ENVIRONMENTAL REMEDIATION MATERIAL |
|
|
|
|
|
Removal of Carbonyl Sulfide by DC Corona Discharge and Analysis of the Product |
WANG Xueqian, CHENG Chen, MA Yixing, NING Ping, XU Ke, WANG Langlang, ZHANG Yinjie
|
Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650093 |
|
|
Abstract The effects of different concentration of O2, different relative humidity and whether if the existence of dust on the concentration of the main product and removal efficiency of carbonyl sulfide (COS) were investigated through direct current corona discharge. The experiment results show that the removal efficiency of carbonyl sulfide (COS) and the production date of sulfur dio-xide (SO2),TS′ were lower with the increase of oxygen(O2); COS inversion quantity was equal to the gross which CO and CO2. The concentration of CO and CO2 were decreased, the production rate of CO was decreased and CO2 was increased. Relative humidity has affected the removal efficiency of COS less,but it has impact on breakdown voltage. With the increase of relative humidity, SO2 formation rate was decreased and TS′ formation rate was increased. The concentration of CO let up and CO2 was increased. The production rate of CO was decreased and CO2 was increased. After add dust in the experiment process, the removal efficiency of COS was increased in some extent, the production rate of SO2 significantly was decreased and TS′ formation rate was in addition. The concentration of CO was decreased and CO2 was increased. The production rate of CO was decreased and CO2 was increased. The remaval efficiency of COS was the best in the condition of low oxygen, low humidity and the exist of dust.
|
Published: 10 January 2017
Online: 2018-05-02
|
|
|
|
1 Whelan M E, Min D H, Rhew R C. Salt marsh vegetation as a carbonyl sulfide (COS) source to the atmosphere [J]. Atmospheric Environ,2013,73(6):131. 2 Mondal S, Teja A U, Singh P C. Effect of microhydration on the atmospherically important metastable carbonyl sulfide anion: Structure, energetic, and infrared study [J]. Int J Quantum Chem,2015,115(12):785. 3 Liu J F, Liu Y C, Xue L, et al. Oxygen poisoning mechanism of ca-talytic hydrolysis of OCS over Al2O3 at room temperature[J]. Acta Physico-Chimica Sinica,2007,23(7):997. 4 Li K, Song X, Ning P, et al. Energy utilization of yellow phospho-rus tail gas: Simultaneous catalytic hydrolysis of carbonyl sulfide and carbon disulfide at low temperature [J]. Energy Technol,2014,3(2):136. 5 Zhao S Z, Yi H H, Tang X L, et al. Low temperature hydrolysis of carbonyl sulfide using Zn-Al hydrotalcite-derived catalysts[J]. Chem Eng J,2013,226(12):161. 6 Sun X, Ning P, Tang X L, et al. Simultaneous catalytic hydrolysis of carbonyl sulfide and carbon disulfide over Al2O3-K/CAC catalyst at low temperature[J]. J Energy Chem,2014,23(2):221. 7 Svoronos P D N,Bruno T J.Carbonyl sulfide:A review of its chemistry and properties[J].Ind Eng Chem Res,2002,41(22):5321. 8 Rhodes C,Riddel S A,West J, et al. The low-temperature hydrolysis of carbonyl sulfide and carbon disulfide:A review[J].Catal Today,2000,59(3-4):443. 9 Wang H Y, Yi H H, Tang X L, et al. Catalytic hydrolysis of carbonyl sulfide over modified activated carbon [J]. J Central South University,2011,42(3):848(in Chinese). 王红妍,易红宏,唐晓龙,等.改性活性炭催化水解羰基硫[J].中南大学学报,2011,42(3):848. 10 Li X X, Liu Y Y, Wei X H. Technology for carbonyl sulfide removal[J]. Modern Chem Ind,2004,24(8):19(in Chinese). 李新学,刘迎新,魏雄辉.羰基硫脱除技术[J].现代化工,2004,24(8):19. 11 Mok Y S, Nam I S. Positive pulsed corona discharge process for si-multaneous removal of SO2 and NOx from iron-ore sintering flue gas [J]. IEEE Trans Plasma Sci,1999,27(4):1188. 12 Reddy E L, Biju V M, Subrahmanyam C. Production of hydrogen and sulfur from hydrogen sulfide assisted by nonthermal plasma [J]. Appl Energy,2012,95(2):87. 