溶胶-凝胶法制备铜锌锡硫薄膜及其太阳能电池的研究进展<sup>*</sup>

doi:10.11896/j.issn.1005-023X.2017.017.021

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (1609KB)
Export: BibTeX | EndNote (RIS)

Abstract The combination of low-cost and abundant Cu₂ZnSnS₄ (CZTS) material and a low-cost non-vacuum and green sol-gel technique attracts researcher’s attention for application in industrialized fabrication of higher performance-price ratio CZTS solar cells. In order to know its future research direction, the development of sol-gel fabrication of CZTS thin films and solar cells has been reviewed. Effects of different preparation conditions such as sol-gel routes, solvents and sulfuration on CZTS thin films and devices are discussed. The effect of Na-doping and sulfuration-annealing on CZTS films are also analyzed. The development trend about green fabrication of CZTS films and devices is discussed.

Key words： CZTS sol-gel method thin-film solar cells green process

Published: 10 September 2017 Online: 2018-05-07

CLC number:

TB43

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	GAO Jinfeng
	LI Minghui
	XU Jian
	FANG Gang

Cite this article:

GAO Jinfeng,LI Minghui,XU Jian, et al. Development of Sol-Gel Fabrication of Cu₂ZnSnS₄ Thin-films and Solar Cells[J]. Materials Reports, 2017, 31(17): 146-151.

URL:

https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.017.021 OR https://www.mater-rep.com/EN/Y2017/V31/I17/146

