羊毛角蛋白亲水性纳米纤维膜的制备及性能

doi:10.11896/cldb.25010131

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (31156KB)
Export: BibTeX | EndNote (RIS)

Abstract Keratin-based nanofibrous membranes hold significant promise for wound dressings; however, developing fibrous membranes that simulta-neously maintain good hydrophilicity and water stability remains challenging. To fabricate nanofiber membranes with high porosity, favorable water stability, and good hydrophilicity, this study utilized polyvinyl alcohol (PVA), wool keratin (KE) and antibacterial agent benzalkonium chloride (BKC) as raw materials. A three-component nanofiber membrane stable in water at room temperature and 40 ℃ was constructed via electrospinning followed by thermal crosslinking. The membranes’ apparent morphology, chemical structure, thermal stability, wettability and porosity were characterized. Results demonstrated that, compared to two-component fiber membranes, the membrane prepared from a 6wt% PVA solution with a PVA/KE/BKC mass ratio of 1∶0.25∶0.1 exhibited optimal water stability while maintaining good hydrophilicity. The water stability and wettability of the PVA/KE/BKC fiber membrane can be tailored by adjusting the spinning solution composition and the thermal crosslinking method, indicating its potential application in wound dressings.

Key words： nanofiber electrospinning antibacterial keratin benzalkonium chloride

Received: 10 May 2026 Published: Online: 2026-05-18

CLC number:

TQ340.64

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHANG Shuqi
	ZHANG Jing
	XU Chengshu
	SHANG Yudong
	REN Yan
	ZHANG Xinqing

Cite this article:

ZHANG Shuqi,ZHANG Jing,XU Chengshu, et al. Preparation and Properties of Hydrophilic Nanofiber Membrane Based onWool Keratin[J]. Materials Reports, 2026, 40(9): 25010131-8.

URL:

https://www.mater-rep.com/EN/10.11896/cldb.25010131 OR https://www.mater-rep.com/EN/Y2026/V40/I9/25010131

1 Pires P C, Mascarenhas-Melo F, Pedrosa K, et al.European Polymer Journal, 2023, 187, 111868.
2 Dharmaraj D, Chavan N, Likhitha U, et al.Journal of Drug Delivery Science and Technology, 2024, 99, 105981.
3 Chopra H, Kumar S, Safi S Z, et al.International Journal of Surgery, 2022, 104, 106793.
4 Al-Abduljabbar A, Farooq I.Polymers, 2022, 15(1), 65.
5 Han Y, Wei H, Ding Q, et al.Molecules, 2024, 29(17), 4271.
6 Ma S, Li A, Pan L.Polymers, 2024, 16(17), 2459.
7 Cao G, Rong M Z, Zhang M Q.ACS Sustainable Chemistry & Engineering, 2020, 8(49), 18148.
8 Cocean I, Cocean A, Postolachi C, et al.Applied Surface Science, 2019, 488, 418.
9 Xu Z, Han S, Guan S, et al.Food Chemistry: X, 2024, 23, 101557.
10 Sun W, Gregory D A, Zhao X.Advances in Colloid and Interface Science, 2023, 314, 102866.
11 Björneholm O, Öhrwall G, de Brito A N, et al.Accounts of Chemical Research, 2022, 55(23), 3285.
12 Serag E, El-Aziz A M A, El-Maghraby A, et al.Scientific Reports, 2022, 12(1), 15460.
13 Ramirez D O S, Vineis C, Cruz-Maya I, et al.Journal of Functional Biomaterials, 2022, 14(1), 5.
14 Tran C D, Prosenc F, Franko M, et al.Carbohydrate Polymers, 2016, 151, 1269.
15 Lyu P, Zhang C, Wang Y, et al.Advanced Powder Technology, 2020, 31(1), 87.
16 Zhang J, Li Y, Li J, et al.Powder Technology, 2013, 246, 356.
17 Ren B H.Study on molecular interaction mechanism and rheological properties of polyvinyl alcohol/surfactants systems.Master’s Thesis, Tianjin University, China, 2021(in Chinese).
任宝华.聚乙烯醇/表面活性剂分子作用机理及流变性质的研究.硕士学位论文, 天津大学, 2021.
18 Yang Q.Study on preparation and modification of polyvinyl alcohol nanomaterials.Master’s Thesis, Dalian Polytechnic University, China, 2021 (in Chinese).
杨强.聚乙烯醇纳米材料制备与改性研究.硕士学位论文, 大连工业大学, 2021.
19 Ramirez D O S, Cruz-Maya I, Vineis C, et al.Journal of Functional Biomaterials, 2021, 12(4), 76.
20 Mouro C, Martins R, Gomes A P, et al.Gels, 2023, 9(8), 661.
21 Khajavi R, Rahimi M K, Abbasipour M, et al.Journal of Bioactive and Compatible Polymers, 2015, 31(1), 60.
22 Lee J, Boo C, Ryu W H, et al.ACS Applied Materials & Interfaces, 2016, 8(17), 11154.
23 Lundin J G, Coneski P N, Fulmer P A, et al.Reactive and Functional Polymers, 2014, 77, 39.
24 Kriegel C, Kit K M, McClements D J, et al.Polymer, 2009, 50(1), 189.
25 Zakrzewska A, Zargarian S S, Rinoldi C, et al.ACS Materials Au, 2023, 3(5), 464.