静电纺羽毛角蛋白/聚乙烯醇/聚氧化乙烯纳米纤维膜的交联改性及表征

doi:10.11896/j.issn.1005-023X.2018.08.003

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Abstract The present work focuses on the fabrication and crosslinking modification of a feather keratin/poly(vinyl alcohol)/poly(ethylene oxide) ternary hybrid nanofibrous membrane. We mixed chicken feathers keratin (FK) (pre-extracted from chicken feathers by oxidation method), poly(vinyl alcohol) (PVA) and poly(ethylene oxide) (PEO) to prepare the spinning solution, and then fabricated the FK/PVA/PEO nanofibrous membrane through a electrospinning process. The glyoxal which acted as a crosslin-king agent was also added into the spinning solution in order to improve product’s performance. The fabricated (crosslinking-modified and unmodified) membranes were characterized by using a scanning electron microscope (SEM), a Fourier transform infrared (FT-IR) spectroscope, an X-ray diffractometer (XRD), a thermogravimetric analyzer (TGA), a water contact angle tester and a universal testing machine. The results indicated an increase of average fiber diameter from (249.76±38.02) nm to (399.67±53.44) nm and a contact angle rise from (42.1±5.1) ° to (84.9±7.1) °, whilst the glyoxal/FK mass ratio was raised from 0% to 8%. The hybrid membranes with 6% glyoxal/FK mass ratio showed pleasurable mechanical properties, as the tensile strength and Young’s modulus reached 4.57 MPa and 6.64 MPa, respectively.

Key words： electrospinning technique feather keratin nanofibrous membrane crosslinking modification

Published: 25 April 2018 Online: 2018-05-11

CLC number:	O636.9
	TB324

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	Articles by authors
	CHEN Man
	HE Ming
	GUO Yanting
	YIN Guoqiang

Cite this article:

CHEN Man,HE Ming,GUO Yanting, et al. Crosslinking Modification and Characterization of the Electrospun Feather Keratin/Poly(vinyl alcohol)/Poly(ethylene oxide) Nanofibrous Membrane[J]. Materials Reports, 2018, 32(8): 1218-1223.

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https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2018.08.003 OR https://www.mater-rep.com/EN/Y2018/V32/I8/1218

