RESEARCH PAPER |
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Biomimetic Synthesis of Porous ZrC/C Composite Ceramic Materials |
KAN Xiaoqing1, DING Jun1, YU Chao1, DENG Chengji1, ZHU Hongxi1, FAN Guodong2, LENG Guanghui2
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1 The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081; 2 Henan Dongda High Temperature & Energy Saving Material Co., Ltd, Hebi 458030 |
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Abstract Porous ZrC/C composite ceramic materials were prepared in a KCl-KF molten salt reaction medium, using the carbonized platane wood as carbon source and Zr as metal source. Systematically investigations of the C templates on microstructures, apparent porosities and bulk densities in different carbonization temperatures were carried out. The carbonize procedure of platane wood and the phase compositions and morphological structures of the composite materials were characterized by X-ray photoelectron spectroscopy (XPS), fourier transform infrared (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results showed that the carbonization of platane wood included the two processes of organic matter decomposition and graphitization. The porous structure of platane wood was well retained in the resulting C templates. The apparent porosities of C templates increased and the bulk densities decreased with the increase of carbonization temperature. The increase of reaction time can strengthen the bin-ding force of ZrC layer and C template. The amount of KF requires strict control because excess KF can damage the structure of the composite material.
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Published: 25 May 2018
Online: 2018-07-06
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