| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
|
|
|
|
|
| Research Progress on Controlled Influencing Factors and Synthesis Methods of Zirconia |
| DONG Zhengwen1, CHANG Xinru1, WANG Kai2, ZHOU Dianxiang1, CHEN Shuai1, GUO Song1,*
|
1 School of Safety Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China 2 China Ship Development and Design Center, Wuhan 430064, China |
|
|
|
|
Abstract Zirconia (ZrO2) nanomaterials are utilized across diverse fields, including medicine, aerospace, detection devices, and advanced ceramics, owing to their outstanding biocompatibility, optoelectronic properties, and mechanical performance, as well as excellent thermal stability and chemical stability. Currently, multiple synthesis techniques are employed to prepare ZrO2 nanomaterials, with precise control to form diverse structures for enhancing their service performance. This paper compiles relevant recent literature on the influencing factors and synthesis methods of ZrO2 in recent years, aiming to provide a reference for synthesizing high-performance ZrO2. During synthesis, the properties of ZrO2 are in-fluenced by multiple factors, such as particle morphology, degree of agglomeration, and crystallinity. The main influencing factors of ZrO2 performance are discussed by adjusting synthesis parameters (including reaction time, reaction and calcination temperatures, solution pH value, and types of precursor solution). Furthermore, ZrO2 can be synthesized through various methods, including hydrothermal method, solvothermal method, sol-gel method, chemical vapor deposition method, and microemulsion method. This paper focuses on elucidating the basic principles and respective advantages of synthesizing ZrO2 using these different methods. Finally, a comparison with the premixed stagnation flame synthesis method adopted in this paper is conducted to further analyze the impact of different synthetic method selection on the final product. The synthesis technology of ZrO2 will advance towards a more efficient, environmentally friendly and precise direction. On the one hand, with the conti-nuous emergence and cross-integration of emerging technologies, more innovative synthesis methods will be fostered. On the other hand, in-depth research on the properties of ZrO2 will drive the expansion of its applications in emerging fields. Meanwhile, how to reduce synthesis costs, improve production efficiency and realize large-scale industrial production will also be the key issues to be solved in the future.
|
|
Published: 25 April 2026
Online: 2026-05-06
|
|
|
|
|
1 Pchelintsev I, Karamov R, Tikhonov A, et al. Ceramics International, 2023, 49(18), 29409 2 Dashtbozorg B, Shi F Z, Tagliaferro A, et al. Acta Materialia, 2024, 262, 119457. 3 Wu P, Hu M Y, Chen L. Journal of the American Ceramic Society, 2019, 102(3), 889. 4 Falahchai M, Asli H N, Daneshvar M, et al. Heliyon, 2024, 10(21), e40164. 5 Ke J Y, Zhang J G, Chen X, et al. Ceramics International, 2024, 50(11), 20313. 6 Yati Y, Kang J S, Noh H, et al. Catalysis Today, 2024, 426, 114402. 