RESEARCH PAPER |
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Property of Sr and Co Codoped Multiferroic Material BiFeO3 |
XIONG Jiangong1, ZHANG Chuangwei1, WANG Kang1, KONG Lingyi2,ZHAO Yifei3, CHEN Long3, LI Yongtao1,3
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1 College of Electronic Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023; 2 School of Communication and Information Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023; 3 School of Science, Nanjing University of Posts and Telecommunications, Nanjing 210023 |
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Abstract BiFeO3, Bi0.95Sr0.05FeO3, BiFe0.95Co0.05O3 and Bi0.95Sr0.05Fe0.95Co0.05O3 samples were prepared by sol-gel method and the structure, morphology, element content, ferroelectricity and ferromagnetism of the samples were investigated. The results manifested that the crystal structure of Bi0.95Sr0.05Fe0.95Co0.05O3 had been changed and the ferroelectricity enhanced dramatically, but the leakage current of it was also larger. Simultaneously, it demonstrated that the magnetic properties of Bi0.95Sr0.05FeO3 and BiFe0.95Co0.05O3 were increased more or less. But the magnetic properties of Bi0.95Sr0.05Fe0.95Co0.05O3 was constant with Sr and Co codoped. The reason for this phenomenon were analyzed by comparing oxygen vacancy concentration, the difference between Fe-O covalent bond structures and the different size of the crystals for all the samples.
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Published: 25 May 2018
Online: 2018-07-06
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1 Hans Schmid. Multi-ferroic magnetoelectrics[J]. Ferroelectrics,1994,162(1):317. 2 Ramesh R. Materials science: Emerging routes to multiferroics[J]. Nature,2009,461(7268):1218. 3 Chu Y H, Martin L W, Holcomb M B, et al. Controlling magnetism with multiferroics [J]. Materials Today,2007,10(10):16. 4 Bucci J D, Robertson B K, James W J. The precision determination of the lattice parameters and the coefficients of thermal expansion of BiFeO3 [J]. Journal of Applied Crystallography,1972,5(3):187. 5 Sharma P, Verma V. Structural, magnetic and electrical properties of La and Mn co-substituted BiFeO3 samples prepared by the sol-gel technique [J]. Journal of Magnetism and Magnetic Materials,2015,374:18. 6 Dai H, Li T, Chen Z, et al. Studies on the structural, electrical and magnetic properties of Ce-doped BiFeO3 ceramics [J]. Journal of Alloys and Compounds,2016,672:182. 7 Verma V, Beniwal A, Ohlan A, et al. Structural, magnetic and ferroelectric properties of Pr doped multiferroics bismuth ferrites [J]. Journal of Magnetism and Magnetic Materials,2015,394:385. 8 Dai H, Xue R, Chen Z, et al. Effect of Eu, Ti co-doping on the structural and multiferroic properties of BiFeO3 ceramics [J]. Cera-mics International,2014,40(10):15617. 9 Song G L, Song Y C, Su J, et al. Crystal structure refinement, ferroelectric and ferromagnetic properties of Ho3+ modified BiFeO3 multiferroic [J]. Journal of Alloys and Compounds,2016,389(1):73. 10 Wen X L, Chen Z, Liu E H, et al. Effect of Ba and Mn doping on microstructure and multiferroic properties of BiFeO3 ceramics [J]. Journal of Alloys and Compounds,2016,678:511. 11 Kumar V, Singh S. Improved structure stability, optical and magnetic properties of Ca and Ti co-substituted BiFeO3 nanoparticles [J]. Applied Surface Science,2016,386:78. 12 Ma Y, Tang X, Lu M, et al. Substitution-driven structural and magnetic transformation of Mn- and Co-doped BiFeO3 [J]. Journal of Superconductivity and Novel Magnetism,2015,28(12):3593. 