| 1ST CONFERENCE ON RESEARCH AND APPLICATION OF ADVANCED CEMENTITIOUS MATERIALS |
|
|
|
|
|
| A State-of-the-art Review on Graphene Oxide Reinforced Cement Based Composites |
| XU Yidong1, ZENG Juqing1, 2, CHEN Wei1, MAO Jianghong1, SHEN Jiansheng1, HU Danye1
|
1 School of CML Engineering &Architecture, Ningbo Institute of Technology, Zhejiang University, Ningbo 315100;
2 School of Architecture and Civil Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003 |
|
|
|
|
Abstract The hydration process of cement is complex, and the formed hydration products have many defects, which lead to the poor mechanical properties and durability of cement based composites. How to control the hydration behavior of cement has become the focus of research. Graphene oxide (GO) is an intermediate product for the graphene preparation by graphite oxidation, which has a large number of active groups and possesses wide application prospect in the field of cement based composites. This paper presents a state-of-the-art report of rheological properties, microstructure, mechanical properties and durability of cement based composites reinforced by graphene oxide. The regulation mechanism of graphene oxide on the hydration and performance of cement-based composites is emphasized. The existing problems in current researches are summarized, and the future research work is proposed.
|
|
Published: 10 December 2017
Online: 2018-05-08
|
|
|
|
|
1 孙伟,缪昌文. 现代混凝土理论与技术[M]. 北京: 科学出版社, 2012.
2 Lv S H, Deng L J, Yang W Q, et al. Fabrication of polycarboxylate/graphene oxide nanosheet composites by copolymerization for reinforcing and toughening cement composites[J]. Cem Concr Compos, 2016, 66:1.
3 Saafi M, Tang L, Fung J, et al. Enhanced properties of graphene/fly ash geopolymeric composite cement[J]. Cem Concr Res, 2015, 67:292.
4 Ranjbar N, Mehrali M, Mehrali M, et al. Graphene nanoplatelet-fly ash based geopolymer composites[J]. Cem Concr Res, 2015, 76:222.
5 Du H, Pang S D. Enhancement of barrier properties of cement mortar with graphene nanoplatelet[J]. Cem Concr Res, 2015, 76:10.
6 Pan Z, He L, Qiu L, et al. Mechanical properties and microstructure of a graphene oxide-cement composite[J]. Cem Concr Compos, 2015, 58:140.
7 Lv S, Zhang J, Zhu L, et al. Preparation of cement composites with ordered microstructures via doping with graphene oxide nanosheets and an investigation of their strength and durability[J]. Materials, 2016, 9(11):924.
8 Lv S, Zhang J, Zhu L, et al. Preparation of regular cement hydration crystals and ordered microstructures by doping GON and an investigation into its compressive and flexural strengths[J]. Crystals, 2017, 7(6):165.
9 Lv S H, Cui Y Y, Sun T, et al. Effects of graphene oxide on fluidity of cement paste and structure and properties of hardened cement paste[J]. J Funct Mater, 2015, 46(4):4051(in Chinese).
吕生华,崔亚亚,孙婷,等. 氧化石墨烯对水泥净浆流动度及水泥石结构和性能的影响[J]. 功能材料, 2015, 46(4):4051.
10 Lv S H, Ding H D, Sun T, et al. Effect of naphthalene superplasticizer/graphene oxide composite on microstructure and mechanical properties of hardened cement paste[J]. J Shaanxi University of Science and Technology (Natural Science Edition), 2014, 32(5):42(in Chinese).
吕生华,丁怀东,孙婷,等. 萘系减水剂/氧化石墨烯复合材料对水泥石微观结构和性能的影响[J]. 陕西科技大学学报(自然科学版), 2014, 32(5):42.
11 Lv S H, Zhang J, Zhu L L, et al. Regulation of graphene oxide on microstructure of cement composites and its impact on compressive and flexural strength[J]. CIESC J, 2017, 68(6):2585(in Chinese).
吕生华,张佳,朱琳琳,等. 氧化石墨烯对水泥基复合材料微观结构的调控作用及对抗压抗折强度的影响[J]. 化工学报, 2017, 68(6):2585.
12 Lv S, Qiu C, Ma Y, et al. Regulation of GO on cement hydration crystals and its toughening effect[J]. Mag Concr Res, 2013, 65(20):1246.
