METALS AND METAL MATRIX COMPOSITES |
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Preparation and Performance of Three-dimensionally Ordered Macropores Copper-based Composites for Iodine Vapor Capture |
WANG Longjiang1, LI Yongguo1, YU Jie1, FAN Huiling2, WU Bo1, HAN Lihong1, LI Yanzhang1, QIAO Taifei1
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1 Institute of Environmental Engineering and Technology, China Institute for Radiation Protection, Taiyuan 030006; 2 State Key Laboratory of Coal Science and Technology Co-founded by Shanxi Province and the Ministry of Science and Technology,Taiyuan University of Technology,Taiyuan 030024 |
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Abstract Copper-silica composites with/without three-dimensionally ordered macropores(3DOM) structure were synthesized by colloidal crystal template method and sol-gel method respectively. The performance of prepared samples for iodine vapor adsorption was evaluated by static testing, the samples before and after adsorption were characterized through SEM,TEM, XRD, TG-DTG, and the N2 isotherm adsorption desorption test was carried out. The results indicated that the structure of 3DOM copper-silica composites is intact, and the performance of 3DOM copper-si-lica composites was improved highly compared with copper-silica composites as well as the commercial nano-copper, this is mainly attributed to the unique structure of 3DOM: the develop pores, high surface areas and nano-sized crystal. This study provided significant results for development of new high performance iodine adsorbents.
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Published: 11 March 2019
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Fund:This work was financially supported by the National Natural Science Foundation of China (21576180). |
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