| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Advances in the Expansion Mechanism and Modification of Silicon-based Anode for Lithium-ion Batteries |
| FU Ju1,2, MA Xingyang1,2, XIE Wenna1,2, LYU Pengfei1,2, ZHI Maoyong1,2,*
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1 Civil Aircraft Fire Science and Safety Engineering Key Laboratory of Sichuan Province,College of Civil Aviation Safety Engineering,Civil Aviation Flight University of China,Guanghan 618307,Sichuan,China
2 Sichuan Key Technology Engineering Research Center for All-electric Navigable Aircraft,College of Civil Aviation Safety Engineering,Civil Aviation Flight University of China,Guanghan 618307,Sichuan,China |
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Abstract Lithium-ion batteries are developing rapidly in the energy field due to their advantages of high energy density,low self-discharge rate,no me-mory effect,etc.Silicon-based anodes are considered to be the most promising anode material following graphite due to its high theoretical specific capacity.However,the serious volume expansion of silicon-based anodes during the lithiation/delithiation process results in capacity degradation,coulombic efficiency decline,and other issues,which still hinder its commercialization.This paper reviews the expansion mechanism and modification research progress of silicon-based anodes,aiming to provide theoretical support and practical guidance for solving the expansion problem faced when it is used as anode material for lithium-ion batteries.Through the introduction of the working principle of silicon-based anodes,it discusses the expansion mechanism in depth and analyzes in detail the effects and potential hazards of expansion on the performance of silicon-based anodes.More specifically,it focuses on four aspects,namely,multi-dimensional nano-silicon structure,composite,binder,and electrolyte design,to systematically elucidate the research on silicon-based anode modification,and to make a prospective outlook on the future development.
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Published: 25 September 2025
Online: 2025-09-11
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2025, Vol. 39 