7 Schwarzer E, Holtzhausen S, Scheithauer U, et al. Journal of the European Ceramic Society, 2018, 39(2-3), 522. 8 Yao Y, Cui H, Wabg W, et al. Journal of the European Ceramic Society, 2024, 44(16), 116795. 9 Li X G, Liu K F, Yue Y, et al. Journal of Colloid and Interface Science, 2022, 625, 936. 10 Ivnov K V, Baranchikov Y A, Kopitsa P G, et al. Journal of Solid State Chemistry, 2013, 198, 496. 11 Muhammad F H, Norzahir S. Materials Today: Proceedings, 2020, 31, 260. 12 Sun Q Y, Liu T, Wen T P, et al. Journal of the European Ceramic Society, 2023, 43(15), 6934. 13 Adamczyk A. Journal of Molecular Structure, 2022, 1264, 133143. 14 Liao Q D, Yu D H, Li X T, et al. Vacuum, 2025, 240, 114471. 15 Watanabe K, Miyao T, Higashiyama K, et al. Catalysis Communications, 2011, 12(11), 976. 16 Fang X, Xi Y T, He J, et al. Journal of Industrial and Engineering Chemistry, 2020, 88, 268. 17 Din U I, Shaharun M, Subbarao D, et al. Journal of Power Sources, 2015, 274, 619. 18 Goharshadi E, Hadadian M. Ceramics International, 2012, 38(3), 1771. 19 Zhang W W, Zhu Y X, Xu H M, et al. Catalysis Today, 2020, 351, 133. 20 Bapat R A, Yang H J, Chaubal V T, et al. RSC Advances, 2022, 12(20), 12773. 21 Guang Y Z, Yin C G, Cheng X Yet al. Sensors and Actuators B: Chemical, 2014, 192, 501. 22 Carla V, Ferenc K, Peitao L, et al. Computational Materials, 2021, 7(1), 156. 23 Goharshadi K E, Hadadian M. Ceramics International, 2012, 38(3), 1771. 24 Gaydhankar T R Jha R K, Nikalje M D, et al. Materials Research Bulletin, 2014, 55, 8. 25 Abd El-Aziz A S, Abd El-Aal M. Journal of Fuel Chemistry and Technology, 2018, 46(1), 67. 26 Aflaki M, Davar F. Ceramics International, 2014, 40(6), 8427. 27 Yang L D, Zhang W L, Hou G Q. Journal of Hebei Polytechnic University: Natural Science Edition, 2010, 32(2), 50 (in Chinese). 杨连弟, 张文丽, 侯贵芹. 河北理工大学学报:自然科学版, 2010, 32(2), 50. 28 Zhao Q, Yang Y, Sun Y X, et al. Micronanoelectronic Technology, 2007, 2007, 44(7), 76 (in Chinese). 赵青, 杨阳, 孙永欣, 等. 微纳电子技术, 2007, 44(7), 76. 29 Wang L, Gao J F, Ding F. Acta Chimica Sinica, 2014(3), 345(in Chinese). 王璐, 高峻峰, 丁峰. 化学学报, 2014(3), 345. 30 Hevorkian E, Michalczewski R, Rucki M, et al. Ceramics International, 2024, 50(19), 35226. 31 Sibil A, Douillard T, Cayron C, et al. Journal of the European Ceramic Society, 2011, 31(9), 1525. 32 Zhao Y C, Xu L J, Guo M Y, et al. Journal of Materials Research and Technology, 2022, 19, 4003. 33 Zhu B J, Tao Y, Qiu Y T, et al. Materials Science and Engineering of Powder Metallurgy, 2008, 13(2), 111(in Chinese). 祝宝军, 陶颖, 邱玉婷, 等. 粉末冶金材料科学与工程, 2008, 13(2), 111. 34 Wen Y, Zhou C L, Yu L F, et al. Solid State Sciences, 2023, 142, 107237. 35 Xin Y. Preparation of zirconia fibers via sol-gel method. Master's Thesis, Jingdezhen Ceramic Institure, China, 2015(in Chinese). 辛莹. 溶胶-凝胶法制备氧化锆纤维. 硕士学位论文, 景德镇陶瓷学院, 2015. 36 Peshev P, Stambolova I, Vassilev S, et al. Materials Science & Enginee-ring B, 2003, 97(1), 106. 37 Ji Y, Han L Z, Zheng W Q, et al. Chinese Journal of Tissue Engineering Research September, 2017, (26), 4131(in Chinese). 季洋, 韩黎梓, 郑伟麒, 等. 中国组织工程研究, 2017, 21(26), 4131 38 Zhu B J, Tao Y, Zhang T T, et al. Rare Metals and Cemented Carbides, 2008, 36(3), 1(in Chinese). 