13 Yan X, Sun Y F, Zhu T L, et al. Conversion of carbon disulfide in air by non-thermal plasma [J]. J Hazard Mater,2013,261(1):669. 14 Ning Pin, Xu Ke, Wang Xueqian, et al. Research progress of removal sulfide odors by the non-thermal plasma[J]. Mater Rev: Rev,2015,29(11):62(in Chinese). 宁平,徐可,王学谦,等.低温等离子体技术处理含硫恶臭气体的研究进展[J].材料导报:综述篇,2015,29(11):62. 15 Wang M Y, Zhu T L, Luo H J, et al. Oxidation of gaseous elemental mercury in a high voltage discharge reactor [J]. J Environ Sci,2009,21(12):1652. 16 An G J, Sun Y F, Zhu T L, et al. Degradation of phenol in mists by a non-thermal plasma reactor [J]. Chemosphere,2011,84(9):1296. 17 Naldco J,Goumri A,Maxshall P. A kinetic study of the reaction of atomic oxygen with SO2[J].Proceedings Combustion Institute,2005,30(1):1219. 18 Yan K P,Hui H X,Cui M, et al.Corona induced non-thermal plasmas:Fundamental study and industrial applications [J]. J Electrostat,1998,44(1-2):17. 19 Daga Nkar M V, Beenuekers A A C M, Pangarkar V G. Absorption of sulfur dioxide into aqueous reactive slurries of calcium and magnesium hydroxide in a stirred cell[J].Chem Eng Sci,2001,56(3):1095. 20 Ma Y X, Wang X Q, Ning P. Conversion of COS by corona plasma and the effect of simultaneous removal of COS and dust[J]. Chem Eng J,2016,290:328. 21 Chen H, Kong L D, Chen J M, et al. Heterogeneous uptake of carbonyl sulfide on hematite and hematite-NaCl mixtures [J]. Environ Sci Technol,2007,41(18):6484. 22 Ameomiya Y, Morikawa Y, Pleizier G. Infrared spectroscopy of C18O2 on alumina [J]. J Catal,1977,46(3):431. 23 Liao L F,Lien C F.FTIR study of adsorption and photoassisted oxy-gen isotopic exchange of carbon monoxide, carbon dioxide, carbo-nate, and formate on TiO2[J]. J Phys Chem B,2002,106(43):11240. 24 Li X X,Xu L,Gao M G, et al. Fourier transform infrared greenhouse analyzer for gases and carbon isotope ratio [J]. Optics Precision Eng,2014,22(9):2359. 25 Zeng Y F, Liu Z L, Qin Z Z, et al. Infrared study on adsorption of O3 at SnO2 surface [J]. Spectroscopy Spectral Analy,2008,28(5):1035. 26 Zhang J B, Han F, Wei X H, et al. Spectral studies of hydrogen bonding and interaction in the absorption processes of sulfur dioxidein poly (ethylene glycol) 400+water binary system [J]. Ind Eng Chem Res,2010,49(5):2025. 27 Subrahmanyam C, Magureanu M, Renken A, et al. Catalytic abatement of volatile organic compounds assisted by non-thermal plasma Part 1. A novel dielectric barrier discharge reactor containing catalytic electrode [J]. Appl Cataly B,2006,65(1-2):150. 28 Paillol J, Esprl P, Reess T, et al. Negative corona in air at atmospheric pressure due to a voltage impulse [J]. J Appl Phys,2002,91(9):5614. 29 Wei Gaoen, Gao Xiang, Luo Zhongyang. Removal of NOx from flue gases by moist air as radical source[J]. China Environ Sci,2004,24(4):492(in Chinese). 魏高恩,高翔,骆仲泱.湿空气作为自由基源物质脱除烟气中的NOx[J].中国环境科学,2004,24(4):492. 30 Zou F, Wu Z C, Kang Y. Electrochemical process of heteroatom degradation by DC corona discharge [J]. CIESC J,2010,61:91(in Chinese). 邹芳,吴祖成,康颖.直流电晕放电降解杂原子有机物的电化学过程[J].化工学报,2010,61(S1):91. 31 Zheng W. Optical study of OH radicals produced by DC corona discharge [D]. Dalian: Dalian University of Technology,2007(in Chinese). 郑维.直流电晕放电OH自由基发射光谱研究[D].大连:大连理工大学,2007. 32 Cao W. Research on simultaneous conversion of NO and SO2 in flue gas by pulsed discharge [D]. Hangzhou: Zhejiang University,2008(in Chinese). 曹玮.脉冲放电协同转化烟气中NO、SO2的研究[D].杭州:浙江大学,2008. 33 Shi X G, Pang Y J, Xu X C. Experimental study on improving the desulfurization efficiency of calcium desulfurizing agent mixed with fly ash[J]. J Eng Thermophys,1992,13(4):443(in Chinese). 施学贵,庞亚军,徐旭常.掺加粉煤灰提高含钙脱硫剂的烟气脱硫率的实验研究[J].工程热物理学报,1992,13(4):443. |
|
|
|