RESEARCH PAPER |
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High Frequency Induction Brazing Process of Copper-Steel and Its Effects on Microstructure and Electrical Conductivity of Weld Joint |
SHI Yu, GAO Haiming, LI Guang, LI Xiang
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State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050 |
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Abstract Aiming at solving copper-steel dissimilar metal welding problems which happened in the permanent cathode plate conducting rod production,the high-frequency induction brazing experiments of T2 copper and 316 stainless steel were conducted with Sn-Cu solder and they were tested in different processes. Optical microscope,SEM,EDS and X-ray diffraction were used to analyze the microstructure, phase morphology and elemental species of the joints. Meanwhile,intelligent metal conductor resistivity meter was also used to test conductivity of different samples. The results show that the cross-sections formed by different processes are obviously divided into copper diffusion reaction layer, central weld layer, steel diffusion reaction layer and no serious welding defects appear. The copper diffusion reaction layer presents continuous “zigzag”,which is composed of Cu6Sn5. Central weld layer mainly contains tin,tin oxides and Cu6Sn5. A few Fe1.3Sn are generated in the steel diffusion reaction layer. The conductivity of the samples are inversely proportional to the formation of the Cu3Sn and the welding temperature. The parameters can be used to control the welding quality,the connection strength and conductivity of the copper-steel welding joint.
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Published: 25 March 2018
Online: 2018-03-25
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1 Magnabosco I, Ferro P, Bonollo F,et al. An investigation of fusion zone microstructures in electron beam welding of copper-stainless steel[J].Materials Science and Engineering A,2006,424(1-2):163. 2 Zhou Linl. Research of a new energy-saving technology of electrolytic copper[D].Shanghai:East China University of Science and Technology,2013(in Chinese). 周玲丽. 电解铜节能新工艺的研究[D].上海:华东理工大学,2013. 3 Xue Fangqing. Studies and application of stainless steel cathode in copper electrolytic refining[D].Kunming:Kunming University of Science and Technology,2003(in Chinese). 薛方勤. 铜电解精炼不锈钢阴极材料的研究与应用[D].昆明:昆明理工大学,2003. 4 Mumin Sahin. Joining of stainless steel and copper materials with friction welding[J].Industrial Lubrication and Tribology,2009,616:71. 5 Chen Shuhai,Huang Jihua,Xia Jun,et al. Microstructural characteri-stics of a stainless steel-copper dissimilar joint made by laser welding[J].Metallurgical and Materials Transactions,2013,448:33. 6 Wang Kehong,Xu Yuelan,Kong Jianshou,et al. Copper-steel CO2 welding with steel electrode[J].Welding Journal,1996(4):258(in Chinese). 王克鸿,徐越兰,孔建寿,等.铜-钢接头的钢焊丝熔化极CO2焊[J].焊接学报,1996(4):258. 7 杨卫鹏,李双吉,朱笑睿,等.铜-钢异种金属CMT熔钎焊工艺研究[J].焊接,2015(4):41. 8 Fu Jun. Laser welding for copper-steel joint[D]. Shanghai:Shanghai jiaotong university,2009(in Chinese). 付俊. 铜钢异种材料激光焊接研究[D].上海:上海交通大学,2009. 9 Wang Xiangbin,Zhao Xiaohong,Zhou Shiquan,et al.Welding T2-copper to 10-steel by electron beam[J].Electric Welding Machine,2005,26(1):42(in Chinese). 王向斌,赵晓红,周石泉,等.T2紫铜与10#钢异种金属电子束焊接工艺研究[J].电焊机,2005,26(1):42. 10 Song Yonglun,OliveriaSantos J F. Laser cladding of thin copper layer on stainless steel[J].Welding Journal,1998,19(2):88(in Chinese). 宋永伦,OliveriaSantos J F.不锈钢表面超薄铜层的激光熔覆[J].焊接学报,1998,19(2):88. 11 Shen Jie. Study on friction welding of copper and low carbon steel[J].Welding Technology,1995(4):17(in Chinese). 申捷. 铜与低碳钢摩擦焊特性研究[J].焊接技术,1995(4):17. 12 Gao Lu,Li Zhuoxin,Li Guodong,et al. Research status and development of copper-steel welding[J].Welding & Joining,2006(12):16(in Chinese). 高禄,栗卓新,李国栋,等.铜-钢异种金属焊接的研究现状和进展[J].焊接,2006(12):16. 13 Wang Houqin, Cao Jian, Zhang Lixia, et al. Research status of joi-ning between copper alloy and steel[J].Welding Technology,2009(3):6(in Chinese). 王厚勤,曹健,张丽霞,等.铜合金与钢连接技术研究进展[J].焊接技术,2009(3):6. 14 Nazar K A, Shabestari S G. Effect of mico alloying elements on the interfacial reactions between molten aluminum alloy and tool steel[J]. Journal of Alloys and Compounds,2008,478(1):523. 15 Zhang Riheng. Welding procedure of copper-steel different materials[J].Pressure Vessel Technology,2003(9):24(in Chinese). 张日恒. 铜-钢异种金属材料的焊接工艺[J].压力容器,2003(9):24. 16 Qin Youqiong.Effects of brazing parameters on microstructure and mechanical properties of copper and steel brazed joint[J].Hot Wor-king Technology,2010(19):145(in Chinese). 秦优琼. 钎焊工艺参数对铜-钢钎焊接头组织及性能的影响[J].热加工工艺,2010(19):145. 17 Lin Maoguang. Study on vacuum brazing of austenitic stainless steel and copper[D].Zhenjiang:Jiangsu University Of Science And Technology,2013(in Chinese). 林茂广. 奥氏体不锈钢与纯铜的真空钎焊工艺研究[D].镇江:江苏科技大学,2013. 18 Zhao Xufeng. Temperature field analysis of high-frequency induction brazing and experimental verification[D].Nanjing:Nanjing University of Aeronautics and Astronautics,2007(in Chinese). 赵旭枫. 高频感应钎焊温度场分析与试验研究[D].南京:南京航空航天大学,2007. 19 Littliton J,Lammas J,Jordan M F. Nitrogen porosity in gas shielded arc welding of copper[J].Welding Journal,1974,53(12):561. 20 Kuwana,Takeshi,Kokawa. Effects of nitrogen and titanium on mechanical properties and annealed structure of the copper weld metal by Ar-N2 gas metal Arc welding[J].Quarterly Journal of the Japan Welding Society,1986,4(4):753. 21 Zhao Ning. The liquid structure of Sn-Cu lead-free solders[J].Metallurgica Sinica,2008,44(4):467. |
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