祝宝军, 陶颖, 张婷婷, 等. 稀有金属与硬质合金, 2008, 36(3), 1. 39 Liu L, Wang S Z, Zhang B Q, et al. Ceramics International, 2022, 48(4), 4401. 40 Zhao Q, Yang Y, Sun Y X, et al. Micronanoelectronic Technology, 2007, 44(7), 76(in Chinese). 赵青, 杨阳, 孙永欣, 等. 微纳电子技术, 2007, 44(7), 76. 41 Liu L, Jiang G Y, Wang S Z, et al. Chemical Engineering Journal, 2024, 493, 152393. 42 Gaydhankar T R, Jha R K, Nikalje M D, et al. Materials Research Bulletin, 2014, 55, 8. 43 Stoia M, Barvinschi P, Barbu-Tudoran L, et al. Journal of Crystal Growth, 2013, 381, 93. 44 Hamed N K A, Ahmad M K, Hairom N H H, et al. Applied Surface Science, 2020, 534, 147571. 45 Qi Q, Liu Z, Chen X M, et al. Biosensors and Bioelectronics, 2024, 264, 116693. 46 Ahmadzadeh, Mirzaei M, Sabouri Z, et al. Inorganic Chemistry Communications, 2024, 160, 111904. 47 Deng G Z, Tang X D, Li J J, et al. Fuel, 2025, 390, 134709. 48 Shandilya R, Kaur G A, Rai R. Materials Chemistry and Physics, 2021, 263, 124422. 49 Sousa O E, Campos M B T, Bergamo T P E, et al. Ceramics International, 2024, 50(19), 36418. 50 Dell’Agli G, Mascolo G. Journal of the European Ceramic Society, 2004, 24(6), 915. 51 Loïc G, Cécile M, Christophe G, et al. Ultramicroscopy, 2024, 267, 114047. 52 Araújo-Júnior N S E, Bergamo T P E, Campos M B T, et al. Journal of the Mechanical Behavior of Biomedical Materials, 2020, 112, 104021. 53 Bergamo T P E, Campos M B T, Lopes C O A, et al. Journal of the Mechanical Behavior of Biomedical Materials, 2021, 124, 104832. 54 Song L R, Li J F, Zhou H D, et al. Ceramics International, 2022, 48(5), 6591. 55 Syeda S B, Ramsha S, Rana R M K, et al. Materials Science in Semiconductor Processing, 2024, 178, 108419. 56 Chang Q B, Zhou J R, Wang Y Q, et al. Advanced Powder Technology, 2010, 10(4), 425. 57 Zulhadjri, Alfir R, Yulia E, et al. Kuwait Journal of Science, 2025, 52(1), 100342. 58 Irawan C, Refki F M, Hidayat R, et al. South African Journal of Chemical Engineering, 2023, 45, 247. 59 Belgacem B J, Nouiri M, Medjnoun K, et al. Materials Science in Semiconductor Processing, 2018, 83, 224. 60 Zhang Y J, Deng Q S, Zhang Y, et al. Ceramics International, 2024, 50(14), 25192. 61 Li G H, Hong Z L, Yang H, et al. Journal of Alloys and Compounds, 2012, 532, 98. 62 Li C Y, Xie T F, Dai J W, et al. Ceramics International, 2018, 44(1), 747. 63 Muge S, Qi F Y, Tian X Y, et al. Journal of Solid State Chemistry, 2021, 296, 121964. 64 Shu Z X, Jiao X L, Chen D. Journal of Alloys and Compounds, 2011, 509(37), 9200. 65 Hua Z L, Wang M X, Xiao P, et al. Journal of the European Ceramic Society, 2005, 26(12), 2257. 66 Liu Z Y, Xiang Q X, ZhangG H, et al. Ceramics International, 2024, 50(5), 7789. 67 Auxéméry A, Frias B B, Smal E, et al. The Journal of Supercritical Fluids, 2020, 162, 104855. 68 Liu C, Wang W L, Xu Y. Applied Surface Science, 2018, 441, 482. 69 Shu Z X, Jiao X L, Chen D R. Journal of Alloys and Compounds, 2011, 509(37), 9200. 70 Lee H S, Lee H, Lee W E, et al. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 676, 132282. 71 Xu L L, Huang T. Coating and Protection, 2015, 36(10), 51(in Chinese). 