU Yongwei, LI Xue, WU Pengfei
Materials Reports
2022,36(7 ):21060121 -12. DOI:10.11896/cldb.21060121
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Hard-brittle materials have low expansion coefficient, high strength and stable chemical properties, which are widely used in aerospace, optical devices, integrated circuits and other key industry fields. However, brittle fracture issue is easy to occur due to its high hardness and poor toughness, and it will severely affect processing efficiency and surface quality. Therefore, how to achieve the high material removal rate (MRR) and gain a low-damage machined surface is the main challenge for hard-brittle materials at present.
Lapping and polishing are the common processing methods to realize the surface flattening of hard-brittle materials, which can obtain the good MRR and nano-scale surface roughness. The workpiece is removed by cutting, ploughing, squeezing and scratching of abrasives during the lapping process, and this removal form is efficient but will cause the serious subsurface damage. Thus, the chemical reaction between slurry and workpiece materials is usually utilized in polishing process to further eliminate the damage and improve the surface quality.
Nevertheless, the machining systems of the lapping and polishing are complicated with many influencing factors. In order to regulate the processing parameters rationally, it is necessary to study the material removal mechanism deeply. Currently, the material removal mechanism of hard-brittle materials can be divided into two aspects, mechanical effect and chemical-mechanical synergistic operation. The mechanical effect can be classified as ductile removal and brittle removal, while the chemical-mechanical synergistic operation is manifested as solid-phase reactions and chemical bonding and fracture, which result from friction and slurry respectively.
This paper introduces several processing technologies for hard-brittle materials in plane lapping and polishing, and reviews the material removal mechanism from the perspective of mechanical and chemical-mechanical synergy effect. Finally, we focus on the problems confronting in the current investigation and prospect the research directions in the future.
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Heat Treatment Process of Induction Braze Coating of Rotary Blades
LONG Weimin, QIN Jian, LU Quanbin, LIU Dashuang, WU Aiping
Materials Reports
2022,36(7 ):21090163 -5. DOI:10.11896/cldb.21090163
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The process of diamond induction brazing has a great influence on the microstructure and property of the steel substrate.Post brazing heat treatment is an important method to improve the performance of the substrate, but it also has great impact on the coating. The influence of post heat treatment on the hardness and microstructure evolution of induction brazing nickel base alloy coating was investigated by means of high temperature microscope, SEM, XRD, hardness testing and other analytical methods. The results show that the NiCrSiB brazing coating structure was mainly composed of Ni solid solution, CrB, Ni
3
Si, Ni
3
B, and Ni-Ni3Si eutectic phases. After quenching treatment, the content and dimension of Ni
3
Si-Ni solid solution eutectic crystals decreased, the CrB phase grew to a certain extent, and the total content of Ni
3
Si phase reduced. After tempering treatment, the content of the eutectic structure near the grain boundary of the NiCrSiB brazing coating increased, and CrB phase grew further to promote the formation of little Ni
3
Si phase. The hardness of the brazed state coating was higher, then it decreased integrally after quenching and rose again after tempering. A novel technology of brazing and coating combined with heat treatment to improve the comprehensive performance of the rotary cultivator was developed, based on the rotary blade for agricultural machinery equipment as the specific object.
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Study on Hydrophobicity of Surface Texture on Fe-based Amorphous Alloy Coating Treated by Nanosecond Laser
XU Junjie, KANG Jiajie, YUE Wen, ZHOU Yongkuan, ZHU Lina, FU Zhiqiang, SHE Dingshun
Materials Reports
2022,36(7 ):21120134 -6. DOI:10.11896/cldb.21120134
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Fe-Cr-Mo-C-B-Y amorphous coatings were prepared on 35CrMo steel by cold spraying (CS) technique. The mastoid-like, dot and groove surface texture structures with regular arrangement were constructed by nanosecond laser. The result show that the surface characteristics of the coating vary with the laser texture structure and spacing. Under the action of high flux pulsed laser, the coating surface produces larger protrusions along the laser path, and the protrusions are covered with particles formed by the splashing structure of molten particles. Texture surface has texture, particle and polished surface at the same time. Besides, the coating surface after laser processing has excellent hydrophobicity, and the contact angle with deionized water and drilling fluid increase to (151.6±0.3)° and (145.9±0.4)° respectively. With the increase of lattice and groove texture spacing, the wettability changes from superhydrophobic to hydrophobic, and becomes hydrophilic when the spacing is maximum. The spacing change of mastoid-like texture has little effect on hydrophobicity, and even if the spacing increases to 300 μm, the coating surface can still keep hydrophobic. At the same time, the coating surface showed hydrophobic stability and low adhesion.