13 Sui Y, Xin C, Zhang X, et al. Enhancement of multiferroic in BiFeO3 by Co doping [J]. Journal of Alloys and Compounds,2015,645:78. 14 Xie Yan, Zhu Yongdan, Hu Cheng, et al. Preparation and properties of Ba and Ti co-doped BiFeO3 multiferroic functional ceramics [J].Journal of Wuhan University,2016,62(4):331(in Chinese). 谢炎,朱永丹,胡诚,等.Ba,Ti双位共掺杂BiFeO3多铁功能陶瓷的制备与性能[J].武汉大学学报,2016,62(4):331. 15 Li Chenyang, Wu Chunfang, Wei Jie, et al. Preparation and multiferroic study of Zr doped BiFeO3 ceramics [J]. Journal of Lanzhou University,2011,47(3):107(in Chinese). 李晨阳,吴春芳,魏杰,等.Zr掺杂BiFeO3陶瓷的制备及其多铁性研究[J].兰州大学学报,2011,47(3):107. 16 Kundu A K, Ranjith R, Kundys B, et al. A multiferroic ceramic with perovskite structure: (La0.5Bi0.5)(Mn0.5Fe0.5)O3.09 [J]. Applied Physics Letters,2008,93(5):803. 17 Villafuerte-Castrejón M E, García-Guaderrama M, Fuentes L. New Fe3+/Cr3+ perovskites with anomalous transport properties: The solid solution LaxBi1-xFe0.5Cr0.5O3 (0.4 ≤ x ≤ 1) [J]. Inorganic Chemistry,2011,50(17):8340. 18 Ruan J H, Yao B M, Tang P, et al. The electrical and enhanced magnetic properties of (Ce, Co) doped BiFeO3 particles synthesized via sol-gel method[J]. Ferroelectrics,2015,489(1):73. 19 Chauhan S, Kumar M, Pal P. Substitution driven structural and magnetic properties and evidence of spin phonon coupling in Sr-doped BiFeO3 nanoparticles[J]. RSC Advances,2016,6(72):64. 20 Islam M R, Galib R H, Sharif A, et al. Correlation of charge defects and morphology with magnetic and electrical properties of Sr and Ta codoped BiFeO3 [J]. Journal of Alloys and Compounds,2016,688:1186. 21 Chen Z, Wu Y, Wang X, et al. Ferromagnetism and enhanced photocatalytic activity in Nd doped BiFeO3 nanopowders [J]. Journal of Materials Science: Materials in Electronics,2015,26(12):9929. 22 Yu X, An X. Enhanced magnetic and optical properties of pure and (Mn, Sr) doped BiFeO3 nanocrystals[J]. Solid State Communications,2009,149(17-18):711. 23 Priyadharsini P, Pradeep A, Sathyamoorthy B, et al. Enhanced multiferroic properties in La and Ce co-doped BiFeO3 nanoparticles [J]. Journal of Physics and Chemistry of Solids,2014,75(7):797. 24 Cazayous M, Malka D, Lebeugle D, et al. Electric field effect on BiFeO3 single crystal investigated by Raman spectroscopy [J]. Applied Physics Letters,2007,91(7):759. 25 Singh M K, Ryu S, Jang H M. Polarized Raman scattering of multiferroic BiFeO3 thin films with pseudo-tetragonal symmetry [J]. Physical Review B,2005,72(13):2101. 26 Hu Z, Chen D, Wang S, et al. Facile synthesis of Sm-doped BiFeO3, nanoparticles for enhanced visible light photocatalytic performance [J]. Materials Science and Engineering B,2017,220:1. 27 Hu W, Chen Y, Yuan H, et al. Structure, magnetic, and ferroelectric properties of Bi1-xGdxFeO3 nanoparticles [J]. Journal of Physical Chemistry C,2011,115(18):8869. 28 Zhang N, Yang Y W, Su J, et al. Role of oxygen vacancies in deciding the high temperature magnetic properties of Ba and Sm substituted BiFeO3 ceramics [J]. Journal of Alloys and Compounds,2016,677:252. 29 Song G, Jian S, Zhang N, et al. Effects of oxygen content on the electric and magnetic properties of BiFeO3 compound [J]. Physica B Condensed Matter,2016,493:47. 30 Mao W, Wang X, Han Y, et al. Effect of Ln (Ln = La, Pr) and Co co-doped on the magnetic and ferroelectric properties of BiFeO3 nanoparticles [J]. Journal of Alloys and Compounds,2014,584(1):520. |
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