METALS AND METAL MATRIX COMPOSITES |
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Tribological Properties of Fe-based Amorphous Coatings in Different Media Solutions |
LI Chunling1,*, WANG Rongfu1, ZHAI Haimin2, LI Wensheng3
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1 School of Mechanical and Electrical Engineering, Lanzhou University of Technology, Lanzhou 730050, China 2 School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China 3 College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou 730070, China |
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Abstract Fe-based amorphous coatings were prepared on 316L stainless steel substrates through detonation spraying. The tribological behavior of these coatings was investigated in various solutions, including 3.5% (mass fraction) NaCl, 0.01 mol/L NaOH, and 0.01 mol/L H2SO4. The findings reveal that the fabricated Fe-based amorphous coating possesses a homogenous amorphous structure and lower porosity, exhibiting significantly higher hardness than the 316L stainless steel substrate. Notably, the lubrication effect of the solutions results in a substantial reduction in the friction coefficient and wear rate of the coating compared to dry sliding conditions. By XPS, it’s found that a corrosion-resistant passive film composed primarily of Cr and Mo oxides is formed on the coating surface. In the NaCl solution, a large amount of oxides are generated to effectively minimize the wear rate to 4.36×10-6 mm3·N-1·m-1. Similarly, the SiO2 film formed in the H2SO4 solution also contributes to a reduced wear rate of 4.61×10-6 mm3·N-1·m-1. However, in the NaOH solution, the high corrosion potential of the strong alkali leads to the highest wear rate of 6.63×10-6 mm3·N-1·m-1 for the coating. The wear mechanism of the coating in these solutions is primarily influenced by the combined effects of mechanical and corrosive wear, with mechanical wear playing a dominant role.
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Published:
Online: 2025-05-29
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