RESEARCH PAPER |
|
|
|
|
|
Surface Modification of Steel Slag and Its Application in Compounded Rubber |
SHEN Haiyang1, WANG Zhengzhou1, 2
|
1 School of Materials Science and Engineering, Tongji University, Shanghai 201804; 2 Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804 |
|
|
Abstract The influence of steel slag on curing characteristics and mechanical properties of a compounded rubber i.e. natural rubber, styrene-butadiene rubber and butadiene rubber was studied. The results show that the addition of steel slag can promote the vulcanization of the compounded rubber by shortened the scorch time (t10) and curing time (t90). Addition of an appropriate amount of steel slag (10 phr) leads to an increase in the tensile strength and elongation at break of the compounded rubber. As the amount of steel slag further increased, the tensile strength and elongation at break of the compounded rubber decreased gradually, whereas the hardness and volume fraction of abrasion of compounded rubber increased. Compared with the compounded rubber without steel slag filled,the t10 and t90 of KH-550 modified steel slag filled compounded rubber decreased; the t10 and t90 of the compounded rubber with Si-69 and CS-105 modified steel slag improved. The tensile strength and the elongation at break of the compounded rubber filled with the modified steel slag increased and the volume fraction of abrasion decreased compared with the compounded rubber filled with the unmodified steel slag. The SEM results elaborate that the compatibility of modified steel slag and compounded rubber is improved.
|
Published: 25 March 2018
Online: 2018-03-25
|
|
|
|
1 Wang Q, Yan P, Wang Q, et al. Hydration properties of basic oxygen furnace steel slag[J].Construction & Building Materials,2010,24(7):1134. 2 Yi H, Xu G, Cheng H, et al. An overview of utilization of steel slag[J].Procedia Environmental Sciences,2012,16(4):791. 3 Yang Y L, Wu J M, Zhang J Q. Research on mix design and pavement performance of SMA-13 asphalt mixture with steel slag[J].Road Machinery & Construction Mechanization,2016(7):36(in Chinese). 杨永利,武建民,张建强.钢渣SMA-13型沥青混合料配合比设计及路用性能研究[J].筑路机械与施工机械化,2016(7):36. 4 Pan S Y, Adhikari R, Chen Y H, et al. Integrated and innovative steel slag utilization for iron reclamation, green material production and CO2, fixation via accelerated carbonation[J].Journal of Cleaner Production,2016,137:617. 5 Yang Q L, Yao Y F, Gao L, et al. Application of the coupling agent on SLAG/GF/PVC composites[J].Journal of Zhejiang Sci-Tech University,2009,26(1):12(in Chinese). 杨琼丽,姚跃飞,高磊,等.偶联剂在SlAG/GF/PVC复合材料中的应用[J].浙江理工大学学报,2009,26(1):12. 6 Guzel G, Deveci H. Properties of polymer composites based on bisphenol a epoxy resins with original/modified steel slag[J].Polymer Composites,http:∥onlinelibrary.wiley.com/doi/10.1002/pc.23962/full. 7 Tong Z, Ma G, Cai X, et al. Characterization and valorization of kanbara reactor desulfurization waste slag of hot metal pretreatment[J].Waste and Biomass Valorization,2016,7(1):1. 8 Wang X M, Wu W B, Wang Y, et al. Study on application of nano-magnesium hydroxide in SBR/NR blend[J].Special Purpose Rubber Products,2008,29(2):20(in Chinese). 王晓明,吴文彪,王雅,等.纳米氢氧化镁在SBR/NR并用胶中的应用研究[J].特种橡胶制品,2008,29(2):20. 9 Bansod N D, Kapgate B P, Das C, et al. Compatibilization of natural rubber/nitrile rubber blends by sol-gel nano-silica generated by in situ method[J].Journal of Sol-Gel Science and Technology,2016,80(2):1. 10 Wang S, Zhang Y, Ren W, et al. Morphology, mechanical and optical properties of transparent BR/clay nanocomposites[J].Polymer Testing,2005,24(6):766. 11 Li Z Q. Study on effect of coupling agent modified CeO2 on reinforcing natural rubber[D].Baotou:Inner Mongolia University of Science and Technology, 2015(in Chinese). 李志强. 偶联剂改性氧化铈补强天然橡胶的研究[D].包头:内蒙古科技大学,2015. 12 Chen J, Xu K, Yang R M, et al. Study on properties of NR reinforced by modified graphite gangue powder[J].China Rubber Industry,2013,60(1):29(in Chinese). 陈静,许逵,杨日敏,等.改性石墨矸石粉补强天然橡胶性能的研究[J].橡胶工业,2013,60(1):29. 13 Ismail H, Othman N, Komethi M. Curing characteristics and mechanical properties of rattan-powder-filled natural rubber composites as a function of filler loading and silane coupling agent[J].Journal of Applied Polymer Science,2012,123(5):2805. 14 Li X X, Yang C Y, Li N, et al. Application of wet modified kaolin and different fillers in SBR[J].Special Purpose Rubber Products,2016(5):33(in Chinese). 李晓晓,杨春影,李楠,等.湿法改性高岭土与不同填料在SBR中的应用[J].特种橡胶制品,2016(5):33. |
|
|
|