RESEARCH PAPER |
|
|
|
|
|
Study on Middle Temperature Brazing of 5083 Aluminum Alloy After Depositing Zn Coatings Produced by Cold Gas Dynamic Spray |
HE Peilong1, CHENG Fangjie1,2, QI Shumei1, XIAO Bing1, ZHAO Huan1
|
1 School of Materials Science and Engineering, Tianjin University, Tianjin 300072; 2 Tianjin Key Laboratory of Advanced Welding and Joining, Tianjin University, Tianjin 300072 |
|
|
Abstract With Zn and 5wt% CsF-AlF3 eutectic flux mixed powders as raw materials, coatings on 5083 aluminum alloy were prepared by cold gas dynamic spray, then the 5083 aluminum alloy deposited coatings were brazed at 530 ℃.The microstructure and composition of the coatings and brazing joint were characterized by SEM and EDS. The results reveal that the combination between coatings and 5083 aluminum alloy substrate is tight, the CsF-AlF3 eutectic flux particles appear at the interface of Zn particles. Due to the protection of coatings, the Mg element isn′t enriched at the 5083 aluminum alloy outermost surface during brazing and the complex oxide film doesn′t form, the bonding of 5083 aluminum alloy deposited coatings and 1060 aluminum alloy can be realized. The brazing joint has a homogeneous microstructure consisting of aluminum based solid solution (α phase) and zinc based solid solution (β phase), only a little of cavities defects occur.
|
Published: 25 February 2017
Online: 2018-05-02
|
|
|
|
1 Cheng Y Y. Medium-temperature vacuum brazing of heat-treatable strengthening aluminum alloy [J]. Aeronaut Manuf Technol,2010(4):26(in Chinese). 程耀永.可热处理强化铝合金中温真空钎焊技术[J]. 航空制造技术,2010(4):26. 2 Wang Z R, Han L, Xu D R, et al. Research status of soldering of aluminum and its alloys[J]. Modern Welding Technol,2014(9):12(in Chinese). 汪再如, 韩磊, 徐道荣, 等. 铝及其合金软钎焊技术的研究现状[J]. 现代焊接,2014(9):12. 3 Xue S B, Chen W H, Lv X C, et al. Mechanism of brazing flux rea-cting with oxide film of LY12 aluminum alloy [J]. Chin J Nonferrous Met,2004,14(4):543(in Chinese). 薛松柏, 陈文华, 吕晓春,等. LY12铝合金氧化膜与钎剂的反应机制[J]. 中国有色金属学报,2004,14(4):543. 4 Zhu H, Xue S B, Sheng Z. Mechanism of CsF-AlF3 and KF-AlF3 fluxes reacting with oxide films of 6063 aluminum alloy [J]. Trans China Welding Inst,2009,30(9):13(in Chinese). 朱宏,薛松柏,盛重.6063 铝合金氧化膜与CsF-AlF3及KF-AlF3钎剂的反应机制[J]. 焊接学报,2009,30(9):13. 5 Cheng F J, Zhao H W, Wang Y, et al. Evolution of surface oxide film of typical aluminum alloy during medium-temperature brazing process[J]. Transactions of Tianjin University,2014,20(1):54. 6 Xiao B, Wang D P, Cheng F J, et al. Oxide film on 5052 aluminium alloy: Its structure and removal mechanism by activated CsF-AlF3 flux in brazing[J]. Appl Surf Sci,2015,337:208. 7 Panda Emila, Jeurgens Lars, Richter Gunther, et al. The amorphous to crystalline transition of ultrathin (Al,Mg)-oxide films grown by thermal oxidation of AlMg alloys: A high-resolution transmission electron microscopy investigation[J]. J Mater Res,2010,25(5):871. 8 Zhang L, Xue S B, Han Z J, et al. Analysis on high strength Al-Li alloy joints brazed in furnace [J]. Trans China Welding Inst,2006,27(8):71(in Chinese). 张玲, 薛松柏, 韩宗杰, 等. 高强铝锂合金炉中钎焊及接头组织分析[J]. 焊接学报,2006,27(8):71. 9 Lu W J, Fan B Z, Yu W Y, et al. Study of preparation and property of AlF3-KF-CsF-ZnCl2 flux [J]. Welding Technol,2014,43(6):52(in Chinese). 路文江, 范百震, 俞伟元, 等, AlF3-KF-CsF-ZnCl2钎剂的研制及性能研究[J]. 焊接技术,2014,43(6):52. 10 Cheng F J, Yang J X, Zhao H W, et al. Relationship of phase structures and melting characteristics of KF-CsF-AlF3 aluminum flux [J]. Trans China Welding Inst,2013,34(6):5(in Chinese). 程方杰, 杨俊香, 赵海微, 等. 低铯含量KF-CsF-AlF3铝钎剂的物相结构与熔化特性的关系[J]. 焊接学报,2013,34(6):5. 11 Luo W, Wang L T, Wang Q M, et al. A new filler metal with low contents of Cu for high strength aluminum alloy brazed joints[J]. Mater Des,2014,63(21):263. 12 Li Y X, Leng X S, Cheng S, et al. Microstructure design and dissolution behavior between 2024 Al/Sn with the ultrasonic-associated soldering [J]. Mater Des,2012,40:427. 13 Nagaoka Toru, Morisada Yoshiaki, Fukusumi Masao, et al. Selection of soldering temperature for ultrasonic-assisted soldering of 5056 aluminum alloy using Zn-Al system solders[J]. J Mater Process Technol,2011,211(9):1534. 14 Xue S B, Dong J, Lv X C, et al. Brazing technology of LY12Al-alloy at middle temperature[J]. Trans China Welding Inst,2003,24(3):21(in Chinese). 薛松柏, 董健, 吕晓春, 等. LY12铝合金中温钎焊技术[J]. 焊接学报,2003,24(3):21. 15 Lee S W, Yeh J W. Super plasticity of 5083 alloys with Zr and Mn additions produced by reciprocating extrusion[J]. Mater Sci Eng A,2007,460-461:409. 16 Yuan X G, Liu Y X, Wang Y S, et al. Influence of heat treatment on interfacial diffusion of Al alloy cold spraying coating on magne-sium alloy[J]. Trans China Welding Inst,2007,28(11):9(in Chinese). 袁晓光, 刘彦学, 王怡嵩, 等.镁合金表面冷喷涂铝合金的界面扩散行为[J]. 焊接学报,2007,28(11):9. 17 Schmidt T, Gartner F, Assadi H, et al. Development of a genera-lized parameter window for cold spray deposition[J]. Acta Mater,2006,54(3):729. |
|
|
|