1 Sen S K. How modeling can attract experimentalists to improve solar cell′s efficiency: Divide-and-conquer approach [J]. Nonlinear Anal,2009,71:196.
2 Ito K, Nakazawa T. Electrical and optical properties of stannite-type quaternary semiconductor thin films [J]. Jpn J Appl Phys,1988,27(11):2094.
3 Tanaka T, Nagatomo T, et al. Preparation of Cu₂ZnSnS₄ thin films by hybrid sputtering [J]. J Phys Chem Solids,2005,66(11):1978.
4 Katagiri H, Saito K, Washio T, et al. Development of thin film solar cell based on Cu₂ZnSnS₄ thin films [J]. Sol Energy Mater Sol Cells,2001,65:141.
5 Vanalakar S A, Shin S W, Agawane G L, et al. Effect of post-annealing atmosphere on the grain-size and surface morphological pro-perties of pulsed laser deposited CZTS thin films [J]. Ceram Int,2014,40(9):15097.
6 Sheng X, Wang L, Tian Y, et al. Low-cost fabrication of Cu₂ZnSnS₄ thin films for solar cell absorber layers [J]. J Mater Sci: Mater Electron,2013,24(2):548.
7 Miyamoto Y, Tanaka K, Oonuki M, et al. Optical properties of Cu₂ZnSnS₄ thin films prepared by sol-gel and sulfurization method [J]. Jpn J Appl Phys,2008,47(1):596.
8 Guo Q, Ford G M, Yang W C, et al. Fabrication of 7.2% efficient CZTSSe solar cells using CZTS nanocrystals [J]. J Am Chem Soc,2010,132(49):17384.
9 Todorov T K, Tang J, Bag S, et al. Beyond 11% efficiency: Cha-racteristics of state-of-the-art Cu₂ZnSn(S,Se)₄ solar cells[J]. Adv Energy Mater,2013,3(1):34.
10 Lu X, et al. Wurtzite Cu₂ZnSnS₄ nanocrystals: A novel quaternary semiconductor [J]. Chem Commun,2011,47(11):3141.
11 Almeida R M, et al. Sol-gel processing of sulfide materials [M]∥Klein L, Aparicio M, Jitianu A. Handbook of Sol-Gel Science and Technology,Springer International Publishing,2016.
12 Zhang K. Preparation of Cu₂ZnSnS₄ thin films using sol-gel method and the study of their properties [D]. Xiangtan: Xiangtan University,2013(in Chinese).
张克栋. Cu₂ZnSnS₄薄膜的溶胶-凝胶制备及其性能研究[D]. 湘潭:湘潭大学,2013.
13 Su Z. Fabrication of Cu₂ZnSnS₄ thin film solar cells via sol-gel route [D]. Changsha: Central South University,2013(in Chinese).
苏正华. 溶胶-凝胶法制备铜锌锡硫(Cu₂ZnSnS₄)膜太阳能电池[D]. 长沙:中南大学, 2013.
14 Schnabel T, Loew M, Ahlswede E. Vacuum-free preparation of 7.5% efficient Cu₂ZnSn(S,Se)₄solar cells based on metal salt precursors [J]. Sol Energy Mater Sol Cells,2013,117(14):324.
15 Ki W, Hillhouse H W, Ki W, et al. Earth-abundant element photovoltaics directly from soluble precursors with high yield using a non-toxic solvent [J]. Adv Energy Mater,2011, 1(5):732.
16 Tanaka K, Moritake N, Uchiki H. Preparation of Cu₂ZnSnS₄ thin films by sulfurizing sol-gel deposited precursors [J]. Sol Energy Mater Sol Cells,2007,91(13):1199.
17 Tanaka K, Oonuki M, Moritake N, et al. Cu₂ZnSnS₄ thin film solar cells prepared by non-vacuum processing[J]. Sol Energy Mater Sol Cells,2009,93:583.
18 Tanaka K, Fukui Y, Moritake N, et al. Chemical composition dependence of morphological and optical properties of Cu₂ZnSnS₄ thin films deposited by sol-gel sulfurization and Cu₂ZnSnS₄ thin film solar cell efficiency[J]. Sol Energy Mater Sol Cells,2011,95(3):838.
19 Maeda K, Tanaka K, Nakano Y, et al. Annealing temperature dependence of properties of Cu₂ZnSnS₄ thin films prepared by sol-gel sulfurization method[J]. Jpn J Appl Phys,2011,50(5):521.
20 Maeda K, Tanaka K, Fukui Y, et al. Influence of H₂S concentration on the properties of Cu₂ZnSnS₄ thin films and solar cells prepared by sol-gel sulfurization [J]. Sol Energy Mater Sol Cells,2011,95:2855.
