液相剥离法制备石墨烯的新进展<sup>*</sup>

doi:10.11896/j.issn.1005-023X.2017.017.006

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Abstract Graphene is a two-dimensional material with unique structure and excellent properties. Since it was successfully prepared for the first time in 2004, graphene has become a hot point of many fields such as materials, chemistry, physics and engineering. Presently, several preparation methods of graphene have been reported, including chemical oxidation-reduction, chemical vapor deposition(CVD) and liquid-phase exfoliation(LPE), etc. Among them, LPE is an important way to realize industrialization. This review article mainly summarizes the recent researches about the LPE with ultrasonic. The effect of ultrasonic is simply explained and the LPE through pure solvents or binary solvents, and the LPE with additives are summarized. Furthermore, the mechanisms of different ways are discussed. Finally, several methods to improve the exfoliation efficiency are proposed and the way of choosing new solvents or additives is pointed out, aiming at providing references for developing more effective exfoliation systems or new methods to prepare high quality graphene more effectively.

Key words： graphene liquid-phase exfoliation preparation

Published: 10 September 2017 Online: 2018-05-07

CLC number:

TQ127.1

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	QI Shuai
	HUANG Guoqiang

Cite this article:

QI Shuai,HUANG Guoqiang. Progress of Graphene Preparation by Liquid-phase Exfoliation[J]. Materials Reports, 2017, 31(17): 34-40.

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https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.017.006 OR https://www.mater-rep.com/EN/Y2017/V31/I17/34

