V含量对S30403奥氏体不锈钢高温抗氧化性能的影响

doi:10.11896/cldb.24040050

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Abstract Austenitic stainless steel, commonly used as a structural material in nuclear power plants, may experience overheating and failures due to the thickening of surface oxides at high temperatures, leading to significant safety accidents. This study utilized the static discontinuous oxidation weight gain method to investigate the high-temperature oxidation resistance of six different V-content S30403 austenitic stainless steels in a 900 ℃ air environment. The results show that Steel 1# exhibited an average oxidation rate of 0.056 9 g·m^-2·h^-1 after 100 hours of oxidation, meeting the complete oxidation resistance level. As the V content in the steel increased to 0.49%, Steel 6# demonstrated the highest average oxidation rate of 0.693 1 g·m^-2·h^-1, corresponding to the oxidation resistance level. The V element in the experimental steels facilitated the internal oxidation of Cr and Si elements, leading to a reduction in the surface oxide content of Cr₂O₃ and SiO₂ in V-containing steels. Mn and Fe elements diffused outward through the oxide film to form a spinel structure of MnCr₂O₄. With the increase of V content in the steels, the continuity and density of the surface oxide film on Steels 2# to 6# gradually decrease, resulting in a decline in high-temperature oxidation resistance performance.

Key words： austenitic stainless steel high-temperature oxidation resistance diffusion control oxide film

Published: Online: 2025-08-28

CLC number:

TG144

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	Articles by authors
	SHEN Bin
	GU Shangjun
	WANG Jie
	WEI Fulong
	XIE Xiang
	LI Zhiying
	ZHANG Junxiang
	LI Changrong

Cite this article:

SHEN Bin,GU Shangjun,WANG Jie, et al. Effect of V Content on High-temperature Oxidation Resistance of S30403 Austenitic Stainless Steel[J]. Materials Reports, 2025, 39(17): 24040050-9.

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https://www.mater-rep.com/EN/10.11896/cldb.24040050 OR https://www.mater-rep.com/EN/Y2025/V39/I17/24040050

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