COMPUTATIONAL SIMULATION |
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Crystallization Kinetics Study of K2O·CaO·4B2O3·12H2O |
BI Ying, WANG Guosheng
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College of Environmental and Safety Engineering, Shenyang University of Chemical Technology, Shenyang 110142 |
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Abstract With KOH, H3BO3 and CaCl2·2H2O as raw materials,K2O·CaO·4B2O3·12H2O crystal was prepared by water solution method which is easily industrialized and pollution-free. Under the condition of 20 ℃, the crystallization process of K2O·CaO·4B2O3·12H2O crystals was studied, and in consequence, the crystallization kinetics equation and the relevant reaction rate equation were obtained.
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Published: 25 May 2018
Online: 2018-07-06
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1 Frosta RL, Lópeza A, Scholzb R, et al. Structural characterization of the borate mineral inyoite CaB3O3(OH)5·4(H2O)[J]. Journal of Molecular Structure,2015,1080(25):99. 2 Wei Q, Cheng J W, He C, et al. An acentric calcium borate Ca2-[B5O9]·(OH)·H2O:Synthesis, structure, and nonliner optical property[J].Inorganic Chemistry,2014,53(21):11757. 3 Frosta R L, Lópeza A, Scholzb R, et al.Vibrational spectroscopy of the borate mineral tunellite SrB6O9(OH)2·3(H2O) implications for the molecular structure[J]. Journal of Molecular Structure,2014,1059(5):40. 4 Yi X, Cong R, Yue M, et al. Coordination environment evolution of Eu3+during the dehydration and recrystallization processes of Sm1-x-Eux[B9O13(OH)4]·H2O by photoluminescent characteristics[J]. Dalton Trans actions,2013,25(42):16318. 5 Li P, Liu Z H. Standard molar enthalpies of formation for the two alkali metal borates, Na6[B4O5(OH)4]3·8H2O and K4[B10O15-(OH)4][J]. Journal of Chemical & Engineering Data,2011,56(1):102. 6 Li W, Yang B F, He H, et al. Two new organic borates with the large[B14O20(OH)6]4-oxoboron clusters[J]. Journal of Cluster Science,2014,25(2):617. 7 Belokoneva E L, Dimitrova O V, Stefanovich S Y. Structures and properties of layered barium borates Ba0.975-[B6O9(OH)(O0.975-Br0.025)·B2O(OH)3], Ba2[B5O8(OH)2](OH), Na2Ba2[B20O34-(OH)4] and Ba5[B20O33(OH)4]H2O[J]. Crystallography Reports,2012,57:64. 8 Cong R H, Yang T, Wang Z M, et al. Syntheses, structure, and luminescent properties of novel hydrated rare earth borates Ln2B6O10(OH)4·H2O (Ln= Pr, Nd, Sm, Eu, Gd, Dy, Ho, and Y)[J]. Inorganic Chemistry,2011,50(5):1767. 9 Belokoneva E L, Zorina A P, Dimitrova O V. New layer megaborate Sm3[B13O22(OH)(3)](OH)·3H2O and its place in the structural systematics[J].Crystallography Reports,2012,57(4):499. 10 Chen Y P, Cheng H, Tang X C, et al. Preparation and fluorescence properties of lithium (borate,phosphate) silicate glasses doped with trivalent cerium[J]. Journal of Functional Materials,2016,47(10):10124(in Chinese). 陈艳平,程浩,唐贤臣,等.Ce3+掺杂锂(硼、磷)硅酸盐玻璃的制备与荧光性质研究[J].功能材料,2016,47(10):10124. 11 Zhou B S. Phase transformation of K2Ca[B4O5(OH)4]2·8H2O in water at boiling point[J]. Journal of Shaanxi Normal University(Natural Science Edition),2004,32(3):69(in Chinese). 周宝石.四硼酸钙钾在沸点温度下水溶液中的相转化研究[J].陕西师范大学学报(自然科学版),2004,32(3):69. 12 Luo J, Pan S L, Han J. Study on growth and properties of K2CaB8O26H24 crystal[J]. Journal of Synthetic Crystals,2011,40(3):548(in Chinese). 罗将,潘世烈,韩健.K2CaB8O26H24晶体的生长及其性质的研究[J].人工晶体学报,2011,40(3):548. 13 Bi Y, Tian Y W, Wang G S, et al. Synthesis and characterization of K2O·CaO·4B2O3·12H2O[J].Journal of Northeastern University(Natural Science),2011,32(3):400(in Chinese). 毕颖,田彦文,王国胜,等.硼氧酸盐(K2O·CaO·4B2O3·12H2O)合成与表征[J].东北大学学报(自然科学版),2011,32(3):400. 14 Bi Y, Tian Y W, Wang G S. Preparation and structure of the noncentrosymmetric hydrated borate K2Ca[B4O5(OH)4]2·8H2O[J].Asian Journal of Chemistry,2013,25(13):7346. 15 Jia Y Z,Gao S Y,Yu K B,et al. Crystal structure,vibrational spectra and mechanism of dissolution of K2CaB8O26H24[J]. Acta Chimica Sinica,2001,59(4):544(in Chinese). 贾永忠,高世扬,郁开北,等.K2CaB8O26H24单晶结构和溶解转化机理[J].化学学报,2001,59(4):544. |
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