1 Li J, Lei T D, Wang Y H, et al. Preparation and characterization of high-content keratin/PEO nanofiber using organic solvent[J].Journal of Donghua University(Natural Science Edition),2016,42(6):793(in Chinese).
李佳,雷通达,王永恒,等.高比例角蛋白/PEO纳米纤维的有机溶剂法制备与性能表征[J].东华大学学报(自然科学版),2016,42(6):793.
2 Song N, Jo W, Song H, et al. Effects of plasticizers and nano-clay content on the physical properties of chicken feather protein compo-site films[J].Food Hydrocolloids,2013,31(2):340.
3 Wang Y, Cao X. Extracting keratin from chicken feathers by using a hydrophobic ionic liquid[J].Process Biochemistry,2012,47(5):896.
4 Cheng Y T,Meng J G,Gou Z.Preparation of wool keratin/PVA regenerated fiber by electrostatic spinning[J].China Textile Leader,2016(6):73(in Chinese).
程燕婷,孟家光,苟喆.静电纺丝法制备羊毛角蛋白/PVA再生纤维[J].纺织导报,2016(6):73.
5 Zoccola M, Montarsolo A, Aluigi A, et al. Electrospinning of polyamide 6/modified-keratin blends[J].e-Polymers,2007,7(1):1204.
6 Na Ayutthaya S I, Wootthikanokkhan J. Extraction of keratin from chicken feather and electrospinning of the keratin/PLA blends[J].Advanced Materials Research,2013,747:711.
7 Zhao X Y,Wang H R.Research progress of keratin materials[J].Research Progress of Keratin Materials,2016,44(2):84(in Chinese).
赵笑宇,王鸿儒.角蛋白材料的研究进展[J].塑料科技,2016,44(2):84.
8 Qian Y F,Mo X M,Ke Q F.Electrospinning nanofibers for tissue engineering scaffolding[J].Chinese Journal of Tissue Engineering Research,2007,11(22):4371(in Chinese).
钱永芳,莫秀梅,柯勤飞.静电纺纳米纤维用于组织工程支架[J].中国组织工程研究,2007,11(22):4371.
9 Wang Y, Li P, Xiang P, et al. Electrospun polyurethane/keratin/AgNP biocomposite mats for biocompatible and antibacterial wound dressings[J].Journal of Materials Chemistry B,2016,4(4):635.
10 Min B, Lee G, Kim S H, et al. Electrospinning of silk fibroin nanofibers and its effect on the adhesion and spreading of normal human keratinocytes and fibroblasts in vitro[J].Biomaterials,2004,25(7):1289.
11 Zhang Y, Ouyang H, Lim C T, et al. Electrospinning of gelatin fibers and gelatin/PCL composite fibrous scaffolds[J].Journal of Biomedical Materials Research Part B Applied Biomaterials,2005,72B(1):156.
12 Zhen H P,Nie J,Sun J F, et al.Electrospun chitosan/poly(vinyl alcohol) blend ultrafine fibers and their ultraviolet photocrosslinking[J].Acta Polymerica Sinica,2007(3):230(in Chinese).
甄洪鹏,聂俊,孙俊峰,等.壳聚糖/聚乙烯醇共混超细纤维的制备及紫外光交联研究[J].高分子学报,2007(3):230.
13 Li S. Fabrication and characterization of electrospun wool keratin/poly(vinyl alcohol) blend nanofibers membrane[D].Suzhou:Soochow University,2014(in Chinese).
李帅.羊毛角蛋白/聚乙烯醇纳米纤维膜的制备与表征[D].苏州:苏州大学,2014.
14 Liu Y, Yu X, Li J, et al. Fabrication and properties of high-content keratin/poly (ethylene oxide) blend nanofibers using two-step cross-linking process[J].Journal of Nanomaterials,2015,11:1.
15 Fan J, Lei T, Li J, et al. High protein content keratin/poly (ethy-lene oxide) nanofibers crosslinked in oxygen atmosphere and its cell culture[J].Materials & Design,2016,104:60.
16 Choi J, Panthi G, Liu Y, et al. Keratin/poly (vinyl alcohol) blended nanofibers with high optical transmittance[J].Polymer,2015,58:146.
17 Rockland L B. Saturated salt solutions for static control of relative humidity between 5°and 40°C[J].Analytical Chemistry,1960,32(10):1375.
18 Wang K.The preparation of regenerated wool keratin polycaprolactone nanofibers and its research in biological properties[D].Shanghai:Donghua University,2016(in Chinese).
王魁.再生羊毛角蛋白-聚己内酯复合纳米纤维的制备及生物性能的研究[D].上海:东华大学,2016.
19 Wang X H.Preparation of polyurethane/keratin nanofibers and their properties[D].Shanghai:Donghua University,2016(in Chinese).
王夏辉.聚氨酯/角蛋白纳米纤维的制备及性能研究[D].上海:东华大学,2016.
20 Chen Y,Guo Y Y,Gao Y, et al.Preparation and characterization of electrospun collagen/PEO composite micro-nanofibers[J].Journal of Donghua University(Natural Science Edition),2014,40(6):739(in Chinese).
陈燕,郭蕴仪,高晶,等.胶原/聚氧化乙烯复合微纳米纤维的静电纺制备及表征[J].东华大学学报(自然科学版),2014,40(6):739.
21 Park M, Shin H K, Panthi G, et al. Novel preparation and characterization of human hair-based nanofibers using electrospinning process[J].International Journal of Biological Macromolecules,2015,76:45.
22 Gao X P,Liu C Y,Zhang Y Q,et al.Influence of glyoxal cross linking on properties of gelatin/PVA biodegradable composite films[J].Journal of Henan University of Science & Technology(Natural Science),2013,27(2):173(in Chinese).
高喜平,刘翠云,张玉清,等.乙二醛交联对明胶/PVA可生物降解复合膜性能的影响[J].材料研究学报,2013,27(2):173.
23 Lu Y,Zhai P Y,Lei T D,et al.Fabrication and properties of high-content keratin/poly(ethylene oxide)blend nanofibers[J].Journal of Tianjin Polyiehn University,2016(6):1(in Chinese).
刘雍,翟培羽,雷通达,等.高角蛋白含量的角蛋白/PEO纳米纤维的制备及其性能表征[J].天津工业大学学报,2016(6):1.
24 Xu X H.Fabrication, modification and characterization of electrospun fibrin-based nanofibers[D].Shanghai:Donghua University,2010(in Chinese).
徐晓红.纤维蛋白基纳米纤维的交联、表征及生物相容性研究[D].上海:东华大学,2010.
25 Chen Q,Lv W J,Zhang W Q, et al.Effect of aldehydes on the properties of the composite chitosan films[J].Journal of East China University of Science and Technology(Natural Science Edition),2005,31(3):398(in Chinese).
陈强,吕伟娇,张文清,等.醛交联剂对壳聚糖复合膜性能的影响[J].华东理工大学学报(自然科学版),2005,31(3):398.