21 Meng M. Research of Cu₂ZnSnSe₄ thin film solar cell [D]. Hefei: Hefei University of Technology, 2013 (in Chinese).
孟明明. 铜锌锡硒薄膜太阳能电池研究[D]. 合肥: 合肥工业大学,2013..
22 Romanyuk Y E, Fella C M, Uhl A R, et al. Recent trends in direct solution coating of kesterite absorber layers in solar cells [J]. Sol Energy Mater Sol Cells, 2013, 119(8): 181.
23 Park H, Hwang Y H, Bae B S. Sol-gel processed Cu₂ZnSnS₄ thin films for a photovoltaic absorber layer without sulfurization [J]. J Sol-Gel Sci Technol,2013,65(1):23.
24 Kanuru C S, Shekar G L, Krishnamurthy L, et al. Surface morphological studies of solar absorber layer Cu₂ZnSnS₄ (CZTS) thin films by non-vacuum deposition methods [J]. J Nano-Electron Phys,2014,6(2):02004.
25 Guo B L, Chen Y H, Liu X J, et al. Optical and electrical properties study of sol-gel derived Cu₂ZnSnS₄ thin films for solar cells [J]. AIP Adv,2014,4(9):802.
26 Corporation H P. Synthesis and characterization of CZTS thin films by sol-gel method without sulfurization [J]. Int J Photoenergy,2014,40(12):976.
27 Tian Q, Cui Y, et al. A robust and low-cost strategy to prepare Cu₂ZnSnS₄ precursor solution and its application in Cu₂ZnSn(S,Se)₄ solar cells[J]. RSC Adv,2015,5:4184.
28 Chaudhuri T K, Tiwari D. Earth-abundant non-toxic Cu₂ZnSnS₄ thin films by direct liquid coating from metal-thiourea precursor solution [J]. Sol Energy Mater Sol Cells,2012,101(6): 46.
29 Rajesh G, Muthukumarasamy N, Subramaniam E P, et al. Synthesis of Cu₂ZnSnS₄ thin films by dip-coating method without sulphurization [J]. J Sol-Gel Sci Technol,2013,66(2):288.
30 Liu C. CZTS thin-film solar cells prepared by the sol-gel spin-coating method [D]. Zhengzhou: Zhengzhou University,2014 (in Chinese).
刘超. 用溶胶-凝胶旋涂法制备CZTS薄膜太阳能电池[D]. 郑州:郑州大学,2014.
31 Seo D, Kim C, Oh E, et al. Control of metal salt ratio and MoS₂ layer thickness in a Cu₂ZnSnS₄ thin film solar cell [J]. J Mater Sci: Mater Electron,2014,25(8):3420.
32 Tunuguntla V, Chen W C, Shih P, et al. A nontoxic solvent based sol-gel Cu₂ZnSnS₄ thin film for high efficiency and scalable low-cost photovoltaic cells [J]. J Mater Chem A, 2015, 3(29): 15324.
33 Kurokawa M, Tanaka K, Moriya K, et al. Fabrication of three-dimensional-structure solar cell with Cu₂ZnSnS₄[J]. Jpn J Appl Phys,2012,51(10):1753.
34 Fischereder A, Rath T, Haas W, et al. Investigation of Cu₂ZnSnS₄ formation from metal salts and thioacetamide [J]. Chem Mater,2010,22(11):3399.
35 Edler M, Rath T, Schenk A, et al. Copper zinc tin sulfide layers prepared from solution processable metal dithiocarbamate precursors [J]. Mater Chem Phys,2012,136:582.
36 Zhang H, Li Z Q, Chen Y R, et al. Growth of Cu₂ZnSn(S,Se)₄ thin films by a simple eco-friendly solution route method [J]. Surf Rev Lett,2012,19(4):1250034.
37 Vanalakar S A, Yeo S J, Patil P S, et al. Structural, optical, surface morphological and electrical properties of Cu₂ZnSnS₄ thin film synthesized by drop casting technique [J]. Zeitschrift für Phy-sikalische Chemie,2014,228(9):917.
38 Tian Q, Huang L, Zhao W, et al. Metal sulfide precursor aqueous solutions for fabrication of Cu₂ZnSn(S,Se)₄ thin film solar cells [J]. Green Chem,2014, 7:1269.
39 Min Y Y, Lee C C, Dong S W. Influences of synthesizing temperatures on the properties of Cu₂ZnSnS₄ prepared by sol-gel spin-coated deposition [J]. J Sol-Gel Sci Technol,2009,52(1): 65.
