METALS AND METAL MATRIX COMPOSITES |
|
|
|
|
|
Effect of Mn Content on High-temperature Tribological Properties of Laser Cladding FeCoCrNiMnx High-entropy Alloy Coatings |
XIE Xiaoming1, SHEN Ying2, LIU Xiubo1,*, ZHU Zhengxing1, LI Mingxi3,*
|
1 Hunan Province Key Laboratory of Materials Surface/Interface Science & Technology, Central South University of Forestry & Technology, Changsha 410004, China 2 School of Aeronautics and Astronautics, Nanchang Institute of Technology, Nanchang 330044, China 3 Agriculture Equipment Institute of Hunan, Changsha 410125, China |
|
|
Abstract High-entropy alloy coatings have great potentialability to improve the wear-resistant and friction-reducing properties of steel substrates. In order to investigate the effects of different Mn contents on the high-temperature tribological properties of laser-cladding-coated FeCoCrNiMnx high-entropy alloy coatings, five high-entropy alloy coatings of FeCoCrNiMnx (x=0, 0.25, 0.5, 0.75, 1.0) were successfully prepared on the surface of Q235 steel using laser cladding technology. The phase composition, micro-morphology and high-temperature tribological properties of five coa-tings were systematically analyzed by characterization and performance testing methods, such as XRD, SEM, EDS and high-temperature friction-wear testing, then their wear-resistant and friction-reducing mechanisms at high temperatures were discussed. The results show that all five high-entropy alloys formed simple solid solution phases and no complex phases were generated. Compared to Q235 steel, five coatings have significantly improved wear and friction reduction properties at high temperature. The average friction coefficients of coatings decrease firstly and then increase with the increasing of Mn content, but the average friction coefficients of all coatings containing Mn element were lower than that without Mn element. To high temperature wear resistance, five coatings' wear rates showed an overall decreasing trend with increasing of Mn content. Among 5 kinds of coatings with Mn element, the one with x=1 got the lowest wear rate of 2.71×10-4 mm3/(N·m), which is reduced by 61.2% and 33.9% compared to substrate and the coating without Mn element, respectively, and the wear mechanisms of five coatings at high temperature are dominated by abrasive wear and oxidative wear.
|
Published: 10 December 2024
Online: 2024-12-10
|
|
Fund:National Natural Science Foundation of China (52075559), Hunan Provincial Key Research & Development Program (2022GK2030), Hunan Provincial Agricultural Science and Technology Innovation Fund Project (2022CX131). |
|
|
1 Zhu L D, Xue P S, Lan Q, et al. Optics & Laser Technology, 2021, 138, 106915. 2 Gao D Q, Wang R, Chen W. et al. Hot Working Technology, 2017, 46(12), 14(in Chinese). 高东强, 王蕊, 陈威, 等. 热加工工艺, 2017, 46(12), 14. 3 Lu P Z, Jia L, Zhang C, et al. Materials Today Communications, 2023, 37, 107162. 4 Lu Y Z, Huang G K, Wang Y Z, et al. Materials Letters, 2018, 210, 46. 5 Arif Z U, Khalid M Y, Rehman E U, et al. Journal of Manufacturing Processes, 2021, 68, 225. 6 Yeh J W, Chen S K, Lin S J, et al. Advanced Engineering Materials, 2004, 6(5), 299. 7 Cantor B, Chang I T H, Knight P, et al. Materials Science and Enginee-ring, A, 2004, 375, 213. 8 Liu Y F, Chang T, Liu X B, et al. Surface Technology, 2021, 50(8), 156(in Chinese). 刘一帆, 常涛, 刘秀波, 等. 表面技术, 2021, 50(8), 156. 9 Han B, Zhang S Y, Zhang T M, et al. Intermetallics, 2023, 158, 107909. 10 Liu H, Gao Q, Dai J B, et al. Tribology International, 2022, 172, 107574. 11 Guo W M, Ding N, Liu G Q, et al. Materials Characterization, 2022, 184, 111660. 12 Li S, Lei S, Wu Y B, et al. ECS Journal of Solid State Science and Technology, 2021, 10(3), 033003. 13 Li Z T, Jing C N, Feng Y, et al. Materials Today Communications, 2023, 35, 105800. 14 Jin G, Cai Z B, Guan Y J, et al. Applied Surface Science, 2018, 445, 113. 15 Zhu Z X, Liu X B, Liu Y F, et al. Wear, 2023, 512, 204533. 16 Lin D Y, Zhang N N, He B, et al. Journal of Iron and Steel Research International, 2017, 24(2), 184. 17 Hao W J, Sun R L, Niu W, et al. Surface Technology, 2021, 50(8), 343(in Chinese). 郝文俊, 孙荣禄, 牛伟, 等. 表面技术, 2021, 50(8), 343. 18 Jiang H, Han K M, Li D Y, et al. Crystals, 2018, 8(11), 409. 19 Yuan Q L, Feng X D, Cao J J, et al. Materials Reports, 2010, 24(3), 112(in Chinese). 袁庆龙, 冯旭东, 曹晶晶, 等. 材料导报, 2010, 24(3), 112. 20 Wang Y D, Gong S L, Tang M R, et al. Journal of Heilongjiang University of Science & Technology, 2022, 32(3), 368(in Chinese). 王永东, 宫书林, 汤明日, 等. 黑龙江科技大学学报, 2022, 32(3), 368. 21 Zhang M N, Wang D F, He L J, et al. Optics & Laser Technology, 2022, 149, 107845. 22 Mohanty A, Sampreeth J K, Bembalge O, et al. Surface and Coatings Technology, 2019, 380, 125028. 23 Yang X, Chen S Y, Cotton J D, et al. Jom, 2014, 66, 2009. 24 Smilgies D M. Journal of Applied Crystallography, 2009, 42(6), 1030. 25 Zhang T, Zhao R D, Wu F F, et al. Materials Science and Engineering, A, 2020, 780, 139182. 26 Wang C M, Yu J X, Zhang Y, et al. Materials & Design, 2019, 182, 108040. 27 Song B X, Yu T B, Jiang X Y, et al. International Journal of Mechanical Sciences, 2020, 165, 105207. 28 Khoramm A, Jamaloei A D, Jagari A, et al. Journal of Materials Processing Technology, 2020, 284, 116735. 29 Nishizawa T, Ishida K. Bulletin of Alloy Phase Diagrams, 1984, 5(3), 250. 30 Naghavi S S, Hegde V I, Wolverton C. Acta Materialia, 2017, 132, 467. 31 Teskeredzic A, Demirdzic I, Muzaferija S. Numerical Heat Transfer, Part B: Fundamentals, 2015, 68(4), 295. 32 Gao Z N, Wang L L, Wang Y N, et al. Journal of Alloys and Compounds, 2022, 903, 163905. 33 Cui Y, Shen J, Manladan S M, et al. Applied Surface Science, 2020, 512, 145736. 34 Zhu Z X, Liu X B, Liu Y F, et al. Journal of Materials Engineering, 2023, 51(3), 78(in Chinese). 朱正兴, 刘秀波, 刘一帆, 等. 材料工程, 2023, 51(3), 78. 35 Sun D, Cai Y C, Zhu L S, et al. Surface and Coatings Technology, 2022, 438, 128407. |
|
|
|