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Microstructure and Properties of Cold Sprayed Cu-Ti
3
SiC
2
Composite Coatings with Different Ceramic Contents
YU Tianyang, MA Guozheng, GUO Weiling, HE Pengfei, HUANG Yanfei, LIU Ming, WANG Haidou
Materials Reports
2022,36(7 ):21120172 -6. DOI:10.11896/cldb.21120172
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In order to obtain metal-ceramic composite coatings with excellent tribological properties, Cu-Ti
3
SiC
2
composite coatings with different ceramic contents were prepared on copper alloy by cold spraying technology. The microstructure, mechanical properties and tribological properties of Cu-Ti
3
SiC
2
composite coatings with different ceramic contents were characterized and analyzed by scanning electron microscope, nano indentation instrument, electronic universal testing machine and reciprocating friction test. The main wear mechanism between Cu-Ti
3
SiC
2
composite coating and 7075Al alloy is adhesive wear during dry friction. The coating with better wear resistance has two main characteristics, as follow: first, it has better mechanical properties and stronger plastic deformation resistance; second, Ti
3
SiC
2
content is high, which can effectively reduce the adhesion of Al in the friction process.It is found that proper ceramic content can effectively improve the mechanical properties of the coa-ting, reduce the porosity of the coating and enhance the wear resistance of the coating.
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Microstructure and Strength Evaluation of EA4T Axle Steel Repaired by Laser-cladding
XIAO Peng, GAO Jiewei, LIU Ligen, HAN Jing
Materials Reports
2022,36(7 ):21070180 -7. DOI:10.11896/cldb.21070180
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In order to prolong the service life and reduce the scrap rate of high-speed train axles, laser cladding remanufacturing was used to repair the damaged surface of axles. In this study, 24CrNiMo alloy powder was cladding on EA4T axle steel surface, and the effect of heat treatment(HT) on the properties of the cladding layer was investigated. The microstructure, microhardness and tensile properties of the cladding layer were analyzed by optical microscope(OM), scanning electron microscope(SEM), electron backscattering diffraction(EBSD), Vickers hardness tester and universal testing machine. The fatigue strength was measured by four-point bending experiments, and the fatigue fracture was observed. The results showed that the microstructure of the cladding layer was mainly composed of cellular dendrite, columnar crystal and fine dendrites with random orientation. The microhardness, tensile strength and yield strength of the cladding layer were much higher than that of the substrate because of the fine grain strengthening and the formation of tempered martensite. After HT, due to grain coarsening and the formation of tempered sorbite, the hardness and strength of the cladding layer decreased, while the plasticity and toughness increased, and the fatigue strength of the sample decreased compared with the original cladding sample. The fatigue fracture of EA4T steel after laser cladding was a micro-cleavage fracture with cleavage steps and tear ridge, and the fracture after HT appeared quasi-cleavage cracks.
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Design and Research of Substituting Electroplating Chromium Coating on Metallurgical Cold Roll Surface Based on Finite Element Method
SUN Wei, ZHANG Shuting, DU Kaiping, OUYANG Peixuan, YANG Jinhe
Materials Reports
2022,36(7 ):21060140 -6. DOI:10.11896/cldb.21060140
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In the process of cold rolling, stress distribution of composite electroplating coating on the roll is an important factor that affects the service performance and life of the coating. In this work, the three-dimensional finite element model consisting of a cold roll and a steel plate was established by using the finite element simulation software ABAQUS based on the cold rolling condition. The effects of thickness, elastic modulus and friction coefficient of the coating on the distribution and magnitude of the peak stress at the roll-coating interface were systematically studied based on the theory of elastic-plastic deformation. The results show that with the increase of the coating thickness in the range of 20—80 μm, the peak stress at the interface first decreases gradually and slightly increases when the thickness exceeds 60 μm, with wear of the coating significantly decreasing and the grid damage obviously improved. With the increase of the elastic modulus of the coating in the range of 200—600 GPa, the peak stress of the roll-coating interface increases first and then decreases, which is the lowest at the elastic modulus of 600 GPa. The friction coefficient of the coating has little effect on the peak stress of the roll-coating interface, which is the secondary factor. Considering the performance requirements of the coating on the roll and according to the relationship between the peak stress of the interface and the bonding state of the coa-ting, it can be seen that the suitable thickness of the coating is 40—60 μm and the optimum elastic modulus is 400—600 GPa.
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