1 Novoselov K S, Geim A K, Morozov S V, et al. Electric field effect in atomically thin carbon films[J]. Science, 2004,306(5696):666.
2 Han Ping, Li Xiaoru, Gu Zheng, et al. Progress of synthesis graphene[J]. J Bohai University: Nat Sci Ed, 2014,35(3):294(in Chinese).
韩萍, 李晓茹, 谷正,等. 石墨烯的制备研究进展[J]. 渤海大学学报:自然科学版,2014,35(3):294.
3 He Dafamg, Wu Jian, Liu Zhanjian, et al. Recent advances in pre-paration of graphene for applications[J]. J Chem Ind Eng (China),2015,66(8):2888(in Chinese).
何大方, 吴健, 刘战剑,等. 面向应用的石墨烯制备研究进展[J]. 化工学报,2015,66(8):2888.
4 Bolotin K I, Sikes K J, Jiang Z, et al. Ultrahigh electron mobility in suspended graphene[J]. Solid State Commun,2008,146(9-10):351.
5 Balandin A A, Ghosh S, Bao W, et al. Superior thermal conductivity of single-layer graphene[J]. Nano Lett, 2008,8(3):902.
6 Lee C, Wei X, Kysar J W, et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene[J]. Science,2008,321(5887):385.
7 Chae H K, Siberio-Pérez D Y, Kim J, et al. A route to high surface area, porosity and inclusion of large molecules in crystals[J]. Nature,2004,427(6974):523.
8 Stoller M D, Park S, Zhu Y, et al. Graphene-based ultracapacitors[J]. Nano Lett,2008,8(10):3498.
9 Eda G, Chhowalla M. Graphene-based composite thin films for electronics[J]. Nano Lett,2009,9(2):814.
10 Parvez K, Yang S, Feng X, et al. Exfoliation of graphene via wet chemical routes[J]. Synth Metals,2015,210:123.
11 Alaferdov A V, Gholamipour-Shirazi A, Canesqui M A, et al. Size-controlled synthesis of graphite nanoflakes and multi-layer graphene by liquid phase exfoliation of natural graphite[J]. Carbon,2014,69(2):525.
12 Hernandez Y, Nicolosi V, Lotya M, et al. High yield production of graphene by liquid phase exfoliation of graphite[J]. Nat Nanotech-nol,2008,3(9):563.
13 Gayathri S, Jayabal P, Kottaisamy M, et al. Synthesis of few layer graphene by direct exfoliation of graphite and a Raman spectroscopic study[J]. AIP Adv,2014,4(2):1296.
14 Sun Z, Huang X, Liu F, et al. Amine-based solvents for exfoliating graphite to graphene outperform the dispersing capacity of N-methyl-pyrrolidone and surfactants[J]. Chem Commun,2014,50(72):10382.
15 Wang X, Fulvio P F, Baker G A, et al. Direct exfoliation of natural graphite into micrometre size few layers graphene sheets using ionic liquids[J]. Chem Commun, 2010,46(25):4487.
16 Matsumoto M, Saito Y, Park C, et al. Ultrahigh-throughput exfo-liation of graphite into pristine ‘single-layer’ graphene using microwaves and molecularly engineered ionic liquids[J]. Nat Chem,2015, 7(9):730.
17 Raccichini R, Balducci A, Varzi A, et al. Method of producing graphene by exfoliation of graphite: WO,2015131933[P]. 2015-09-11.
18 Hossain M M, Park O K, Hahn J R, et al. High yield and high concentration few-layer graphene sheets using solvent exfoliation of graphite with pre-thermal treatment in a sealed bath[J]. Mater Lett,2014,123(123):90.
19 Liu W, Tanna V A, Yavitt B M, et al. Fast production of high-qua-lity graphene via sequential liquid exfoliation[J]. ACS Appl Mater Interfaces,2015,7(49):27027.
20 Hernandez Y, Lotya M, Rickard D, et al. Measurement of multicomponent solubility parameters for graphene facilitates solvent discovery[J]. Langmuir,2010,26(5):3208.
21 Chia J S Y, Tan M T T, et al. A novel one step synthesis of graphene via sonochemical-assisted solvent exfoliation approach for electrochemical sensing application[J]. Chem Eng J,2014,249:270.
22 Dang D K, Kim E J. Solvothermal-assisted liquid-phase exfoliation of graphite in a mixed solvent of toluene and oleylamine[J]. Nanoscale Res Lett,2015,10(1):1.
23 Chen J, Shi W, Fang D, et al. A binary solvent system for improved liquid phase exfoliation of pristine graphene materials[J]. Carbon,2015,94:405.
24 Xu M, Zhang W, Yang Z, et al. One-pot liquid-phase exfoliation from graphite to graphene with carbon quantum dots[J]. Nanoscale,2015,7(23):10527.
25 Jagiello J, Judek J, Zdrojek M, et al. Production of graphene composite by direct graphite exfoliation with chitosan[J]. Mater Chem Phys,2014,148(3):507.
26 Niazi M B K. Effect of concentration of surfactant on the exfoliation of graphite to graphene in aqueous media[J]. Nanomater Nanotech-nol,2016,6(14):1.
27 Unalan I U, Wan C, Trabattoni S, et al. Polysaccharide-assisted rapid exfoliation of graphite platelets into high quality water-disper-sible graphene sheets[J]. RSC Adv,2015,5(34):26482.
28 Lotya M, Hernandez Y, King P J, et al. Liquid phase production of graphene by exfoliation of graphite in surfactant/water solutions[J]. J Am Chem Soc,2009, 131(10):3611.
29 Liu W, Zhou R, Zhou D, et al. Lignin-assisted direct exfoliation of graphite to graphene in aqueous media and its application in polymer composites[J]. Carbon,2015, 83:188.
30 Zhang L, Zhang Z, He C, et al. Rationally designed surfactants for few-layered graphene exfoliation: Ionic groups attached to electron-deficient π-conjugated unit through alkyl spacers[J]. ACS Nano,2014,8(7):6663.
31 Ager D, Vasantha V A, Crombez R, et al. Aqueous graphene dispersions-optical properties and stimuli-responsive phase transfer[J]. ACS Nano,2014, 8(11):11191.
32 Tung T T, Yoo J, Alotaibi F K, et al. Graphene oxide-assisted li-quid phase exfoliation of graphite into graphene for highly conductive film and electromechanical sensors[J]. ACS Appl Mater Interfaces,2016,8(25):16521.
33 Naboka O, Yim C H, Abu-Lebdeh Y. Graphene/Na carboxymethyl cellulose composite for Li-ion batteries prepared by enhanced liquid exfoliation[J]. Mater Sci Eng B,2016,213:41.
34 Shinde D B, Brenker J, Easton C D, et al. Shear assisted electrochemical exfoliation of graphite to graphene[J]. Langmuir,2016,32(14):3552.
35 Cui J, Song Z, Xin L, et al. Exfoliation of graphite to few-layer graphene in aqueous media with vinylimidazole-based polymer as high-performance stabilizer[J]. Carbon,2016,99:249.
36 Ciesielski A, Haar S, Gemayel M, et al. Harnessing the liquid-phase exfoliation of graphene using aliphatic compounds: A supramolecular approach[J]. Angew Chem-Int Ed,2014,53(39):10355.
37 Zhang R, Zhang B, Sun S. Preparation of high-quality graphene with a large-size by sonication-free liquid-phase exfoliation of gra-phite with a new mechanism[J]. RSC Adv,2015,5(56):44783.
38 Hui S. A supramolecular strategy to leverage the liquid-phase exfo-liation of graphene in the presence of surfactants: Unraveling the role of the length of fatty acids[J]. Small,2015,11(14):1691.
39 Sebastien H, Matteo B, Jian X, et al. Liquid-phase exfoliation of graphite into single and few layers graphene with α-functionalized alkanes[J]. J Phys Chem Lett,2016,7(14):2714.
40 Usca G T, Hernandez-Ambato J, Pace C, et al. Liquid-phase exfo-liated graphene self-assembled films: Low-frequency noise and thermal-electric characterization[J]. Appl Surf Sci,2016,380:268.
41 Mutyala S, Mathiyarasu J. Preparation of graphene nanoflakes and its application for detection of hydrazine[J]. Sens Actuat B: Chem,2015,210:692.
42 Chen J, Shi W, Chen Y, et al. Eco-friendly exfoliation of graphite into pristine graphene with little defect by a facile physical treatment[J]. Appl Phy Lett,2016,108(7):31051.