徐磊磊, 黄腾. 涂料技术与文摘, 2015, 36(10), 51. 72 Wang J, Li C, Xu B. Chemical Industry and Engineering, 2009, 26(3), 273(in Chinese). 王焆, 李晨, 徐博. 化学工业与工程, 2009, 26(3), 273. 73 Haritha A, Faturíková K, Duran A, et al. Open Ceramics, 2024, 18, 100607. 74 Alhindawy G I, Marashdeh W M, Aljaafreh J M, et al. Nuclear Engineering and Technology, 2024, 56(7), 2444. 75 Yao X Z, Zhao W Y, Zhang H Q, et al. Colloid and Interface Science Communications, 2023, 57, 100758. 76 Li L, Liu X L, Wang G, et al. Chemical Engineering Journal, 2020, 421(2), 127744. 77 Fernández-Osorio A, Ramos-Olmos L, Julián C F. Materials Chemistry and Physics, 2014, 147(3), 796. 78 Chen Y J, Lunsford K S, Song Y, et al. Chemical Engineering Journal, 2010, 170(2), 518. 79 Zhang J Y, Sun H Y, Lin S, et al. Ceramics International, 2024, 50(7), 10698. 80 Wang W, Weng D, Wu X. Progress in Natural Science: Materials International, 2011, 21(2), 117. 81 Díaz-Parralejo A, Macías-García A, Cuerda-Correa E M, et al. Journal of Non-Crystalline Solids, 2005, 351(24), 2115. 82 Prasad R A, Shamsheera K O, Joseph A. Journal of the Indian Chemical Society, 2021, 98(4), 100052 83 Guo Z J. Low Carbon World, 2017(27), 288(in Chinese). 郭展郡. 低碳世界, 2017(27), 288. 84 Kazuki A, Keigo S, Shin-Ichi N, et al. Journal of Membrane Science, 2024, 692, 122293. 85 Lv S, Yang Q, Ye F, et al. Ceramics International, 2024, 50(22), 46557. 86 Majumdar S, Chaitoglou S, Serafin J, et al. International Journal of Hydrogen Energy, 2024, 89, 977. 87 Zhao K. Study on the applications of carbon nanotubes in electroanalytical chemistry. Ph. D. Thesis, East China Normal University, China, 2007(in Chinese). 赵琨. 碳纳米管在电分析化学中的应用研究. 博士学位论文, 华东师范大学, 2007. 88 Eva H, Izumi K, Nicolas L, et al. Microporous and Mesoporous Materials, 2012, 163, 229. 89 Ron S F, Yoram C. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2001, 191, 27. 90 Sanchez-Dominguez M, Liotta F L, Carlo D G, et al. Catalysis Today, 2010, 158, 35. 91 Ma T, Huang Y, Yang J, et al. Materials & Design, 2004, 25(6), 515. 92 Wu J, Glisenti A, Dacquin J P, et al. Applied Catalysis A: General, 2020, 598, 117527. 93 Kondo M, Tada S, Shioiri T, et al. Applied Catalysis A, General, 2024, 676, 119638. 94 Guild C, Biswas S, Meng Y T, et al. Catalysis Today, 2014, 238, 87. 95 Xiao B, Jiao A Q, Zhang Y R, et al. Sensors and Actuators: B. Chemical, 2021, 346, 130470. 96 Miki I, Junichi H. Advanced Powder Technology, 2022, 33(7), 103647. 97 Zhao F, Li S D, Chen Y F. Journal of Solid State Chemistry, 2021, 300, 122216. 98 Harish V, Ansari M M, Tewari D, et al. Journal of the Taiwan Institute of Chemical Engineers, 2023, 149, 105010. 99 Cheng Y, Guo S, Tang Z D, et al. Transducer and Microsystem Technologies, 2024, 43(1), 21(in Chinese). 程洋, 郭耸, 汤振东, 等. 传感器与微系统, 2024, 43(1), 21. 100 Liu S, Mohammadi M M, Swihart M T. Chemical Engineering Journal, 2021, 405, 126958. 101 Zhou D, Ding C Z, Han W J, et al. Ceramics International, 2024, 50(23), 49210. 102 Gutierrez-Sanchez C D, Téllez-Jurado L, Dorantes-Rosales H J. Ceramics International, 2024, 50(11), 20547. |
|
|
|