纳米Al<sub>2</sub>O<sub>3</sub>/聚醚砜-环氧树脂复合材料的介电性能及热稳定性能

doi:10.11896/j.issn.1005-023X.2017.020.005

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (1414KB)
Export: BibTeX | EndNote (RIS)

Abstract The nano-Al₂O₃/polyether sulfone-epoxy resin (EP/5PES/1Al₂O₃) composites were fabricated and the effects of different nano-Al₂O₃ and PES addition on the mechanical, dielectric and thermal stability properties of composite were also investigated. The results shows that the tensile strength, elongation at break and impact strength of EP/5PES/1Al₂O₃ composite arrive at 58 MPa, 13% and 16.2 kJ/m², respectively, which increase by 61.1%, 20.3% and 8.0% compared to the pure epoxy resin. Additio-nally, the EP/5PES/1Al₂O₃ composite show higher dielectric constant and dielectric loss of 7.6 and 0.016 (100 Hz) compared with the pure epoxy resin. The thermogravimetric analysis (TG) results shows that the thermal stability of EP/5PES/1Al₂O₃ composites has been improved and its initial decomposition temperature is improved to 358 ℃, which is 14 ℃ higher than that of the pure epoxy resin, indicating a great improvement to thermal stability of composites.

Key words： nano-Al₂O₃ polyether sulfone epoxy resin dielectric properties thermal stability

Published: 25 October 2017 Online: 2018-05-05

CLC number:

TB332

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	WU Wei
	CHEN Shiying
	ZONG Mengjingzi

Cite this article:

WU Wei,CHEN Shiying,ZONG Mengjingzi. Dielectric Properties and Thermal Stability of Nano-Al₂O₃/Polyether Sulfone-epoxy Resin Composites[J]. Materials Reports, 2017, 31(20): 21-24.

URL:

https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.020.005 OR https://www.mater-rep.com/EN/Y2017/V31/I20/21

1 Cao Y M, Sun J, Yu D H. Preparation and properties of nano-Al₂O₃, particles/polyester/epoxy resin ternary composites[J]. Appl Polym Sci, 2002,83(1):70.
2 Liu W. Preparation and properties of epoxy composite material of high dielectric constant[D]. Mianyang: Southwest University of Science and Technology, 2014(in Chinese).
刘卫. 高介电常数环氧复合材料的制备及性能研究[D]. 绵阳: 西南科技大学, 2014.
3 Wei H. Research of performance and preparation of graphene/epoxy high dielectric permittivity polymer composites[D]. Changchun: Jilin University, 2014(in Chinese).
魏红. 高介电环氧树脂复合材料的制备及性能研究[D]. 长春: 吉林大学, 2014.
4 Yu J, Huo R, Wu C, et al. Influence of interface structure on dielectric properties of epoxy/alumina nanocomposites[J]. Macromol Res, 2012,20(8):816.
5 李冰, 江雄知, 张晓伟. 纳米Al₂O₃/环氧树脂复合材料的研究进展[C]∥玻璃钢/复合材料学术年会. 广州, 2008:301.
6 Xu D D, Zhu J, Liu Z Y, et al. Thermal stability and insulation strength of nano-Al₂O₃/epoxy resin composites[J]. China Plastics Ind, 2015(4):87(in Chinese).
徐丹丹, 朱婕, 刘子仪, 等. 纳米Al₂O₃/环氧树脂复合材料热稳定性及绝缘强度的研究[J]. 塑料工业, 2015(4):87.
7 蒋德意, 赵江涛, 周权, 等. 聚醚砜增韧改性环氧树脂性能研究[C]∥玻璃钢/复合材料学术交流会.武汉,2014:192.
8 Francis B, Thomas S, Thomas S P, et al. Diglycidyl ether of bisphenol-A epoxy resin-polyether sulfone/polyether sulfone ether ketone blends: Phase morphology, fracture toughness and thermo-mechanical properties[J]. Colloid Polym Sci, 2006,285(1):83.
9 Hou Y N. Study on properties of epoxy resin toughed by polyether sulfone[D]. Mianyang: Southwest University of Science and Technology, 2014(in Chinese).9 侯雅楠. 聚醚砜改性环氧树脂的性能研究[D]. 绵阳: 西南科技大学, 2014.
10Chen Y, Yuan G, Xiao Y, et al. Preparation and study on properties of epoxy resin modified by poly(ether sulfone)[C]∥ Strategic Technology (IFOST), 2011 6th International Forum. Harbin, 2011:126.
11Alessi S, Conduruta D, Pitarresi G, et al. Accelerated ageing due to moisture absorption of thermally cured epoxy resin/polyether sulfone blends. Thermal, mechanical and morphological behavior [J]. Polym Degrad Stab, 2011,96(4):642.
12Yu Q Q,Chen G,Chong L,et al. Mechnical properties of high performance epoxy resin toughed by PES[J]. Eng Plastics Appl, 2012,40(9):22(in Chinese).
于倩倩, 陈刚, 崇琳, 等. PES增韧高性能环氧树脂力学性能研究[J]. 工程塑料应用, 2012,40(9):22.
13Chen Y F, Dai Q W, Teng C J, et al. Microstructure and heat-resistance of sce-Al₂O₃/PES-BMI-BBA-BBE composites[J]. Acta Mater Compos Sin, 2015,32(3):665(in Chinese).
陈宇飞, 代起望, 滕成君, 等. 超临界氧化铝/聚醚砜-BMI-BBA-BBE复合材料的微观结构与耐热性[J]. 复合材料学报, 2015,32(3):665.
14Naganuma Z, Kagawa Z. Effect of particle size on light transmittance of glass particle dispersed epoxy matrix optical composites[J]. Polym Compos, 2001,47(13):4321.
15Neldon J K, Hu Y. The impact of nanocomposite formulations on electrical voltage endurance[C]∥Solid Dielectrics, Proceedings of the 2004 IEEE Internationl Conference. Toulouse, France, 2004:832.
16Bai M Y. Preparation and study on properties of epoxy resin modified by poly(ether-sulfone)/nano-silica[D]. Harbin: Harbin University of Science and Technology(in Chinese).
白孟瑶. 聚醚砜/纳米二氧化硅改性环氧树脂胶黏剂的制备及性能研究[D]. 哈尔滨: 哈尔滨理工大学, 2011.