40 Wang D, Sun Y, Meng X, et al. Preparation and characterization of Cu₂ZnSnS₄ films by sol-gel method [J]. Jilin Normal University Journal:Nat Sci Ed, 2013, 34(1): 29 (in Chinese).
王多, 孙亚明, 孟祥成,等. 溶胶-凝胶法制备Cu₂ZnSnS₄薄膜及其表征[J]. 吉林师范大学学报:自然科学版,2013,34(1):29.
41 Gao J,Xu J,et al. Sol-gel derived Cu₂ZnSnS₄ films and thin-film solar cells [J]. J Chin Ceram Soc,2015,43(12):1765(in Chinese).
高金凤,徐键,等. 溶胶-凝胶法制备Cu₂ZnSnS₄薄膜及其太阳能电池器件[J]. 硅酸盐学报2015,43(12):1765.
42 Jiang M, Li Y, Dhakal R, et al. Cu₂ZnSnS₄ polycrystalline thin films with large densely packed grains prepared by sol-gel method [J]. J Photon Energy,2011,1(35):232.
43 Jiang M, Dhakal R, Li Y, et al. Cu₂ZnSnS₄ (CZTS) polycrystalline thin films prepared by sol-gel method [C]∥IEEE Photovoltaic Spe-cialists Conference.Seattle,WA,USA,2011.001283.
44 Xie M, Zhuang D, Li B, et al. Influence of sulfurization time on phase structures of Cu₂ZnSnS₄ thin films[J].Chin J Vacuum Sci Technol,2014,34(4):391(in Chinese).
谢敏,庄大明,李博建, 等. 硫化时间对铜锌锡硫薄膜特性的影响[J]. 真空科学与技术学报,2014,34(4):391.
45 Sun Y, Zhang Y, Wang H, et al. Novel non-hydrazine solution processing of earth-abundant Cu₂ZnSn(S,Se)₄ absorbers for thin-film solar cells [J]. J Mater Chem A,2013,1(23):6880.
46 Chung C, Rhee, Yoo D J, et al. Properties of kesterite Cu₂ZnSnS₄ (CZTS) thin films prepared by sol-gel method using two types of solution [J]. J Ceram Process Res,2013,14:255.
47 Maeda K, Tanaka K, Fukui Y, et al. Dependence on annealing temperature of properties of Cu₂ZnSnS₄ thin films prepared by sol-gel sulfurization method [J]. Jpn J Appl Phys, 2011,50(S2):317.
48 Ilari G M, Fella C M, Ziegler C, et al. Cu₂ZnSnSe₄ Solar cell absorbers spin-coated from amine-containing ether solutions [J]. Sol Energy Mater Sol Cells,2012,104:125.
49 Hong T K, Donghwan K, Chinho P. Temperature effects on Cu₂ZnSnS₄ (CZTS) films deposited by spraying method [J]. Mol Cryst Liq Cryst,2012,564(1):155.
50 黄剑锋. 溶胶-凝胶原理与技术[M]. 北京:化学工业出版社,2005.
51 Kaelin M, Rudmann D, Kurdesau F, et al. Low-cost CIGS solar cells by paste coating and selenization [J]. Thin Solid Films,2005,480-481:486.
52 Wei S H, Zhang S B, Zunger A. Effects of Na on the electrical and structural properties of CuInSe₂[J]. J Appl Phys,1999,85:7214.
53 Kronik L, Cahen D, Schock H W. Effects of sodium on polycrystalline Cu(In,Ga)Se₂ and its solar cell performance [J]. Adv Mater,1998,10:31.
54 Liu H, Xue Y, Qiao Z. Progress of application research on Cu₂ZnSnS₄thin film and its devices [J]. Acta Phys Sin,2015,64(6):068801 (in Chinese).
刘浩, 薛玉明, 乔在祥,等. 铜锌锡硫薄膜材料及其器件应用研究进展[J]. 物理学报, 2015,64(6):068801.
55 Tejas P, Nagaraju J. Effect of sodium diffusion on the structural and electrical properties of Cu₂ZnSnS₄ thin films [J]. Sol Energy Mater Sol Cells,2011,95(3):1001.
56 Li, J V, Kuciauskas D, Young M R, et al. Effects of sodium incorporation in co-evaporated Cu₂ZnSnSe₄ thin-film solar cells [J]. Appl Phys Lett,2013,102(16):163905.
57 Su Z, Sun K, Han Z, et al. Fabrication of Cu₂ZnSnS₄ solar cells with 5.1% efficiency via thermal decomposition and reaction using a non-toxic sol-gel route [J]. J Mater Chem A, 2013,2(2):500.
58 Katagiri H. Cu₂ZnSnS₄ thin film solar cells [J]. Thin Solid Films,2005,480:426.
59 Su Z, Sun K, Han Z, et al. Fabrication of ternary Cu-Sn-S sulfides by a modified successive ionic layer adsorption and reaction (SILAR) method [J]. J Mater Chem,2012,22:16346.