| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Construction and Modification of Germanium-based Anode Materials in Lithium-ion Batteries |
| GOU Qingyi1, LIAO Hua2, CHEN Fengyang2, ZENG Ruilin2, LIU Huizhe1, YANG Ni3, HOU Yanqing1,2,*, XIE Gang3
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1 State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650000, China
2 School of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650000, China
3 Kunming Metallurgical Research Institute Co., Ltd., Kunming 650000, China |
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Abstract Lithium-ion batteries have been widely used in portable electronic devices and electric vehicles due to their high energy density, long cycle life, and no memory effect. Germanium-based anode materials have emerged as a key focus of research in the realm of lithium-ion batte-ries, owing to their high theoretical specific capacity (approximately 4 times that of graphite), low lithium insertion potential, and excellent conductivity (roughly 104 times that of silicon). In recent years, researchers have conducted extensive studies on the synthesis and modification of germanium-based anode materials, resulting in significant breakthroughs. However, there are still many challenges in the cycling stability of germa-nium-based anode materials, mainly due to the severe volume effect and unstable interface during the charge and discharge processes. This paper presents the preparation methods, morphology, structure, and electrochemical performance of diverse germanium-based anode materials through the lens of four modification strategies: dimensional nanostructuring, porous structuring, carbon material composites, and alloying. Finally, it delves into the research progress of modification techniques and approaches for germanium-based anode materials, along with outlining future research directions.
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Published: 25 April 2025
Online: 2025-04-18
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