| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Optimization and Design Principles of Non-spherical Scatterers Used as Random Scattering Structures for Radiative Cooling |
| YANG Wanglin, PAN Jingyi, LI Hongchao, GONG Hao, ZHOU Xiao, WANG Zhongyang, FAN Tongxiang*
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| State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China |
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Abstract Radiative cooling materials achieve passive cooling by strongly reflecting solar radiation and efficiently emitting thermal radiation in the infrared range, offering notable advantages in energy saving and environmental protection. Achieving high reflectivity in the solar spectrum critically depends on both the material selection and structural design. Currently, random scattering structures commonly utilize spherical particles to enhance reflectivity via the Mie scattering effect. However, spherical particles suffer from weak backscattering and limited enhancement in scattering efficiency at high volume fractions, which significantly constrains the performance improvement and practical implementation of random scattering structures. This work systematically investigates the optical scattering characteristics of various non-spherical particles using the discrete dipole approximation method. The results show that pyramidal and conical particles exhibit superior backward scattering performance, while cylindrical and cuboidal structures demonstrate higher scattering efficiency across the solar spectrum. Based on the volume scattering cross section and asymmetry factor, a comprehensive evaluation parameter is proposed to optimize the design of non-spherical scatterers. These findings provide an important innovative strategy for the development of efficient random scattering structures for radiative cooling.
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Published: 10 March 2026
Online: 2026-03-10
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