大斯托克斯位移荧光染料研究进展

doi:10.11896/cldb.24060129

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Abstract As an important class of fluorescent materials,fluorescent dyes are widely used to label and stain target in a great variety of fields. However, commercially available fluorescent dyes often exhibit very small Stokes shifts, resulting in their fluorescent signal easily influenced by high background interference and self-absorption. Over the past few decades, abundant fluorescent dyes with large Stokes shifts have been synthesized and various mechanisms to extend the Stokes shift have also been developed and implemented. In this paper, we reviewed four mechanisms to enlarge Stokes shift and three types of large Stokes shift fluorescent dyes based on different frameworks. The sources of large Stokes shift are attributed to the substituent groups and the expanded conjugation system. Finally, the research progress to enlarge Stokes shift is introduced while analyzing the ideas to design molecule and photophysical processes based on different mechanisms with representative fluorescent dyes.

Key words： fluorescent dye large Stokes shift excited-state intramolecular proton transfer intramolecular charge transfer energy transfer

Published: 25 July 2025 Online: 2025-07-29

CLC number:

TQ617.3

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	Articles by authors
	ZHENG Senzhe
	DONG Wenkun
	CHEN Dong
	LING Shisheng
	QIAO Xusheng
	FAN Xianping

Cite this article:

ZHENG Senzhe,DONG Wenkun,CHEN Dong, et al. Research Progress on Large Stokes Shift Fluorescent Dyes[J]. Materials Reports, 2025, 39(14): 24060129-8.

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https://www.mater-rep.com/EN/10.11896/cldb.24060129 OR https://www.mater-rep.com/EN/Y2025/V39/I14/24060129

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