TiFe基储氢合金活化及电化学性能研究进展

doi:10.11896/cldb.24010105

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Abstract The energy crisis is giving rise to the rapid development of new energy. Hydrogen is one of the widely distributed elements on earth, and is considered an ideal secondary energy source due to its high calorific value, abundant sources, and environmental characteristics. With the rapid growth of the new energy vehicle industry, fuel cell technology, especially nickel hydrogen (Ni-MH) fuel cells, has become a hot research. Among various hydrogen storage materials, TiFe based alloys are highly favored due to their low cost and high hydrogen storage capacity, and have become a focus of modern research as negative electrode materials for nickel hydrogen fuel cells. TiFe based alloys are a typical represen-tative of AB type hydrogen storage alloys, with potential high theoretical hydrogen storage capacity, and exhibit good reversible hydrogen absorption and desorption performance at room temperature. However, the application of TiFe based alloys faces some challenges. Firstly, the activation process of alloys requires extreme conditions, which increases the complexity of preparation. Secondly, alloys are susceptible to poisoning during hydrogen absorption and desorption, which may reduce their performance. Finally, fluctuations in the hydrogen absorption and desorption kinetics of alloys may also have adverse effects on their performance in electrochemical applications. These issues limit the further development of TiFe based alloys in commercial applications.
Single element alloying or multi-element alloying can effectively change the composition layout and lattice structure of TiFe based alloys, optimize hydrogen storage performance, including improving activation kinetics, increasing hydrogen storage capacity, and optimizing hydrogen absorption and desorption kinetics. It can also significantly improve the electrochemical comprehensive performance of the alloy, including maximum discharge capacity, high rate discharge, and cycle stability. The casting method and ball milling method used in the preparation process can also increase the hydrogen storage activity of the alloy, significantly improve its hydrogen absorption and desorption kinetic performance, and thus improve the electrochemical charging and discharging capacitance. The surface modification method optimizes the microstructure and contact sites of the alloy, thereby improving hydrogen storage performance and cycle life, and making the electrochemical charging and discharging process of the alloy more stable.

Key words： hydrogen storage alloy TiFe based alloy activity property electrochemical performance

Published: 25 February 2025 Online: 2025-02-18

CLC number:

TG174

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	SUN Lili
	GUAN Ning
	WANG Yong
	LI Yongcun

Cite this article:

SUN Lili,GUAN Ning,WANG Yong, et al. Research Progress on Activation and Electrochemistry Property of TiFe Based Hydrogen Storage Alloys[J]. Materials Reports, 2025, 39(4): 24010105-9.

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https://www.mater-rep.com/EN/10.11896/cldb.24010105 OR https://www.mater-rep.com/EN/Y2025/V39/I4/24010105

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