13 Horszczaruk E, Mijowska E, Kalenczuk R J, et al. Nanocomposite of cement/graphene oxide-Impact on hydration kinetics and Young’s modulus[J]. Constr Build Mater, 2015, 78:234.
14 Lv SH, Sun T, Liu JJ, et al. Toughening effect and mechanism of graphene oxide nanosheets on cement matrix composites[J]. Acta Mater Compos Sin, 2014, 31(3):644(in Chinese).
吕生华,孙婷,刘晶晶,等. 氧化石墨烯纳米片层对水泥基复合材料的增韧效果及作用机制[J]. 复合材料学报, 2014, 31(3):644.
15 Mohammed A, Sanjayan J G, Duan W H, et al. Incorporating graphene oxide in cement composites:A study of transport properties[J]. Constr Build Mater, 2015, 84:341.
16 Gao D G, Ma Y J. Preparation and properties of copolymer of graphene oxide and monomers of polycarboxylate superplasticizer[J]. Fine Chem, 2015, 32(1):103(in Chinese).
高党国,马宇娟. 氧化石墨烯与聚羧酸减水剂单体共聚物的制备与性能[J]. 精细化工, 2015, 32(1):103.
17 Shang Y, Zhang D, Yang C, et al. Effect of graphene oxide on the rheological properties of cement pastes[J]. Constr Build Mater, 2015, 96:20.
18 Li X, Wei W, Qin H, et al. Co-effects of graphene oxide sheets and single wall carbon nanotubes on mechanical properties of cement[J]. J Phys Chem Solids, 2015, 85:39.
19 Chen J, Zhao D, Ge H, et al. Graphene oxide-deposited carbon fiber/cement composites for electromagnetic interference shielding application[J]. Constr Building Mater, 2015, 84:66.
20 Wang M, Yao H, Wang R, et al. Chemically functionalized graphene oxide as the additive for cement-matrix composite with enhanced fluidity and toughness[J]. Constr Build Mater, 2017, 150:150.
21 Lv S H, Ma Y J, Qiu C C, et al. Study on reinforcing and toughening of graphene oxide to cement-based composites[J]. J Funct Mater, 2013, 44(15):2227(in Chinese).
吕生华,马宇娟,邱超超,等. 氧化石墨烯增强增韧水泥基复合材料的研究[J]. 功能材料, 2013, 44(15):2227.
22 Wang Q, Wang J, Lu C, et al. Influence of graphene oxide additions on the microstructure and mechanical strength of cement[J]. New Carbon Mater, 2015, 30(4):349.
23 Mokhtar M M, Abo-El-Enein S A, Hassaan M Y, et al. Mechanical performance, pore structure and micro-structural characteristics of graphene oxide nano platelets reinforced cement[J]. Constr Build Mater, 2017, 138:333.
24 Lv S, Liu J, Sun T, et al. Effect of GO nanosheets on shapes of cement hydration crystals and their formation process[J]. Constr Build Mater, 2014, 64:231.
25 Cui H, Yan X, Tang L, et al. Possible pitfall in sample preparation for SEM analysis—A discussion of the paper “Fabrication of polycarboxylate/graphene oxide nanosheet composites by copolymerization for reinforcing and toughening cement composites” by Lv et al[J]. Cem Concr Composi 2017, 77:81.
26 Tong T, Fan Z, Liu Q, et al. Investigation of the effects of graphene on the micro-and macro-properties of cementitious materials[J]. Constr Build Mater, 2016, 106:102.
27 Gong K, Pan Z, Korayem A H, et al. Reinforcing effects of graphene oxide on portland cement paste[J]. J Mater Civil Eng,2015,27(2):A4014010.
28 Yang Y L, Yuan X Y, Shen X, et al. Research on the corrosion resistance of graphene oxide on cement mortar[J]. J Funct Mater, 2017, 48(5):5144(in Chinese).
杨雅玲,袁小亚,沈旭,等. 氧化石墨烯改性水泥砂浆耐腐蚀性能的研究[J]. 功能材料, 2017, 48(5):5144.
29 Lu Z, Li X, Hanif A, et al. Early-age interaction mechanism between the graphene oxide and cement hydrates[J]. Constr Build Mater, 2017, 152:232. |
|
|
|
渝公网安备50019002502923号 © Editorial Office of Materials Reports.
2017, Vol. 31 
