ZSM-22在烷烃加氢异构反应中应用的研究进展

doi:10.11896/cldb.24120008

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Abstract The bifunctional catalysts with zeolites as supports have long been the main research topic in the hydroisomerization of alkanes. ZSM-22, as a type of single dimensional zeolite, has demonstrated excellent shape selectivity in the isomerization reaction. However, the crystal morphology-induced diffusion limitation of ZSM-22 is an unavoidable obstacle to its application. This review briefly describes the diffusion and hydroisomerization mechanism of alkanes, and outlines the efforts in exploring and hypothesizing the preparation of ideal ZSM-22 made by global researchers in recent years. It focuses on the methods of adjusting, doping, and postprocessing of zeolites to elaborate their influence on the catalytic performance, and summarizes the optimization law of the zeolite support as well as its limitations in the preparation process. The structure-activity relationship between the modified molecular sieve properties and the catalytic performance is discussed in detail. The paper ends with a discussion about the future trends of the research on postprocessing ZSM-22 for enhancing its quality and efficiency.

Key words： alkane hydroisomerization ZSM-22 molecular sieve postprocessing reaction mechanism

Published: 25 December 2025 Online: 2025-12-17

CLC number:	TQ032
	TE65

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	WANG Zhiying
	SAN Xiaoguang
	MIAO Yulu
	DONG Lei

Cite this article:

WANG Zhiying,SAN Xiaoguang,MIAO Yulu, et al. Research Progress on Applying ZSM-22 to Alkane Hydroisomerization[J]. Materials Reports, 2025, 39(24): 24120008-9.

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https://www.mater-rep.com/EN/10.11896/cldb.24120008 OR https://www.mater-rep.com/EN/Y2025/V39/I24/24120008

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